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公开(公告)号：KR1020160109550A
公开(公告)日：2016-09-21
申请号：KR1020150034199
申请日：2015-03-12
Applicant: 한국세라믹기술원
IPC: H01G11/06
Abstract: 본발명은, 양극활물질을포함하는양극물질이표리면을관통하는복수의구멍을갖는집전체의일면또는양면에도포된구조를이루는양극을제조하는단계와, 음극활물질을포함하는음극물질이표리면을관통하는복수의구멍을갖는집전체의일면또는양면에도포된구조를이루는음극을제조하는단계와, 리튬염과리튬메탈이비수계용매에용해되어있는전해액을제조하는단계와, 상기양극, 상기음극, 그리고상기양극과상기음극사이에배치되고상기양극과상기음극의단락을방지하기위한분리막을금속캡내에배치하고, 상기양극와상기음극이함침되게상기전해액을주입한후 밀봉하여울트라커패시터를제조하는단계및 상기금속캡에전압을인가하여첫 충전과정을수행하는단계를포함하며, 상기첫 충전과정에서상기리튬메탈및 상기리튬염으로부터나온리튬이상기흑연의표면및 내부에도핑되는것을특징으로하는울트라커패시터의리튬이온도핑방법에관한것이다. 본발명에의하면, 별도의프리도핑단계없이첫 충전과정에서전해액내에미리용해되어있는리튬메탈에의해리튬을울트라커패시터(ultra capacitor)의음극에도핑할수 있고, 이를통해울트라커패시터의용량특성및 안정적인충방전특성을제공할수 있다.
Abstract translation: 本发明涉及一种用于超级电容器的锂离子掺杂方法。 本发明的锂离子掺杂方法包括：制造正极的步骤，所述正极具有将包含正极活性物质的正极材料施加到集电器的一侧或两侧，所述集电器包括穿过前端的多个孔 及其背面; 制造具有包括负极活性物质的负极材料的结构的负极的步骤，该负极材料包括穿过其前表面和后表面的多个孔的集电器的一侧或两侧; 制造其中锂盐和锂金属溶解在非水溶剂中的电解质的步骤; 通过在金属盖中配置隔膜来制造超级电容器的步骤，并且在将电解质注入到金属帽中之后密封电解质，以便用电解质浸渍正极和负极，其中隔板布置在正极 和负极，防止正极和负极之间的短路; 以及通过向金属帽施加电压来进行第一充电处理的步骤，其中从锂金属和锂盐获得的锂掺杂在石墨的表面和石墨的内部。 根据本发明，在第一充电过程中，锂可以通过预先溶解在电解质中的锂金属掺杂在超级电容器的负极中，而不需要预先掺杂工艺，从而提供改进的容量特性和稳定的电荷 /放电特性的超级电容器。
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公开(公告)号：KR1020160074296A
公开(公告)日：2016-06-28
申请号：KR1020140183463
申请日：2014-12-18
Applicant: 한국세라믹기술원
IPC: B29C70/34
CPC classification number: B29C70/34 , B29C70/342 , B29C70/345
Abstract: 본발명에따른하이브리드세라믹섬유강화복합재료제조방법에따르면, 현무암직물및 탄소직물을수지에함침하여현무암적층기재(prepreg) 및탄소적층기재를제조하고, 현무암적층기재및 탄소적층기재를 0° 내지 90°의일정한배향각도를이루도록배열하고다단으로적층하여세라믹섬유강화복합재료를제조하기때문에친환경적이고기계적특성이우수하며고기능성이면서도생산비가저렴한세라믹섬유강화복합재료를제조할수 있다. 또한, 본발명에따른하이브리드세라믹섬유강화복합재료는다단으로현무암적층기재및 탄소적층기재를적층하고, 적층시현무암적층기재에 0 내지 90°이하의각도를이루도록탄소적층기재를적층하여세라믹섬유강화복합재료를제조하기때문에, 생산비가고가인탄소직물의사용을줄이면서도내연성이우수할뿐만아니라인장강도, 굽힘강도및 굴곡탄성율이높아유연성소재를이용하는다양한분야에사용이가능하다.
