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1.发明申请중합형 인계 화합물을 포함하는 열가소성 수지 조성물, 상기 조성물로부터 성형된 플라스틱 성형품 및 중합형 인계 화합물의 제조방법 审中-公开包含聚合磷化合物的热塑性树脂组合物，由组合物制成的塑料成型部分，以及制造聚合磷化合物的方法
公开(公告)号：WO2011081287A2
公开(公告)日：2011-07-07
申请号：PCT/KR2010/007245
申请日：2010-10-21
CPC classification number: C08G79/04 , C08L51/04 , C08L55/02 , C08L69/00 , C08L85/02 , C08L2201/02 , C09K21/14 , C08L2666/02
Abstract: 본 발명은 폴리카보네이트계 수지(A)를 30∼100 중량% 포함하는 기초수지 100 중량부; 및 중합형 인계 화합물(C) 0.1∼40 중량부를 포함하여 이루어지는 것을 특징으로 하는 난연성이 우수한 열가소성 수지 조성물을 제공한다. 상기 열가소성 수지 조성물은 중합형 난연제인 인계 화합물을 난연제로 적용하여 우수한 난연성을 가지면서도, 충격강도, 내열도, 유동성 등의 물성 발란스가 뛰어나며, 친환경적이다.
Abstract translation: 本发明涉及具有良好阻燃性的热塑性树脂组合物，其包含：100重量％的包含30至100重量％的聚碳酸酯基树脂（A）的基础树脂; 和0.1〜40重量％的聚合磷化合物（C）。 应用磷化合物（即，聚合阻燃材料）作为阻燃材料的热塑性树脂组合物具有良好的阻燃性，并且包括耐冲击性，耐热性，流动性等在内的物理性能的优异平衡是 也环保。
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2.发明申请
公开(公告)号：WO2013085097A1
公开(公告)日：2013-06-13
申请号：PCT/KR2011/010325
申请日：2011-12-29
Abstract: 본 발명은 터셔리부틸기(tertiary butyl group)에 오쏘(ortho) 위치에 치환된 페닐기, 및 비페놀(biphenol) 링커(linker)를 포함하여 고온에서의 내가수분해성 및 내열성이 우수한 인계 화합물, 이의 제조방법, 및 이를 포함하는 난연성 열가소성 수지 조성물에 관한 것이다.
Abstract translation: 本发明涉及：包含在邻位被苯基取代的叔丁基和双酚接头的磷基化合物，并且在高温下具有优异的耐水解性和耐热性; 其制备方法 和含有该阻燃剂的热塑性树脂组合物。
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公开(公告)号：KR101611002B1
公开(公告)日：2016-04-08
申请号：KR1020130065013
申请日：2013-06-05
Applicant: 제일모직주식회사
Abstract: 본발명의난연성폴리아미드계수지조성물은난연성이우수하고결정성저하를방지할수 있는것으로서, 폴리아미드계수지; 충진제; 난연제; 및폴리페닐렌설파이드계수지를포함하며, 상기난연제는하기화학식 1로표시되는단위를포함하는중합체를포함하는것을특징으로한다: [화학식 1]상기화학식 1에서, A 및 B는각각독립적으로단일결합, C1-C5의알킬렌기, C1-C5의알킬리덴기, C5-C6의시클로알킬리덴기, -S- 또는 -SO-이고, 단, A 및 B는서로동일하지않으며, R 및 R는각각독립적으로치환또는비치환된 C1-C6의알킬기, 치환또는비치환된 C6-C20의아릴기, 또는 C6-C20의치환또는비치환된아릴옥시기이고, R, R, R및 R는각각독립적으로치환또는비치환된 C1-C6의알킬기, 치환또는비치환된 C3-C6의시클로알킬기, 치환또는비치환된 C6-C12의아릴기또는할로겐원자이며, a, b, c 및 d는각각독립적으로 0 내지 4의정수이고, m은 0 내지 500의정수이며, n은 1 내지 500의정수이다.
