公开(公告)号：US20040225028A1

公开(公告)日：2004-11-11

申请号：US10866607

申请日：2004-06-11

Inventor： Walter H. Ohrbom ,  Marvin L. Green ,  Gregory G. Menovcik

IPC: C08J003/28

CPC classification number: C08F4/28 ,  C08F2/06 ,  C08F2/52 ,  C08F2/56 ,  C08F4/04 ,  C09D175/04 ,  C09D201/02 ,  C09D201/025 ,  C08L2666/16

Abstract: Disclosed is a method of making an environmentally durable material, the method requiring providing a material comprising at least one functional group Fc, and subjecting the material to a free radical source such that substantially all functional groups Fc are eliminated but the material is not polymerized. In one embodiment, the functional group Fc is at least one of a nonaromatic carbon-carbon double bond, a hydrogen atom alpha to an aromatic ring, a hydrogen atom alpha to a carbon-carbon double bond, or a hydrogen atom attached to a tertiary substituted carbon. In another embodiment, functional group Fc is present in the material as a contaminant. In one exemplary embodiment, the material comprises from 0.05 to less than 15% by weight of functional group Fc, based on the total weight of the material.

Abstract translation: 公开了一种制备环境耐久材料的方法，该方法需要提供包含至少一个官能团Fc的材料，并使材料经受自由基源，使得基本上所有的官能团Fc都被去除，但是材料没有聚合。 在一个实施方案中，官能团Fc是非芳族碳 - 碳双键，芳族环中的α，氢原子，碳 - 碳双键的氢原子或连接到第三个碳原子上的氢原子中的至少一个 取代碳。 在另一个实施方案中，官能团Fc作为污染物存在于材料中。 在一个示例性实施方案中，基于材料的总重量，该材料包含0.05至小于15重量％的官能团Fc。

公开(公告)号：US20040063850A1

公开(公告)日：2004-04-01

申请号：US10261428

申请日：2002-09-30

Applicant: BASF CORPORATION

Inventor： Walter H. Ohrbom ,  Sergio E. Balatan ,  David J. Law ,  Robert D. Weise

IPC: C08K003/00

CPC classification number: C09D5/02 ,  C09D133/14 ,  C09D201/00 ,  C09D201/02 ,  C09D201/025

Abstract: The invention provides curable waterborne coating compositions comprising an aqueous dispersion (A) comprising an organic binder component (A1) comprising at least 5% by weight of a reactive component (a), based on the total weight of organic binder component (A1), and at least one crosslinking component (B). The reactive component (a) is substantially free of any heteratoms and is a not a crystalline solid at room temperature and comprises from (i) 12 to 72 carbon atoms, and (ii) at least two functional groups. The curable waterborne coating compositions of the invention show significantly improved pop resistance while also providing improved chip resistance, weathering resistance, flexibility, and/or scratch & mar resistance.

Abstract translation: 本发明提供可固化的水性涂料组合物，其包含基于有机粘合剂组分（A1）的总重量的包含至少5重量％的反应性组分（a）的有机粘合剂组分（A1）的水性分散体（A） 和至少一种交联组分（B）。 反应性组分（a）基本上不含任何杂原子，并且在室温下不是结晶固体，并且包含（i）12至72个碳原子，和（ii）至少两个官能团。 本发明的可固化水性涂料组合物显示出显着改善的弹性阻力，同时还提供改善的耐碎屑性，耐候性，柔韧性和/或抗划痕性。

公开(公告)号：US06686432B2

公开(公告)日：2004-02-03

申请号：US10076984

申请日：2002-02-15

Applicant: Simion Coca ,  Edward R. Coleridge ,  Gregory J. McCollum ,  James B. O'Dwyer ,  James E. Poole ,  Victoria A. Trettel

Inventor： Simion Coca ,  Edward R. Coleridge ,  Gregory J. McCollum ,  James B. O'Dwyer ,  James E. Poole ,  Victoria A. Trettel

IPC: C08F1000

CPC classification number: C09D201/02 ,  C08F8/00 ,  C08F10/00 ,  C08F20/00

Abstract: A copolymer composition that includes a copolymer comprised of at least 30 mol % of residues having the following alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer and at least 15 mol % of an acrylic monomer as an acceptor monomer. The copolymer is substantially free of maleate or fumarate monomer segments and the copolymer composition is substantially free of Lewis acids and transition metals. Also disclosed is a thermosetting composition that includes a reactant comprising functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups first reactant, and a copolymer flow control agent that includes the copolymer composition as well as substrates coated with the thermosetting composition.

公开(公告)号：US06555225B1

公开(公告)日：2003-04-29

申请号：US09535532

申请日：2000-03-27

Applicant: Hiroshi Yoshioka ,  Yuichi Mori ,  Sunao Kubota

Inventor： Hiroshi Yoshioka ,  Yuichi Mori ,  Sunao Kubota

IPC: B32B2728

CPC classification number: A61L33/00 ,  A61L33/0011 ,  A61L33/0035 ,  A61L33/062 ,  C09D201/02 ,  Y10T428/31 ,  Y10T428/31504 ,  Y10T428/31855

Abstract: An ion complex which comprises a water-insoluble polyion (P) and a water-soluble polyion (A); and is insoluble in water and soluble in an aqueous organic solvent. Such an ion complex becomes a coating material which can preferably be used for coating of various ionic substances (e.g., substance having biological activity such as an anticoagulant property or an antibacterial property).

