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公开(公告)号：KR101012078B1
公开(公告)日：2011-02-07
申请号：KR1020080126939
申请日：2008-12-15
Applicant: 제일모직주식회사
Abstract: 본 발명의 비할로겐계 난연성 폴리카보네이트 수지 조성물은 (A) 폴리카보네이트 수지 50~99 중량% 및 (B) 고무 변성 스티렌 수지 1~50 중량%로 이루어지는 기초수지 (A)+(B) 100중량부; 및 (C) 2,4-디터셔리부틸페닐 페닐포스페이트 0.5∼50 중량부;로 구성되는 것을 특징으로 한다. 본 발명에 따른 비할로겐계 난연성 폴리카보네이트계 수지 조성물은 화재에 대하여 안정성이 있고, 연소 시에 환경 오염을 야기시키지 않는 환경 친화적인 효과를 얻을 수 있다.
폴리카보네이트계 수지, 고무변성 스티렌계 수지, 2,4-디터셔리부틸페닐 페닐포스페이트, 인계 화합물-
公开(公告)号：KR1020100068544A
公开(公告)日：2010-06-24
申请号：KR1020080126939
申请日：2008-12-15
Applicant: 제일모직주식회사
Abstract: PURPOSE: A non-halogenated flame retarding polycarbonate resin composition is provided to have stability to fire and to obtain environment-friendly effect without raising environmental contaminants in combustion. CONSTITUTION: A non-halogenated flame retarding polycarbonate resin composition comprises: base resin 100.0 parts by weight and 2,4-ditertbutylphenyl phenyl phosphate compound 0.5~50 parts by weight. The base resin is comprised of polycarbonate resin 50~99 parts by weight and rubber-modified styrene resin 1~50 parts by weight. The 2,4-ditertbutylphenyl phenyl phosphate compound has a structure of a chemical formula 1.
Abstract translation: 目的：提供非卤化阻燃聚碳酸酯树脂组合物以具有稳定的火焰和获得环境友好的效果，而不会引起燃烧中的环境污染物。 构成：非卤化阻燃聚碳酸酯树脂组合物包括：100.0重量份的基础树脂和0.5〜50重量份的2,4-二叔丁基苯基苯基磷酸酯化合物。 基础树脂由50〜99重量份的聚碳酸酯树脂和1〜50重量份的橡胶改性苯乙烯树脂构成。 2,4-二叔丁基苯基苯基磷酸酯化合物具有化学式1的结构。
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公开(公告)号：KR1020100004848A
公开(公告)日：2010-01-13
申请号：KR1020090029478
申请日：2009-04-06
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic resin composition containing frame retardant and impact modifier is provided to improve flame retardance and impact strength of the thermoplastic resin. CONSTITUTION: A flame retardant and an impact modifier are denoted by chemical formula 1. A method for producing the flame retardant and an impact modifier comprises: a step of reacting 2,4-ditertierybutylphenol with phosphorus oxychloride to prepare 2,4-ditertiarybutylphenyl dichlorophosphate; and a step of reacting phenol to the 2,4-ditertiarybutylphenyl dichlorophosphate. A thermoplastic resin composition contains 100 weight parts of thermoplastic resin and 0.1-30 weight parts of flame retardant and an impact modifier. The thermoplastic resin comprises 70-99 weight% of rubber-modified polystyrene system and 1-30 weight% of polyphenyleneether resin.
Abstract translation: 目的：提供含有阻燃和抗冲击改性剂的热塑性树脂组合物，以改善热塑性树脂的阻燃性和冲击强度。 构成：阻燃剂和抗冲改性剂由化学式1表示。阻燃剂和抗冲改性剂的制造方法包括：使2,4-二叔丁基苯酚与磷酰氯反应制备2,4-二叔丁基苯基二氯磷酸盐的步骤; 以及使苯酚与2,4-二叔丁基苯基二氯磷酸盐反应的步骤。 热塑性树脂组合物含有100重量份的热塑性树脂和0.1-30重量份的阻燃剂和抗冲改性剂。 热塑性树脂包含70-99重量％的橡胶改性聚苯乙烯体系和1-30重量％的聚苯醚树脂。
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公开(公告)号：KR1020090067028A
公开(公告)日：2009-06-24
申请号：KR1020080098437
申请日：2008-10-08
Applicant: 제일모직주식회사
IPC: C07F9/6587 , C07F9/547 , C08L25/08 , C08K5/5337
CPC classification number: C07F9/6571 , C08K5/5357 , C08L25/08 , C08L2201/02 , C08L2666/84 , C09K21/12
Abstract: A flame retardant styrene resin composition containing symmetric cyclic phosphonate compound is provided to ensure excellent flam resistance and impact strength. A symmetric cyclic phosphonate compound of the chemical formula is produced by reacting a phosphonic dichloride of the chemical formula 2 and a polyol of the chemical formula 3 under the presence of the base. In the chemical formula 1, R1 and R2 are individually hydrogen, alkyl group of C1~C6 or aryl group of C6~C20. A flame retardant styrene resin composition comprises 100 weight part of base resin containing 60-99 weigh% of styrene resin and 1-40 weight% of polyphenylene ether resin, and 0.5-50 weight par of symmetric cyclic phosphonate compounds or their mixture.