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公开(公告)号：KR101489956B1
公开(公告)日：2015-02-06
申请号：KR1020110147917
申请日：2011-12-30
Applicant: 제일모직주식회사
Abstract: 본 발명의 난연성 열가소성 수지 조성물은 방향족 비닐계 수지 및 폴리페닐렌 옥사이드 수지를 포함하는 기초수지 100 중량부; 및 하기 화학식 1로 표시되는 폴리포스포네이트 공중합체 0.1 내지 30 중량부를 포함한다:
[화학식 1]
(상기 식에서, A 및 B는 각각 독립적으로 단일 결합, C
1 -C
5 의 알킬렌, C
1 -C
5 의 알킬리덴, C
5 -C
6 의 시클로알킬리덴, -S- 또는 -SO2-이고, 단, A 및 B는 서로 동일하지 않으며, R5 및 R6은 각각 독립적으로 치환 또는 비치환된 C
1 -C
6 알킬기, 치환 또는 비치환된 C
6 -C
20 인 아릴기 또는 C
6 -C
20 인 치환 또는 비치환된 아릴옥시기이고, R1, R2, R3 및 R4는 각각 독립적으로 치환 또는 비치환된 C
1 -C
6 알킬기, 치환 또는 비치환된 C
3 -C
6 사이클로알킬기, 치환 또는 비치환된 C
6 -C
12 아릴기 또는 할로겐 원자이며, a 및 b는 각각 독립적으로 0 내지 4의 정수, n 및 m은 1 내지 500의 정수임).-
公开(公告)号：KR1020130129791A
公开(公告)日：2013-11-29
申请号：KR1020120053916
申请日：2012-05-21
Applicant: 제일모직주식회사
IPC: C08G77/04 , C08G77/448 , C08L83/04 , C08L83/10
CPC classification number: C08G77/16 , C08G77/448 , C08L83/10
Abstract: Polysiloxane of the present invention is represented by chemical formula 1. In chemical formula 1, each of R1 and R2 is independently a C1-C10 alkyl group, C6-C18 aryl group, or halogen or alkoxy-containing C1-C10 alkyl group or C6-C18 aryl group; each of A and B is independently substituted or unsubstituted C2-C20 hydrocarbon group, or -O- or -S- containing substituted or unsubstituted C2-C20 hydrocarbon group; Z is substituted or unsubstituted C1-C24 hydrocarbon group or substituted or unsubstituted C1-C24 hydrocarbon group containing ester bond, urethane bond, or a combination thereof; Y is independently hydrogen atom, halogen, C1-C18 halogenated alkyl group, cyano group (-CN), or ester group; and each of m and n is independently an integer from 4 to 100. The polysiloxane uses an end group with reduced electron density, thereby improving low temperature impact strength and yellowness index.
Abstract translation: 本发明的聚硅氧烷由化学式1表示。在化学式1中，R1和R2各自独立地为C1-C10烷基，C6-C18芳基或含卤素或含烷氧基的C1-C10烷基或C6 -C18芳基; A和B各自独立地为取代或未取代的C 2 -C 20烃基，或含-O-或-S-的取代或未取代的C 2 -C 20烃基; Z是取代或未取代的C 1 -C 24烃基或取代或未取代的含C 1 -C 24烃基的酯基，氨基甲酸酯键或其组合; Y独立地为氢原子，卤素，C1-C18卤代烷基，氰基（-CN）或酯基; m和n各自独立地为4〜100的整数。聚硅氧烷使用具有降低的电子密度的端基，从而改善低温冲击强度和黄度指数。
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Patent Agency Ranking
公开(公告)号：KR1020130078741A
公开(公告)日：2013-07-10
申请号：KR1020110147853
申请日：2011-12-30
Applicant: 제일모직주식회사
Abstract: PURPOSE: A flame retardant thermoplastic resin composition is provided to include a biphenyl polyphosphate, thereby improving flame retardancy, heat resistance, impact resistance, dispersity, and transparency. CONSTITUTION: A flame retardant thermoplastic resin composition includes 100.0 parts by weight of a base resin and 0.1-30 parts by weight of a biphenyl polyphosphate represented by chemical formula 2. The base resin includes 10-99 wt% of a polycarbonate resin and 1-90 wt% of a rubber-modified aromatic vinyl-based copolymer. The weight average molecular weight of the biphenyl polyphosphate is 1,000-50,000 g/mol. The rubber-modified aromatic vinyl-based copolymer is a polymer of a rubber polymer, an aromatic vinyl-based monomer, and a monomer copolymerizable with the aromatic vinyl-based monomer.