Abstract translation: 一种离子络合物，其包含水不溶性聚阳离子（P）和水溶性聚阳离子（A）; 并且不溶于水并溶于含水有机溶剂中。 这样的离子络合物成为能够优选用于各种离子性物质（例如具有抗凝血性，抗菌性等生物活性的物质）的涂布物质。

公开(公告)号：US20030039757A1

公开(公告)日：2003-02-27

申请号：US10106449

申请日：2002-03-27

Applicant: NIPPON PAINT CO., LTD.

Inventor： Hiroto Yoneda ,  Takashi Irie ,  Akihiro Kanakura ,  Yoshifumi Ichinose ,  Yuji Okura ,  Hideo Morimoto

IPC: B05D003/02

CPC classification number: C09D201/02 ,  C09D163/00 ,  C08L2666/02

Abstract: The present invention provides a thermosetting coating composition having a storage stability sufficient to be formed into a one-pack coating despite a small content of organic solvent contained therein and having a sufficient curability, and a method of forming a coating film by which the content of the organic solvent present in a coating at the time of application can be reduced. A thermosetting coating composition comprising a component (a) having a number average molecular weight of 300 to 3000 and two or more active methylene group and/or active methine groups per molecule, a component (b) having a number average molecular weight of 200 to 3000 and two or more null,null-unsaturated carboxylic ester groups per molecule, a component (c) having an onium salt, a component (d) having an epoxy group and/or 5-membered ring carbonate group and a component (e) being an organic acid, a phenol or a Lewis acid, wherein a solid content of said coating composition at a viscosity of 100 mPanulls is 50% by weight or more at 20null C.

Abstract translation: 本发明提供了一种热固性涂料组合物，其具有足以形成为单组分涂料的储存稳定性，尽管其中含有少量有机溶剂并且具有足够的固化性，并且形成涂膜的方法， 可以减少涂布时存在于涂料中的有机溶剂。 一种包含数均分子量为300〜3000的成分（a）和每分子2个以上的活性亚甲基和/或活性次甲基的组分（a）的热固性涂料组合物，数均分子量为200〜 3000和每个分子两个或更多个α，β-不饱和羧酸酯基团，具有鎓盐的组分（c），具有环氧基的组分（d）和/或5-元环碳酸酯基团和组分（e） 作为有机酸，苯酚或路易斯酸，其中在20℃下粘度为100mPa.s的所述涂料组合物的固体含量为50重量％以上。

公开(公告)号：US20030009052A1

公开(公告)日：2003-01-09

申请号：US10206466

申请日：2002-07-26

Inventor： Swaminathan Ramesh ,  Marvin L. Green

IPC: C07C261/00

CPC classification number: C08G63/42 ,  C08G63/58 ,  C08G63/6854 ,  C09D5/04 ,  C09D7/43 ,  C09D201/005 ,  C09D201/02 ,  C09D201/025 ,  Y10T428/31551 ,  Y10T428/31786 ,  Y10T428/31794

Abstract: The present invention is directed to a rheology control agent. The rheology control agent is used in a coating composition and is the reaction product of a first compound comprising a plurality of hydroxyl groups, of a lactone compound, and of a carbamate compound. The present invention is also directed to a coating composition including the rheology control agent and to a method of preparing the rheology control agent.

Abstract translation: 本发明涉及一种流变控制剂。 流变控制剂用于涂料组合物中，并且是包含多个羟基的第一化合物，内酯化合物和氨基甲酸酯化合物的反应产物。 本发明还涉及包含流变控制剂的涂料组合物和制备流变控制剂的方法。

公开(公告)号：US20020123607A1

公开(公告)日：2002-09-05

申请号：US10007354

申请日：2001-11-09

Inventor： Marko Strukelj

IPC: C08G069/26

CPC classification number: C09D201/02 ,  C07C251/08 ,  C08F14/16 ,  C08F14/20 ,  C08G18/3256 ,  C08K5/29 ,  C09D7/20 ,  C09D175/02 ,  C09D201/005 ,  C08L101/02

Abstract: This invention concerns low viscosity aldimine and ketimine reactive diluents having multi-imine functionality, which are useful in automotive refinish coating compositions, including a process for making them and the coatings that contain them.

