Abstract:
The present invention relates to a high purity metal manufacturing method from metal scrap using a molten salt electrolytic refining method and an integrated ingot manufacturing device for salt distillation and, more specifically, to a method for manufacturing a master alloy by placing seed metal of a master alloy to be manufactured in cathode inside an electrolytic cell, placing a scrap or an alloy which an alloying element of the master alloy is a master element in anode, electrodepositioning in cathode through a molten salt electrolytic method, and dissolving the seed metal (cathode) of the master alloy, the alloying element (electrodeposition material), and the remaining salt co-electrodeposited in the electrodeposition material at once in an integrated ingot manufacturing device for salt distillation.
Abstract:
The present invention relates to a device capable of collecting high-purity tellurium powder in high demand as a thermoelectric material or a photoelectric material and a method for manufacturing tellurium powder and, more specifically, to a device for manufacturing a high-purity tellurium powder including a carrier gas inlet and a furnace capable of being partially heated and a technology capable of controlling the particle size of the high-purity tellurium powder by injecting carrier gas. The present invention can collect purer tellurium powder than the tellurium powder manufactured by an existing powder manufacturing method such as a ball-milling method, which manufactures the tellurium powder by mechanically grinding solid tellurium, and a method using atomization after melting; can manufacture nanopowder by controlling the temperature of a collecting tank; and can control the particle size of deposited powder. Especially, the present invention obtains excellent economic efficiency as the high-purity tellurium powder in 5N or higher class of metallurgical grade can be manufactured through a single step using a low-purity tellurium material of 2N metallurgical grade. Furthermore, the purity of the 5N-class tellurium and the nanopowder manufactured by the present method can be useful for improving thermoelectric and photoelectric properties in consideration of the utilization of the tellurium powder for a thermoelectric material or a photoelectric material.
Abstract:
PURPOSE: An electrolytic refining apparatus for specializing impurity control for removing salt and method for removing salt from nuclear reactor waste using the same are provided to recover the high purity electrodeposit by efficiently removing impurity, thereby being applied to the type of precious metal, such as rare metal, rare soil, and the like refined by fused-slat electrolysis method and being widely used in the industry. CONSTITUTION: An electrolytic refining apparatus for specializing impurity control for removing salt includes an electrolyzer (10), a positive electrode (30), a negative electrode (80), a constant potentiostat (90), a fluoride system molten salt electrolyte (20), and a liquid metal pool (60). The fluoride system molten salt electrolyte ensures the soundness of Zr electrodeposit. The liquid metal pool is positioned at the lower portion of fluoride system molten salt electrolyte. The liquid metal pool is for collecting a group of element which is more precious than Zr and which is not liquefied at the temperature of electrolyte among impurity elements separated by molten salt electrolytic refining method.
Abstract:
본 발명은 지르코늄 사염화물 및 금속환원제를 포함하는 자전연소합성 방법을 이용한 지르코늄 스폰지의 제조방법에 관한 것으로, 보다 상세하게 본 발명에 따른 지르코늄 스폰지 제조방법은 지르코늄 사염화물과 금속환원제의 혼합물로부터 자전연소합성반응을 통하여 지르코늄과 금속 환원제의 염화물이 혼합된 다공성의 펠렛으로 제조 할 수 있고, 이후 펠렛은 산 침출 공정을 통하여 반응 부산물인 금속염화물을 용액 내 해리 시킴으로서 지르코늄만 선택적으로 회수 할 수 있는 방법이다. 본 발명에 따른 지르코늄 스폰지 제조방법은 지속적인 열원이 공급이 요구되는 종래기술인 크롤공정과는 달리 초기 점화열 공급이후로는 반응열에 의하여 자발적으로 반응이 일어남에 따라 비용 절감적 측면이 뛰어난 기술이며, 제조된 지르코늄도 고순도를 지니는 지르코늄 스폰지를 제조 할 수 있어 기존공정을 대체 할 수 있는 효과가 있다.