Abstract translation: 目的：提供阻燃热塑性树脂组合物以包含多磷酸联苯，从而改善阻燃性，耐热性，耐冲击性，分散性和透明性。 构成：阻燃热塑性树脂组合物包含100.0重量份的基础树脂和0.1-30重量份由化学式2表示的多磷酸联苯。基础树脂包括10-99重量％的聚碳酸酯树脂和1- 90重量％的橡胶改性芳族乙烯基类共聚物。 多磷酸联苯酯的重均分子量为1000-50,000g / mol。 橡胶改性的芳族乙烯基类共聚物是橡胶聚合物，芳族乙烯基类单体和可与芳族乙烯基类单体共聚的单体的聚合物。
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公开(公告)号：KR1020130078739A
公开(公告)日：2013-07-10
申请号：KR1020110147851
申请日：2011-12-30
Applicant: 제일모직주식회사
IPC: C08G79/04 , C08L85/02 , C08L101/00
Abstract: PURPOSE: A polyphosphate copolymer is provided to improve flame retardancy, transparency, thermal resistance, impact strength, heat resistance, impact strength, and the exterior appearance. CONSTITUTION: A polyphosphate copolymer includes a repeating unit represented by chemical formula 1. In chemical formula 1, A and B is a single bond, a C1-5 alkylene, a C1-5 alkylidene, a C5-6 cycloalkylidene, -S-, or -SO2-; R5 and R6 is a substituted or unsubstituted C1-6 alkyl group, a substituted or unsubstituted C6-20 aryl group, or a C6-20 substituted or unsubstituted aryloxy group; each of R1, R2, R3, and R4 is a substituted or unsubstituted C1-6 alkyl group, a substituted or unsubstituted C3-6 cycloalkyl group, a substituted or unsubstituted C6-12 aryl group, or halogen; each of a and b is an integer from 0-4; and each of n and m is an integer from 1-500.
Abstract translation: 目的：提供聚磷酸酯共聚物以改善阻燃性，透明性，耐热性，冲击强度，耐热性，冲击强度和外观。 构成：聚磷酸酯共聚物包括由化学式1表示的重复单元。在化学式1中，A和B是单键，C1-5亚烷基，C1-5亚烷基，C5-6亚环烷基，-S-， 或-SO 2 - ; R5和R6是取代或未取代的C1-6烷基，取代或未取代的C6-20芳基或C6-20取代或未取代的芳氧基; R 1，R 2，R 3和R 4各自为取代或未取代的C 1-6烷基，取代或未取代的C 3-6环烷基，取代或未取代的C 6-12芳基或卤素; a和b各自为0-4的整数; n和m各自为1-500的整数。
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公开(公告)号：KR1020130078604A
公开(公告)日：2013-07-10
申请号：KR1020110147629
申请日：2011-12-30
Applicant: 제일모직주식회사
Abstract: PURPOSE: A flame retardant thermoplastic resin composition is provided to have physical property balance including not only excellent fire retardant but also excellent transparency, heat resistance, impact strength, and appearance by including biphenyl polyphosphonate in which a biphenyl group is introduced as flame retardant. CONSTITUTION: A flame retardant thermoplastic resin composition comprises; a basic resin which includes an aromatic vinyl resin and polyphenylene oxide resin of 100.0 weight part; and biphenyl polyphosphate of 0.1-30 weight part which is indicated as a chemical formula. The R is hydrogen, a substitution or non-substitution C1-5 alkyl group, a substitution or non-substitution C2-5 alkenyl group, a substitution or non-substitution C5-6 cycloalkyl group, a substitution or non-substitution C5-6 cycloalkenyl group, a substitution or non-substitution C6-20 aryl group, or a substituted or non-substituted C6-20 aryloxy group. The R1 and the R2 are respectively a substitution or non-substitution C1-6 alkyl group, a substitution or the non-substitution C5-6 cycloalkyl group, a substitution or non-substitution C6-12 aryl group, or halogen. The a and b are respectively the fixed number of 0-4. The n is the fixed number of 4-500.