Abstract translation: 根据本发明的混合陶瓷纤维增强复合材料的制造方法包括使用玄武岩纤维或碳纤维浸渍树脂，从而制备玄武岩预浸料坯或碳预浸料，单向形成玄武岩预浸料或碳预浸料 取向角为0-90°，并将预浸料彼此堆叠，制成环境友好，功能高，制造便宜的陶瓷纤维增强复合材料，具有优异的机械性能。 此外，由于本发明的混合陶瓷纤维增强复合材料具有多层堆叠的玄武岩预浸料坯和碳预浸料坯，并且碳预浸料坯以0〜90°的取向角相对于 玄武岩预浸料; 可以降低生产成本高的碳预浸料，同时保持优异的阻燃性，拉伸强度，弯曲强度和挠曲模量; 因此混合陶瓷纤维增强复合材料可以用于使用柔性材料的各种领域。
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公开(公告)号：KR101494622B1
公开(公告)日：2015-02-23
申请号：KR1020130051594
申请日：2013-05-08
Applicant: 한국세라믹기술원
CPC classification number: Y02E60/13
Abstract: 본 발명은, 전극활물질인 다공성 활성탄 분말과, 상기 다공성 활성탄 분말 100중량부에 대하여 도전재 0.1∼20중량부와, 상기 다공성 활성탄 분말 100중량부에 대하여 불소 함유 바인더 1∼20중량부와, 상기 다공성 활성탄 분말 100중량부에 대하여 전도성 고분자 0.01∼10중량부 및 상기 다공성 활성탄 분말 100중량부에 대하여 분산매 100∼300중량부를 포함하는 슈퍼커패시터 전극용 조성물 및 이를 이용한 슈퍼커패시터 전극의 제조방법에 관한 것이다. 본 발명에 의하면, 성형성이 우수하여 성형시간의 단축이 가능하고, 내구성, 전극 밀도 및 전극의 유연성을 높일 수 있으며, 에너지 밀도가 높아 고용량 특성을 발현할 수 있다.
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公开(公告)号：KR101409178B1
公开(公告)日：2014-07-02
申请号：KR1020130045115
申请日：2013-04-24
Applicant: 한국세라믹기술원
Abstract: Provided is a composition for a supercapacitor electrode comprising: porous activated carbon powder; 2 to 20 parts by weight of a conductor per 100 parts by weight of the porous activated carbon powder; 2 to 20 parts by weight of a fluorine containing binder per 100 parts by weight of the porous activated carbon powder; 0.01 to 10 parts by weight of an alkaline organic compound per 100 parts by weight of the porous activated carbon powder; and 100 to 300 parts by weight of a dispersion medium per 100 parts by weight of the porous activated carbon powder; wherein the alkaline organic compound includes one or more elements selected from N, O, and S having lone pair electrons. Also, provided is a method for manufacturing a supercapacitor electrode using the composition. According to the present invention, binding of an electrode of the supercapacitor can be improved by using the alkaline organic compound to improve the binding. Thus, exfoliation or separation of an electrode active material can be suppressed and performance degradation of the supercapacitor can be prevented.
Abstract translation: 提供一种用于超级电容器电极的组合物，其包括：多孔活性炭粉末; 每100重量份多孔活性炭粉末2至20重量份导体; 相对于100重量份多孔活性炭粉末为2〜20重量份的含氟粘合剂; 0.01〜10重量份的碱性有机化合物/ 100重量份多孔活性炭粉末; 相对于100重量份多孔活性炭粉末为100〜300重量份的分散介质; 其中所述碱性有机化合物包括选自具有孤对电子的N，O和S的一种或多种元素。 此外，提供了使用该组合物制造超级电容器电极的方法。 根据本发明，通过使用碱性有机化合物来改善结合，可以提高超级电容器的电极的结合。 因此，可以抑制电极活性物质的剥离或分离，并且可以防止超级电容器的性能劣化。
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公开(公告)号：KR101375611B1
公开(公告)日：2014-03-18
申请号：KR1020120028276
申请日：2012-03-20
Applicant: 한국세라믹기술원
IPC: H01M4/485 , H01M4/1391 , C01G23/04
Abstract: 본 발명은, 구형 구조의 입자를 가지며, 상기 입자의 표면 및 벌크에 1∼200㎚의 직경을 갖는 복수의 기공들이 분포되어 다공성을 나타내고, 상기 입자의 평균 입경이 0.5∼10㎛이며, 충전 또는 방전 동작에 따라 상기 복수의 기공들을 통해 상기 입자의 표면 및 벌크 모두에서 이온의 삽입 또는 탈리가 가능한 Li
4 Ti
5 O
12 음극 활물질의 제조방법에 관한 것이다. 본 발명에 의하면, 입자의 표면 및 벌크에 1∼200㎚의 직경을 갖는 복수의 기공들이 분포되어 다공성을 나타내므로 충전 또는 방전 동작에 따라 상기 복수의 기공들을 통해 상기 입자의 표면 및 벌크 모두에서 이온의 삽입 또는 탈리가 가능하고, 0.5∼10㎛ 크기를 갖는 균일한 구형 입자를 가짐으로써 종래의 Li
4 Ti
5 O
12 음극 활물질보다 탭 밀도(겉보기밀도)가 향상되고 음극 제조시에 바인더의 절대 사용량을 감소시킬 수 있으며, 전지에 사용될 경우 다공성 구조로 인하여 전해액과의 반응 활성 사이트를 극대화하여 출력밀도를 개선할 수 있다.-
Patent Agency Ranking
公开(公告)号：KR1020130117985A
公开(公告)日：2013-10-29
申请号：KR1020120040784
申请日：2012-04-19
IPC: H01M4/13
Abstract: PURPOSE: A positive electrode for a lithium primary battery improves medium to high rate discharging capacity, improves energy density, and minimizes the capacity deviation of discharging in the positive electrode. CONSTITUTION: A positive electrode for a lithium primary battery has a positive electrode sheet, a conductive coating film, a current collector, a conductive coating film, and a positive electrode sheet which are laminated in order. The positive electrode sheet contains a conductive positive active material. The positive electrode sheet has a rolled sheet type shape with a thickness of 100 micron - 2 mm. The current collector has a net structure including a plurality of first frames arranged in a first direction and a plurality of second frames in a second direction. The positive active material includes acetylene black or the mixture of acetylene black and ketchen black.
