Abstract:
A process for the preparation of 1-chloro-2,2-difluoroethane ("142") wherein 1,2-dichloroethene ("1130") is fluorinated in the gas phase in the presence of a catalyst which is a supported or unsupported fluorinated salt of one or more of chromium, iron, niobium, nickel, antimony, tin, tantalum or titanium. 142 is a known foam blowing agent.
Abstract:
Disclosed is a process for the preparation of cis/trans 1,1,1,3-tetrafluoro-2-propene (1234 ze) which comprises (a) contacting 1,1,1,3,3-pentafluoropropane (245fa) with an alkaline solution, preferably an aqueous or alcoholic solution of a base such as KOH, NaOH, Ca(OH) 2 or Mg(OH) 2 , or with a chromium-based catalyst, such as fluorided Cr 2 O 3 or fluorided Cr/Ni/Alf 3 , and (b) recovering cis/trans 1,1,1,3-tetrafluoro-2-propene from the reaction mixture.
Abstract translation:公开了一种制备顺式/反式1,1,1,3-四氟-2-丙烯(1234 ze)的方法,其包括(a)使1,1,1,3,3-五氟丙烷(245fa)与 碱性溶液,优选碱如KOH,NaOH,Ca(OH)2或Mg(OH)2的水溶液或醇溶液,或与铬基催化剂如氟化Cr 2 O 3或氟化Cr / Ni / Alf 3, 和(b)从反应混合物中回收顺/反1,1,1,3-四氟-2-丙烯。
Abstract:
An uncatalyzed liquid phase process is provided for the preparation of oligomer free 1233zd via the fluorination of 1230za with a high molar excess of HF. The 1233zd is a known intermediate useful for preparing 245fa (1,1,1,3,3-pentafluoropropane).
Abstract:
A process for the preparation of 1,1,1,3,3-pentafluoropropane (245fa) is provided, wherein 1233zd is first fluorinated to 1234ze, followed by fluorination of 1234ze to 245fa. 245fa is a known foam blowing agent and refrigerant.
Abstract:
New and novel copolymers of vinylidene fluoride and hexafluoropropylene containing up to about 24 % by weight hexafluoropropylene having improved solution clarity and fluidity, longer gel times and lower extractables than prior art vinylidine fluoride-hexafluoropropylene copolymers of comparable HFP content whose syntheses are disclosed in sufficient detail to duplicate, the novel compositions of matter and articles of manufacture containing such copolymers, of the compositions of matter containing such copolymers and of the articles of manufacture containing such copolymers are disclosed. Also disclosed are novel battery constructions based on the novel copolymers of vinylidene fluoride/hexafluoropropylene copolymers of the invention, on vinylidene fluoride homopolymers having a bimodal molecular weight distribution and on vinylidene fluoride/chlorotrifluoroethylene copolymers having a substantially homogeneous monomer distribution.
Abstract:
Dual cure organotin salts of strong organic acids, the use of such salts as catalysts and an improved process for producing the catalysts are provided. The catalysts are capable of effectively catalyzing esterification and transesterification reactions and urethane, silicone, melamine, ester and acrylic forming reactions and can simultaneously catalyze more than one reaction in a mixture of urethane, silicone, amino, ester and acrylic polymer forming reactants to produce a polymer mixture.
Abstract:
A paint base comprising a vinylidene fluoride-hexafluoropropylene copolymer having one or more discrete vinylidene fluoride-hexafluoropropylene copolymer domains and one or more discrete vinylidene fluoride homopolymer domains including a major portion of vinylidene fluoride homopolymer domain which contains at least 50% of the vinylidene fluoride content of the polymers, paints and varnishes therefrom, coatings derived from said paints and varnishes and articles coated with said coatings are disclosed. The coatings have improved gloss, flex, crack resistance and other use properties.