Abstract translation: 目的：提供一种阻燃热塑性树脂组合物，其具有不仅具有优异的阻燃性，而且还包括通过引入联苯基作为阻燃剂的联苯基聚膦酸酯，具有优异的透明性，耐热性，冲击强度和外观的物理性能平衡。 构成：阻燃热塑性树脂组合物包含： 包含100.0重量份的芳族乙烯基树脂和聚苯醚树脂的碱性树脂; 以及重量份为0.1-30重量份的联苯聚磷酸酯，以化学式表示。 R为氢，取代或未取代的C 1-5烷基，取代或未取代的C 2-5烯基，取代或未取代的C 5-6环烷基，取代或未取代的C 5-6 取代或未取代的C6-20芳基，或取代或未取代的C6-20芳氧基。 R1和R2分别为取代或非取代C1-6烷基，取代或非取代C5-6环烷基，取代或未取代的C6-12芳基或卤素。 a和b分别为0-4的固定数。 n是4-500的固定数。
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公开(公告)号：KR1020130077704A
公开(公告)日：2013-07-09
申请号：KR1020110146569
申请日：2011-12-29
Applicant: 제일모직주식회사
Abstract: PURPOSE: An ultra-high melt flow polycarbonate resin is provided to be able to remarkably improve the inherent mobility of polycarbonate resin without degrading the transparency or colors, and to be suitable to extrude a thin film light guide plate with a large size without changing the polymerization process. CONSTITUTION: An ultra-high melt flow polycarbonate resin includes 100.0 parts by weight of polycarbonate and 0.001-1 part by weight of phosphate-based polymer with a repeating unit of Chemical formula 1. In Chemical formula 1, A is a single bond, C1-5 alkylene, C1-5 alkylidene, C5-6 cycloalkylidene, -S- or -SO2-, R is substituted or non-substituted C6-20 aryl, R1 and R2 are substituted or non-substituted C1-6 alkyl, substituted or non-substituted C5-6 cycloalkyl, substituted or non-substituted C6-12 aryl or halogen, respectively, a and b are an integer of 0-4, independently, and n is an integer of 3-500.
Abstract translation: 目的：提供超高熔点流动性聚碳酸酯树脂，能够显着提高聚碳酸酯树脂的固有迁移率，而不降低透明度或颜色，适合于挤出大尺寸的薄膜导光板，而不会改变 聚合过程。 构成：超高熔融流动性聚碳酸酯树脂包括100.0重量份聚碳酸酯和0.001-1重量份具有化学式1重复单元的磷酸酯基聚合物。在化学式1中，A是单键，C1 -5亚烷基，C 1-5亚烷基，C 5-6亚环烷基，-S-或-SO 2 - ，R是取代或未取代的C 6-20芳基，R 1和R 2是取代或未取代的C 1-6烷基，取代或 未取代的C5-6环烷基，取代或未取代的C6-12芳基或卤素，a和b分别为0-4的整数，n为3-500的整数。
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公开(公告)号：KR1020120078586A
公开(公告)日：2012-07-10
申请号：KR1020110127937
申请日：2011-12-01
Applicant: 제일모직주식회사
CPC classification number: C09K21/14
Abstract: PURPOSE: A polyphosphonate is provided to able to provide a flame retardant thermoplastic resin composition having excellent flame retardance and thermal resistance without degrading other physical properties in case used as a flame retardant. CONSTITUTION: A polyphosphonate has acid value has acid value of 5.5 KOH mg/g or less. In chemical formula 1, A is a single bond, C1-C5 alkylene, C1-C5 alkylidene, C5-C6 cycloalkylidene, -S- or -SO2-, R is a substituted or unsubstituted C6-20 aryl group, or a substituted or unsubstituted aryloxy group, R1 and R2 is respectively a substituted or unsubstituted C1-6 alkyl group, a substituted or unsubstituted C3-6 cycloalkyl group, a substituted or unsubstituted C6-12 aryl group or a halogen atom, a and b is respectively and independently an integer from 0-4, and n is an integer from 1-500.
Abstract translation: 目的：提供聚膦酸盐以能够提供具有优异的阻燃性和耐热性的阻燃热塑性树脂组合物，而不会在用作阻燃剂的情况下降解其它物理性能。 构成：聚磷酸盐酸值的酸值为5.5KOHmg / g以下。 在化学式1中，A是单键，C1-C5亚烷基，C1-C5亚烷基，C5-C6亚环烷基，-S-或-SO2-，R是取代或未取代的C6-20芳基，或取代或未取代的 未取代的芳氧基，R1和R2分别为取代或未取代的C1-6烷基，取代或未取代的C3-6环烷基，取代或未取代的C6-12芳基或卤素原子，a和b分别独立地为 0-4的整数，n为1-500的整数。
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