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    Composition for refrigerator working fluid use
    372.
    发明公开
    Composition for refrigerator working fluid use 失效
    Zusammensetzung zur Verwendung alsArbeitsflüssigkeitfürKältemaschinen。

    公开(公告)号：EP0501440A1

    公开(公告)日：1992-09-02

    申请号：EP92103253.8

    申请日：1992-02-26

    Applicant: KAO CORPORATION

    Inventor： Hagihara, Toshiya ,  Sakai, Akimitsu ,  Suzuki, Hideo

    IPC: C10M169/04 ,  C10M171/00 ,  C09K5/04

    CPC classification number: C10M105/42 ,  C09K5/045 ,  C09K2205/24 ,  C10M129/18 ,  C10M133/22 ,  C10M133/44 ,  C10M137/02 ,  C10M137/04 ,  C10M169/04 ,  C10M171/008 ,  C10M2201/041 ,  C10M2201/042 ,  C10M2207/042 ,  C10M2207/08 ,  C10M2207/301 ,  C10M2207/302 ,  C10M2207/304 ,  C10M2209/112 ,  C10M2211/022 ,  C10M2211/06 ,  C10M2211/08 ,  C10M2213/00 ,  C10M2213/04 ,  C10M2213/06 ,  C10M2215/14 ,  C10M2215/223 ,  C10M2223/02 ,  C10M2223/04 ,  C10M2223/041 ,  C10M2223/049 ,  C10M2223/10

    Abstract: This invention provides a refrigerator working fluid composition characterized by excellent compatibility, lubricating ability, thermal stability, and electrical insulation capacity, and comprising a refrigerating machine oil and a hydrofluorocarbon compound, wherein the refrigerating machine oil comprises:

    (A) 100 parts by weight of at least one ester compound selected from the group consisting of:

    (1) ester compounds obtained from

    (a) an aliphatic polyhydric alcohol having 1 to 6 primary hydroxyl groups,
    (b) a straight or branched chain saturated aliphatic monocarboxylic acid having 2 to 9 carbon atoms or a derivative thereof, and
    (c) a straight or branched chain saturated aliphatic dicarboxylic acid having 2 to 10 carbon atoms or a derivative thereof; and

    (2) ester compounds obtained from

    (a) an aliphatic polyhydric alcohol having 1 to 6 primary hydroxyl groups,
    (d) a straight or branched chain saturated aliphatic monohydric alcohol having 1 to 10 carbon atoms, and
    (e) a polycarboxylic acid having 2 to 10 carbon atoms or a derivative thereof; and


    (B) at least one compound selected from the group consisting of 0.1 to 5.0 parts by weight of a triaryl phosphate, a triaryl phosphite, or a mixture thereof; 0.001 to 0.1 parts by weight of benzotriazole, a derivative thereof, or a mixture thereof; 0.05 to 2.0 parts by weight of an epoxy group-containing compound; and 0.001 to 2.0 parts by weight of a metal deactivator having a chelating function.

    Abstract translation: 本发明提供了一种特征在于相容性，润滑能力，热稳定性和电绝缘能力优异的冰箱工作流体组合物，并且包括冷冻机油和氢氟烃化合物，其中冷冻机油包含：（A）100重量份 至少一种选自以下的酯化合物：（1）由（a）具有1至6个伯羟基的脂族多元醇获得的酯化合物，（b）具有2至9个直链或支链的直链或支链饱和脂肪族单羧酸 碳原子或其衍生物，和（c）具有2-10个碳原子的直链或支链饱和脂族二羧酸或其衍生物; 和（2）由（a）具有1至6个伯羟基的脂族多元醇得到的酯化合物，（d）具有1至10个碳原子的直链或支链饱和脂族一元醇，和（e）多羧酸，其具有 2至10个碳原子或其衍生物; 和（B）至少一种选自0.1至5.0重量份的磷酸三芳基酯，亚磷酸三芳基酯或它们的混合物的化合物; 0.001至0.1重量份的苯并三唑，其衍生物或其混合物; 0.05〜2.0重量份含环氧基的化合物; 0.001〜2.0重量份具有螯合功能的金属钝化剂。

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