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    Polyethylene film with high tensile strength and high tensile energy to break
    381.
    发明公开
    Polyethylene film with high tensile strength and high tensile energy to break 审中-公开
    Polyethylenfolie mit hoher Bruchfestigkeit und hoher Zugbrucharbeit

    公开(公告)号：EP2014445A1

    公开(公告)日：2009-01-14

    申请号：EP07013377.2

    申请日：2007-07-09

    Applicant: Teijin Aramid B.V.

    Inventor： De Weijer, Anton Peter ,  Peters, Martinus Wilhemis Maria Gemma ,  Van de Hee, Hendrik ,  Sanjay, Rastogi ,  Wang, Bing

    IPC: B29C55/00 ,  B29C55/04 ,  B29K23/00

    CPC classification number: B29C55/005 ,  B29C55/04 ,  B29K2023/0683 ,  D07B1/025 ,  D07B2201/2003 ,  D07B2201/2009 ,  D07B2205/2014 ,  Y10T428/249921 ,  Y10T442/10 ,  D07B2801/10

    Abstract: The present invention pertains to a UHMWPE film having a tensile strength of at least 2.0 GPa, a tensile energy to break of at least 30 J/g, an Mw of at least 500 000 gram/mole, and a Mw/Mn ratio of at most 8.
    The film may be manufactured via a process which comprises subjecting a starting UHMWPE with a weight average molecular weight of at least 500 000 gram/mole, an elastic modulus determined directly after melting at 160°C of at most 0.9 MPa, and a Mw/Mn ratio of at most 8 to a compacting step and a stretching step under such conditions that at no point during the processing of the polymer its temperature is raised to a value above its equilibrium melting point.
    The film may be used as starting material in any applications where high tensile strength and high energy to break are important. Suitable applications include ballistic applications, ropes, cables, nets, fabrics, and protective applications.

    Abstract translation: 本发明涉及一种UHMWPE薄膜，其拉伸强度为至少2.0GPa，拉伸断裂能至少为30J / g，Mw至少为500000克/摩尔，Mw / Mn比为 该膜可以通过以下方法制造，该方法包括使重均分子量为至少500000克/摩尔的起始UHMWPE，直接在160℃下熔化至0.9MPa的弹性模量，以及 在压缩加工过程中任何时候，将其温度升高到高于其平衡熔点的值的条件下，Mw / Mn比至多为8的压实步骤和拉伸步骤。 在高拉伸强度和高能量破裂重要性的任何应用中，该膜可用作起始材料。 合适的应用包括弹道应用，绳索，电缆，网，织物和保护性应用。

    A protective glove comprising high strength polyethylene fibers
    385.
    发明公开
    A protective glove comprising high strength polyethylene fibers 有权
    Schutzhandschuh enthaltend hochfeste聚乙烯

    公开(公告)号：EP1335049A1

    公开(公告)日：2003-08-13

    申请号：EP03006188.1

    申请日：2000-03-23

    Applicant: Toyo Boseki Kabushiki Kaisha

    Inventor： Konishi, Takuya, c/o Toyo Boseki K.K., Res. Inst., ,  Ohta, Yasuo, c/o Toyo Boseki K.K., Res. Inst., ,  Sakamoto, Godo, c/o Toyo Boseki K.K., Res. Inst.,

    IPC: D01F6/04

    CPC classification number: C04B16/0625 ,  D01F6/04 ,  D07B1/025 ,  D07B2201/2009 ,  D07B2205/2014 ,  Y10S428/911 ,  Y10T428/24124 ,  Y10T428/249932 ,  Y10T428/24994 ,  Y10T428/29 ,  Y10T428/2913 ,  Y10T428/2936 ,  Y10T428/2964 ,  Y10T428/2967 ,  Y10T428/2969 ,  D07B2801/10

    Abstract: A protective glove comprising high strength polyethylene fibers
       in which the fiber is characterized in that: it contains a high molecular weight polyethylene consisting essentially of a repeating unit of ethylene; it has an intrinsic viscosity number of 5 or larger and an average strength of 22 cN/dtex or higher; and the measurement of the fiber by differential scanning calorimetry (DSC) exhibits a temperature-increasing DCS curve having at least one endothermic peak over a temperature region of 140°C to 148°C (on the low temperature side) and at least one endothermic peak over a temperature: region of 148°C or higher (on the high temperature side) or the number of frictions until the fiber is broken in an abrasion test according to method B for measuring abrasion resistance in the Testing Methods for Spun Yarn (JIS L 1095) is 100,000 or larger.

    Abstract translation: 高强度聚乙烯纤维及其应用，例如短切纤维，绳索，网，弹道材料或物品，防护手套，纤维增强混凝土制品，头盔以及由此获得的其他产品，其中纤维的特征在于：其包含 基本上由乙烯的重复单元组成的高分子量聚乙烯; 其特性粘数为5以上，平均强度为22cN / dtex以上; 并且通过差示扫描量热法（DSC）测量纤维表现出在140℃至148℃的温度区域（在低温侧）具有至少一个吸热峰的升温DCS曲线和至少一个吸热 在“纺纱试验方法”（JIS L）中，在148℃以上的温度区域（高温侧）上的峰值，或者在根据用于测量耐磨性的方法B的磨损试验中直到纤维断裂的摩擦次数 1095）为100,000以上。

    A net comprising high strength polyethylene fibers
    386.
    发明公开
    A net comprising high strength polyethylene fibers 有权
    Netz enthaltend hochfeste聚乙烯