Abstract translation: 提供含有对称环状膦酸酯化合物的阻燃苯乙烯树脂组合物，以确保优异的抗燃性和冲击强度。 化学式的对称环状膦酸酯化合物是通过在碱的存在下使化学式2的二氯化膦与化学式3的多元醇反应来制备的。 在化学式1中，R1和R2分别为氢，C1〜C6的烷基或C6〜C20的芳基。 阻燃苯乙烯树脂组合物包含100重量份含60-99重量％苯乙烯树脂和1-40重量％聚苯醚树脂的基础树脂和0.5-50重量比对称的环状膦酸酯化合物或它们的混合物。
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公开(公告)号：KR1020090060585A
公开(公告)日：2009-06-15
申请号：KR1020070127462
申请日：2007-12-10
Applicant: 제일모직주식회사
IPC: C09K21/02
CPC classification number: C09K21/12 , C07F9/4006 , C07F9/4021 , C07F9/4084 , C08K5/51 , C08L51/04 , C08L69/00 , C08L2666/24
Abstract: A sterically hindered phenolic phosphonate-based flame retardant is provided to ensure excellent fire retardant effect, to prevent environmental contamination, and to be applicable to the thermalplastic flame retardant polycarbonate resin composition. A sterically hindered phenolic phosphonate-based flame retardant has a structure of chemical formula 1. In chemical formula 1, R1 is C1-C6 alkyl and C6-C14 aryl group; R2 is C1-C6 linear alkyl and C3-C6 branched alkyl group; and n is 1-3. A flame retardant polycarbonate-based resin composition comprises a base resin 100.0 parts by weight including a polycarbonate resin; and a sterically hindered phenolic phosphonate-based compound 0.5~20 parts by weight represented by chemical formula 1.
Abstract translation: 提供空间位阻酚型膦酸酯类阻燃剂，以确保优异的阻燃效果，防止环境污染，并适用于热塑性阻燃聚碳酸酯树脂组合物。 空间位阻酚膦酸酯类阻燃剂具有化学式1的结构。在化学式1中，R 1为C 1 -C 6烷基和C 6 -C 14芳基; R2是C1-C6直链烷基和C3-C6支链烷基; n为1-3。 阻燃聚碳酸酯类树脂组合物包含100.0重量份的包含聚碳酸酯树脂的基础树脂; 和以化学式1表示的0.5〜20重量份的空间位阻酚膦酸酯类化合物。
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Patent Agency Ranking
公开(公告)号：KR100877291B1
公开(公告)日：2009-01-07
申请号：KR1020070117717
申请日：2007-11-19
Applicant: 제일모직주식회사
IPC: C08L69/00 , C08K5/5373 , C08L53/00 , C08L33/06
CPC classification number: C08L69/00 , C08K5/523 , C08K5/5357 , C08L25/08 , C08L25/12 , C08L33/06 , C08L33/12 , C08L51/04 , C08L55/02 , C08L2666/04 , C08L2666/02
Abstract: An environment-friendly flame retardant polycarbonate resin composition is provided to ensure the stability to an environment-friendly flame retardant polycarbonate-based resin composition without using a halogen-based flame retardant. A halogen-based flame retardant polycarbonate resin composition comprises a base resin 100.0 parts by weight and a cyclic tertial-butyl phosphonate 0.5-30 parts by weight. The base resin comprises (A) a polycarbonate resin 50-100 weight%, and (B) a rubber-modified aromatic vinyl resin 0-50 weight% and (C) an alkyl (meth) acrylate resin 0-50 weight%. The cyclic t-butyl phosphonate has a structure of the chemical formula 1. In the chemical formula 1, R1 and R2 are H, C1-C6 alkyl and C6-C10 aryl.
Abstract translation: 提供一种环保型阻燃聚碳酸酯树脂组合物，以确保不使用卤素类阻燃剂的环保型阻燃聚碳酸酯类树脂组合物的稳定性。 卤素系阻燃聚碳酸酯树脂组合物包含100.0重量份的基础树脂和0.5-30重量份的环状叔丁基膦酸酯。 基础树脂包含（A）50-100重量％的聚碳酸酯树脂和（B）0-50重量％的橡胶改性芳族乙烯基树脂和（C）0-50重量％的（甲基）丙烯酸烷基酯树脂。 环状叔丁基膦酸酯具有化学式1的结构。在化学式1中，R 1和R 2是H，C 1 -C 6烷基和C 6 -C 10芳基。
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公开(公告)号：KR100776212B1
公开(公告)日：2007-11-29
申请号：KR1020060111126
申请日：2006-11-10
Applicant: 제일모직주식회사
Abstract: A nonhalogenated flame retardant styrene-based resin composition is provided to obtain excellent flame retardancy without using a harmful halogen-based flame retardant. A styrene-based resin composition comprises 100 parts by weight of a base resin which comprises 50-90 parts by weight of a styrene-based resin, and 10-50 parts by weight of a polyphenylene ether resin; 0.1-50 parts by weight of a phosphorus triazine compound represented by the formula 1; and 0.1-30 parts by weight of at least one phosphorus-based compound selected from the group consisting of an alkyl phosphinic acid metal salt, an aromatic phosphoric acid compound and a phosphazene compound.