Abstract translation: 目的：用于锂一次电池的正极可提高中高容量放电容量，提高能量密度，并最大限度地减少正极放电的容量偏差。 构成：锂一次电池用正极具有依次层叠的正极片，导电性涂膜，集电体，导电性涂膜，正极片等。 正极片包含导电正极活性物质。 正极片具有厚度为100微米-2mm的轧制片型。 集电器具有包括沿第一方向布置的多个第一框架和第二方向上的多个第二框架的网状结构。 正极活性物质包括乙炔黑或乙炔黑和ketchen黑色的混合物。
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37.发明授权전사법을 이용한 ＳＯＦＣ 단전지의 동시소성용 전사지 제조방법 및 이의 제조방법에 의해 제조된 ＳＯＦＣ 단전지의 동시소성용 전사지, 연료극(Ａｎｏｄｅ) 지지체형 ＳＯＦＣ 단전지의 제조방법 및 이의 제조방법에 의해 제조된 연료극(Ａｎｏｄｅ) 지지체형 ＳＯＦＣ 단전지 有权SOFC单电池使用可转换制造方法和由SOFC单元的分解可编程的转印纸的制备方法，阳极支持的SOFC单体体系制造方法及其制造方法由制造阳极支持的SOFC单元体
公开(公告)号：KR101322858B1
公开(公告)日：2013-10-29
申请号：KR1020120047041
申请日：2012-05-03
Applicant: 한국세라믹기술원
Abstract: PURPOSE: A manufacturing method of a transfer paper is provided to offer the transfer paper which is capable of coating regardless of the shape or size of an anode supporter even a bent and controlling the thickness of coating. CONSTITUTION: A manufacturing method of a transfer paper comprises the following steps: printing the anode functional layer paste on the surface of the transfer paper using a screen printing equipment; manufacturing an anode functional layer transfer paper by drying the transfer paper in which the anode functional layer paste is printed at 20-40°C; transferring the electrolyte paste on the anode functional layer transfer paper using the screen printing equipment; and manufacturing a transfer paper for co-firing of the anode functional layer and the electrolyte by drying the anode functional layer transfer paper to which the electrolyte paste is transferred. [Reference numerals] (AA) Electrolyte surface SEM images; (BB) Cathode surface SEM images; (CC) End cell cross section SEM images
Abstract translation: 目的：提供转印纸的制造方法，即使弯曲并且控制涂层的厚度，也能提供能够涂覆阳离子支撑体的形状或尺寸的转印纸。 构成：转印纸的制造方法包括以下步骤：使用丝网印刷设备将阳极功能层浆料印刷在转印纸的表面上; 通过干燥在20-40℃下印刷阳极功能层浆料的转印纸来制造阳极功能层转印纸; 使用丝网印刷设备将电解质浆料转移到阳极功能层转印纸上; 并通过干燥转印有电解质浆料的阳极功能层转印纸来制造用于共烧阳极功能层和电解质的转印纸。 （标号）（AA）电解质表面SEM图像; （BB）阴极表面SEM图像; （CC）末端细胞横截面SEM图像
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公开(公告)号：KR1020130116455A
公开(公告)日：2013-10-24
申请号：KR1020120031543
申请日：2012-03-28
Abstract: PURPOSE: An activated carbon-transition metal oxide composite electrode active material and a manufacturing method thereof have a super capacitor electrode with high specific capacitance and energy density by using an activated carbon-transition metal oxide composite active material as an anode or a cathode. CONSTITUTION: Porous activated carbon powder having multiple porous is prepared. The porous activated carbon powder is oxidized by being precipitated in an acid solution. The acid solution with the oxidized porous activated carbon powder is added in a transition metal oxide precursor solution. A deposit is obtained by titrating an alkali compound in the transition metal oxide precursor solution with the porous activated carbon powder. A material that a transition metal hydroxide and the porous activated carbon are compounded is obtained by selectively separating the deposit. A nanocomposite is obtained by thermally processing the material that the transition metal hydroxide and the porous activated carbon are compounded under oxidizing atmosphere.
