Abstract:
PURPOSE: A manufacturing method of porous alumina is provided to have pseudoboehmite or boehmite structure which has fine and even particle distribution and big pore volume. CONSTITUTION: A manufacturing method of porous alumina comprises the following steps: concurrently inserting sodium aluminate solution and nitric acid or polyaluminumchloride(PAC) solution into a continuous flow mixture machine; forming hydrogel by instantaneous neutralization reaction of the sodium aluminate solution and nitric acid or polyaluminum chloride solution; converting the hydrogel into colloidal sol by staying the hydrogel in the mixture machine for 5-20 seconds; and manufacturing porous alumina having pseudoboehmite or boehmite structure by crystallizing the colloidalsole at 90-150 deg. Celsius in a hydrothermal synthesis reactor. [Reference numerals] (AA) Sodium aluminate solution + a PAC solution, or a sodium aluminate solution + a nitric acid solution; (BB) Hydrogel; (CC) Colloidal sol; (DD) Determination; (EE) Dispersion; (FF) Filtration, washing, drying; (GG) Porous alumina
Abstract:
PURPOSE: A spherical zeolite molding body and a manufacturing method thereof are provided to offer improved mechanical intensity with high shape density by forming pores inside the molding body. CONSTITUTION: A manufacturing method of a spherical zeolite molding body comprises the following steps of: manufacturing the spherical zeolite molding body by mixing colloidal silica aqueous solution with a compound in which zeolite powder and cellulose-based compound are included; separating the spherical zeolite molding body having a particle diameter of 0.50 ~ 3.35 mm; manufacturing the spherical molding body in which the cellulose-based compound is removed; reacting an alkali aqueous solution and a sodium aluminate aqueous solution with the spherical molding body; ion-exchanging the spherical molding body with the alkali metal salt or alkaline-earth metal salt; and sintering the ion-exchanged spherical molding body at a temperature of 350 ~ 650 °C.
Abstract:
A method for preparing spherical activated carbon granules is provided to improve the productivity of the spherical activated carbon granules, by rotating a mixture of pitch powder and carbon-based powder to form the spherical granules. Spherical activated carbon granules are prepared by using pitch as a starting source, and performing a rounding process, an oxidizing process, a carbonizing process, and an activating process. In the rounding process, spherical granules are formed by mixing pitch powder of no less than 120 mesh and carbon-based powder of no less than 200 mesh into each other and rotating the mixture while adding a water-soluble polymer solution into the mixture. Further, 60-90 wt.% of pitch powder is mixed with 10-40 wt.% of carbon powder.
Abstract:
The present invention relates to a porous metal oxide-carbon composite having an impregnated photoactive metal oxide, a manufacturing method thereof, and a photocatalyst including the same and, more specifically, to a porous metal oxide-carbon composite having titanium dioxide and a post-transition metal impregnated with carbon-based media. The metal oxide-carbon composite according to the present invention can exhibit excellent photocatalytic activities in the range of visible light (λ>=400 nm) as well as in the range of ultraviolet rays and facilitates separation and recovery thereof after use because the particle size thereof is on a scale of approximately hundreds of micrometers. Loss induced by collisions between particles in a fluid state can be prevented, thereby facilitating application of the metal oxide-carbon composite to a commercial process because one particle of the metal oxide-carbon composite can resist the strength of 5 to 15 kg-f/a unit. Besides, the metal oxide-carbon composite according to the present invention can be applied to various fields such as water treatment and air purification industry, thereby being capable of being applied to commercial processes using a photocatalyst because the metal oxide-carbon composite exhibits photocatalytic activities in a wide wavelength range. [Reference numerals] (AA) Comparative example 1; (BB) Example 1; (CC) Example 2; (DD) Example 3