Abstract translation: 提供非卤化阻燃苯乙烯类树脂组合物，以在不使用有害的卤素类阻燃剂的情况下获得优异的阻燃性。 苯乙烯类树脂组合物包含100重量份的包含50-90重量份苯乙烯基树脂和10-50重量份聚苯醚树脂的基础树脂; 0.1-50重量份由式1表示的磷三嗪化合物; 和0.1-30重量份的至少一种选自烷基次膦酸金属盐，芳族磷酸化合物和磷腈化合物的磷基化合物。
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公开(公告)号：KR1020120078582A
公开(公告)日：2012-07-10
申请号：KR1020110114177
申请日：2011-11-03
Applicant: 제일모직주식회사
CPC classification number: C09K21/14
Abstract: PURPOSE: A polyphosphonate is provided to remarkably reduce acid value without using an end-capping agent, and to able to provide a flame retardant thermoplastic resin composition having excellent flame retardance, and thermal resistance, and not degrading other physical properties. CONSTITUTION: A polyphosphonate is in chemical formula 1, and has acid value of 5.5 KOH mg/g or less. In chemical formula 1, A is a single bond, C1-5 alkylene, C1-5 alkylidene, C5-6 cycloalkylidene, -S- or -SO2-, R is a substituted or unsubstituted C6-20 aryl group, or a C6-20 substituted or unsubstituted aryloxy group, R1 and R2 is respectively and independently a substituted or unsubstituted C1-6 alkyl group, a substituted or unsubstituted C3-6 cycloalkyl group, a substituted or unsubstituted C6-12 aryl group, or halogen atom, and a and b is respectively an integer from 0-4, and n is an integer from 1-500.
Abstract translation: 目的：提供聚膦酸盐以不使用封端剂显着降低酸值，并且能够提供具有优异的阻燃性和耐热性并且不降解其它物理性能的阻燃热塑性树脂组合物。 构成：聚膦酸盐在化学式1中，酸值为5.5KOHmg / g以下。 在化学式1中，A是单键，C1-5亚烷基，C1-5亚烷基，C5-6亚环烷基，-S-或-SO2-，R是取代或未取代的C6-20芳基或C6- 20取代或未取代的芳氧基，R 1和R 2分别独立地为取代或未取代的C 1-6烷基，取代或未取代的C 3-6环烷基，取代或未取代的C 6-12芳基或卤素原子， b分别为0-4的整数，n为1-500的整数。
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公开(公告)号：KR101156089B1
公开(公告)日：2012-06-20
申请号：KR1020080135464
申请日：2008-12-29
Applicant: 제일모직주식회사
IPC: C09K21/12
Abstract: 본 발명에 따른 하기 화학식 1로 표시되는 새로운 구조의 디페녹시포스포릴계 난연제를 제공한다. 상기 난연제를 열가소성 수지 조성물에 적용할 경우, 친환경적이며, 우수한 난연성 뿐만 아니라, 개선된 유동성을 부여할 수 있어 가공 시에 잇점이 있다:
[화학식 1]
(상기 식에서, R
1
및 R
2 는 각각 독립적으로 H, C
1 -C
6 알킬기이고, n은 0～5의 정수이며, R3는 수소, C
1 -C
6 알킬기 또는 페닐기이고, R4는 수소, 메틸기 또는 페닐기임)
디페녹시포스포릴 난연제, 스티렌계 수지, 폴리페닐렌 에테르 수지, 인계 화합물-
公开(公告)号：KR101150816B1
公开(公告)日：2012-06-13
申请号：KR1020090029478
申请日：2009-04-06
Applicant: 제일모직주식회사
Abstract: 본 발명은 하기 화학식 1로 표시되는 난연 및 충격 개선제를 제공한다. 상기 난연 및 충격 개선제는 열가소성 수지의 난연성과 충격강도를 향상시킬 뿐만 아니라, 우수한 내열성, 유동성의 물성발란스를 얻을 수 있다. 본 발명에서는 상기 하기 화학식 1로 표시되는 난연 및 충격 개선제의 새로운 제조방법과 이를 이용한 열가소성 수지 조성물을 제공한다:
[화학식 1]
스티렌계 수지, 폴리페닐렌에테르, 2,4-디터셔리부틸페닐 디페닐포스페이트, 인계 화합물, 난연성
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