Abstract translation: 目的：一种活性炭 - 过渡金属氧化物复合电极活性材料及其制造方法，通过使用活性炭 - 过渡金属氧化物复合活性材料作为阳极或阴极，具有高电容和能量密度的超级电容器电极。 构成：制备多孔多孔活性炭粉末。 多孔活性炭粉末通过在酸性溶液中沉淀而被氧化。 将具有氧化的多孔活性炭粉末的酸溶液加入到过渡金属氧化物前体溶液中。 通过用多孔活性炭粉末滴定过渡金属氧化物前体溶液中的碱性化合物获得沉积物。 通过选择性地分离沉积物来获得过渡金属氢氧化物和多孔活性炭复合的材料。 通过在氧化气氛下热处理过渡金属氢氧化物和多孔活性炭的材料来获得纳米复合材料。
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公开(公告)号：KR1020130101664A
公开(公告)日：2013-09-16
申请号：KR1020120020296
申请日：2012-02-28
Abstract: PURPOSE: A super capacitor electrode and a manufacturing method thereof are provided to have high non-capacitance and high energy density using a nano complex material in which a transition metal hydroxide is compounded for porosity activated charcoal which provides a path in which a polyelectrolyte ion is inserted or discharged as an electrode active material of an anode or a cathode. CONSTITUTION: A coin type super capacitor is a metal cap (50) as a conductor in which super capacitor electrode is applied. The coin type super capacitor is a separation film (60) of a porous material for preventing insulation and short circuit between super capacitor electrodes. The coin type super capacitor is formed of a gasket (70) for preventing the leakage of an electrolyte and insulation and short circuit. The super capacitor electrode is securely fixed to the metal cap with an adhesive.
Abstract translation: 目的：提供一种超级电容器电极及其制造方法，其使用纳米复合材料具有高的非电容和高能量密度，其中过渡金属氢氧化物复合用于孔隙活性炭，其提供聚电解质离子为 作为阳极或阴极的电极活性物质插入或排出。 构成：硬币型超级电容器是作为施加超级电容器电极的导体的金属盖（50）。 硬币型超级电容器是用于防止超级电容器电极之间的绝缘和短路的多孔材料的分离膜（60）。 硬币型超级电容器由用于防止电解液泄漏和绝缘和短路的垫圈（70）形成。 超级电容器电极用粘合剂固定在金属盖上。
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公开(公告)号：KR1020130066766A
公开(公告)日：2013-06-21
申请号：KR1020110133407
申请日：2011-12-13
Applicant: 한국세라믹기술원
IPC: H01M4/58 , H01M4/1397 , C01B25/45 , H01M10/0525
CPC classification number: C01B25/45 , C01P2006/40 , H01M4/136 , H01M4/5825 , H01M10/0525 , Y02E60/122
Abstract: PURPOSE: LiFePO4 positive electrode active material for a lithium ion battery is provided to improve tap density(apparent density) and to reduce use amount of a binder when manufacturing a positive electrode for a lithium secondary battery. CONSTITUTION: An LiFePO4 positive electrode active material includes a spherical particle. A plurality of pores with a particle diameter of 2-300 nm are distributed on the surface of the particle or bulk, thereby having porosity. According to charging or discharging operation, the insertion or deintercalation of cations can be possible both on the surface of the particle and bulk. The spherical particle has a porosity of 1-50%, and the specific surface area thereof is 0.1-100 m^2/g.
Abstract translation: 目的：提供锂离子电池用LiFePO 4正极活性物质，以提高锂二次电池正极制造时的振实密度（表观密度），降低粘合剂的使用量。 构成：LiFePO 4正极活性物质包含球状粒子。 多个孔径为2-300nm的孔分布在颗粒或块体的表面上，从而具有多孔性。 根据充电或放电操作，阳离子的插入或脱嵌可以在颗粒表面和块体上进行。 球形颗粒的孔隙率为1-50％，比表面积为0.1-100m 2 / g。
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