    公开(公告)号：EP1335047A1

    公开(公告)日：2003-08-13

    申请号：EP03006186.5

    申请日：2000-03-23

    Applicant: Toyo Boseki Kabushiki Kaisha

    Inventor： Ohta, Yasuo, c/o Toyo Boseki K.K. Res. Inst., ,  Nakahashi, Junichi

    IPC: D01F6/04

    CPC classification number: C04B16/0625 ,  D01F6/04 ,  D07B1/025 ,  D07B2201/2009 ,  D07B2205/2014 ,  Y10S428/911 ,  Y10T428/24124 ,  Y10T428/249932 ,  Y10T428/24994 ,  Y10T428/29 ,  Y10T428/2913 ,  Y10T428/2936 ,  Y10T428/2964 ,  Y10T428/2967 ,  Y10T428/2969 ,  D07B2801/10

    Abstract: A net comprising high strength polyethylene fibers
       in which the fiber is characterized in that: it contains a high molecular weight polyethylene consisting essentially of a repeating unit of ethylene; it has an intrinsic viscosity number of 5 or larger and an average strength of 22 cN/dtex or higher; and the measurement of the fiber by differential scanning calorimetry (DSC) exhibits a temperature-increasing DCS curve having at least one endothermic peak over a temperature region of 140°C to 148°C (on the low temperature side) and at least one endothermic peak over a temperature region of 148°C or higher (on the high temperature side) or the number of frictions until the fiber is broken in an abrasion test according to method B for measuring abrasion resistance in the Testing Methods for Spun Yarn (JIS L 1095) is 100,000 or larger.

    Abstract translation: 高强度聚乙烯纤维及其应用，例如短切纤维，绳索，网，弹道材料或物品，防护手套，纤维增强混凝土制品，头盔以及由此获得的其他产品，其中纤维的特征在于：其包含 基本上由乙烯的重复单元组成的高分子量聚乙烯; 其特性粘数为5以上，平均强度为22cN / dtex以上; 并且通过差示扫描量热法（DSC）测量纤维表现出在140℃至148℃的温度区域（在低温侧）具有至少一个吸热峰的升温DCS曲线和至少一个吸热 在“纺纱试验方法”（JIS L）中，在148℃以上的温度区域（高温侧）上的峰值，或者在根据用于测量耐磨性的方法B的磨损试验中直到纤维断裂的摩擦次数 1095）为100,000以上。

    HIGH STRENGTH POLYETHYLENE FIBER AND ITS USE
    389.
    发明公开
    HIGH STRENGTH POLYETHYLENE FIBER AND ITS USE 有权
    德国VERWENDUNG的HOCHFESTE POLYETHYLENFASERN

    公开(公告)号：EP1126052A1

    公开(公告)日：2001-08-22

    申请号：EP00911305.1

    申请日：2000-03-23

    Applicant: Toyo Boseki Kabushiki Kaisha

    Inventor： OHTA, Yasuo ,  Sakamoto, Godo ,  Miyasaka, Tadayo ,  Okano, Takayoshi ,  Nakahashi, Junichi ,  Nomura, Yukihiro ,  Konishi, Takuya

    IPC: D01F6/04 ,  C04B16/06

    CPC classification number: C04B16/0625 ,  D01F6/04 ,  D07B1/025 ,  D07B2201/2009 ,  D07B2205/2014 ,  Y10S428/911 ,  Y10T428/24124 ,  Y10T428/249932 ,  Y10T428/24994 ,  Y10T428/29 ,  Y10T428/2913 ,  Y10T428/2936 ,  Y10T428/2964 ,  Y10T428/2967 ,  Y10T428/2969 ,  D07B2801/10

    Abstract: High strength polyethylene fibers and their applications, for example, chopped fibers, ropes, nets, ballistic materials or items, protective gloves, fiber reinforced concrete products, helmets, and other products obtained therefrom, in which the fiber is characterized in that: it contains a high molecular weight polyethylene consisting essentially of a repeating unit of ethylene; it has an intrinsic viscosity number of 5 or larger and an average strength of 22 cN/dtex or higher; and the measurement of the fiber by differential scanning calorimetry (DSC) exhibits a temperature-increasing DCS curve having at least one endothermic peak over a temperature region of 140°C to 148°C (on the low temperature side) and at least one endothermic peak over a temperature region of 148°C or higher (on the high temperature side) or the number of frictions until the fiber is broken in an abrasion test according to method B for measuring abrasion resistance in the Testing Methods for Spun Yarn (JIS L 1095) is 100,000 or larger.

    Abstract translation: 高强度聚乙烯纤维及其应用，例如短切纤维，绳索，网，弹道材料或物品，防护手套，纤维增强混凝土制品，头盔以及由此获得的其他产品，其中纤维的特征在于：其包含 基本上由乙烯的重复单元组成的高分子量聚乙烯; 其特性粘数为5以上，平均强度为22cN / dtex以上; 并且通过差示扫描量热法（DSC）测量纤维表现出在140℃至148℃的温度区域（在低温侧）具有至少一个吸热峰的升温DCS曲线和至少一个吸热 在“纺纱试验方法”（JIS L）中，在148℃以上的温度区域（高温侧）上的峰值，或者在根据用于测量耐磨性的方法B的磨损试验中直到纤维断裂的摩擦次数 1095）为100,000以上。

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