公开(公告)号：US06423788B1

公开(公告)日：2002-07-23

申请号：US08686929

申请日：1995-10-06

Applicant: Brian D. Bammel ,  John D. McGee ,  Walter H. Ohrbom ,  Todd A. Seaver ,  Paul J. Harris ,  John W. Rehfuss

Inventor： Brian D. Bammel ,  John D. McGee ,  Walter H. Ohrbom ,  Todd A. Seaver ,  Paul J. Harris ,  John W. Rehfuss

IPC: C09D17300

CPC classification number: C09D201/02 ,  C08G71/00 ,  C09D167/04 ,  C09D201/025 ,  Y10T428/31551

Abstract: A curable coating composition is described comprising (A) a carbamate- or urea-functional compound that is the reaction product of a mixture comprising (1) a compound comprising a carbamate or urea group or a group that can be converted to carbamate or urea, and a hydroxyl functional group that is the reaction product of (a) a compound comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group that is reactive with a lactone ring or a hydroxy carboxylic acid, and (b) a lactone or a hydroxy carboxylic acid, and (2) a compound that is reactive with hydroxyl groups on a plurality of molecules of compound (A)(1), but that is not reactive with the carbamate or urea groups on compound (A)(1), (B) a compound comprising a plurality of groups that are reactive with carbamate or urea.

Abstract translation: 描述了可固化涂料组合物，其包含（A）氨基甲酸酯或脲官能化合物，其为包含（1）包含氨基甲酸酯或脲基团的化合物或可转化为氨基甲酸酯或脲的基团的混合物的反应产物， 和作为（a）包含氨基甲酸酯或脲基的化合物或可以转化为氨基甲酸酯或脲基的基团的反应产物的羟基官能团以及与内酯环或 羟基羧酸和（b）内酯或羟基羧酸，和（2）与多个化合物（A）（1）分子上的羟基反应但不与氨基甲酸酯反应的化合物 或化合物（A）（1）上的脲基，（B）包含与氨基甲酸酯或脲反应的多个基团的化合物。

公开(公告)号：US20020018898A1

公开(公告)日：2002-02-14

申请号：US09855923

申请日：2001-05-15

Inventor： Margaret P. Opolski

IPC: B32B027/00

CPC classification number: C09D175/04 ,  A61L27/34 ,  A61L29/085 ,  A61L31/10 ,  C08G18/833 ,  C08L39/06 ,  C08L71/02 ,  C09D133/062 ,  C09D201/02 ,  Y10T428/1307 ,  Y10T428/1376 ,  Y10T428/31504 ,  Y10T428/31511 ,  Y10T428/31551 ,  Y10T428/31562 ,  Y10T428/31573 ,  Y10T428/31591 ,  Y10T428/31855 ,  Y10T428/31862 ,  Y10T428/3188 ,  Y10T428/31909 ,  Y10T428/31928 ,  C08L2666/04 ,  C08L2666/14 ,  C08L2666/16 ,  C08L2666/20 ,  C08L2666/22 ,  C08L61/20 ,  C08L2666/02 ,  C08L75/04

Abstract: A water-based coating composition suitable for preparing hydrophilic surfaces on various articles is provided which includes a supporting polymer having functional moieties capable of undergoing crosslinking reactions, said supporting polymer soluble in or emulsified in an aqueous based medium; and a hydrophilic polymer, said hydrophilic polymer associated with the supporting polymer. The composition is characterized in that, when crosslinked at the functional moieties, the supporting polymer forms a three-dimensional network which substantially minimizes disassociation of the hydrophilic polymer.

Abstract translation: 提供了适用于制备各种制品上的亲水表面的水性涂料组合物，其包括具有能够进行交联反应的官能部分的支撑聚合物，所述支持聚合物可溶于水基介质中或在水性介质中乳化; 和亲水性聚合物，所述亲水性聚合物与支持聚合物相关联。 该组合物的特征在于，当在官能部分交联时，支持聚合物形成三维网络，其基本上最小化亲水性聚合物的分离。

公开(公告)号：US06262169B1

公开(公告)日：2001-07-17

申请号：US09078924

申请日：1998-05-14

Applicant: Bradley James Helmer ,  David Logan Murray ,  Charles Howard Foster

Inventor： Bradley James Helmer ,  David Logan Murray ,  Charles Howard Foster

IPC: C08L3900

CPC classification number: C09D133/062 ,  C08F8/30 ,  C08K5/17 ,  C08L101/02 ,  C09D201/02 ,  C08L33/062 ,  C08L2666/36

Abstract: The latex polymer compositions of the present invention exhibit latent crosslinking properties. Latent crosslinking in the polymers takes advantage of the fast reaction that occurs between amine-reactive carbonyl groups in the polymer component and carbonyl-reactive amine nitrogens in the crosslinking component, but controls the rate of crosslinking by protonating the amines with a volatile acid. Once the latex is coated onto a substrate, the volatile acid evaporates and the carbonyl reactive amine nitrogens react with the amine reactive carbonyl groups to form a crosslinked coating.

Abstract translation: 本发明的胶乳聚合物组合物具有潜在的交联性能。 聚合物中的潜在交联利用了聚合物组分中的胺反应性羰基和交联组分中的羰基 - 反应性胺氮之间发生的快速反应，但通过用挥发性酸质子化胺来控制交联速率。 一旦将胶乳涂覆到基底上，挥发性酸就蒸发，羰基反应性胺氮与胺反应性羰基反应形成交联涂层。