公开(公告)号：US07425662B2

公开(公告)日：2008-09-16

申请号：US10509356

申请日：2003-03-28

Applicant: Jon E. Stanat ,  Georges M. K. Mathys ,  David Wayne Turner ,  Jane C. Cheng ,  Stephen W. Beadle ,  Cesar M. Cheng Guajardo ,  Roger Eijkhoudt ,  Allen D. Godwin ,  Ernest E. Green ,  Charles M. Yarbrough ,  Raphael Frans Caers ,  Carolyn B. Duncan ,  Ramzi Y. Saleh

Inventor： Jon E. Stanat ,  Georges M. K. Mathys ,  David Wayne Turner ,  Jane C. Cheng ,  Stephen W. Beadle ,  Cesar M. Cheng Guajardo ,  Roger Eijkhoudt ,  Allen D. Godwin ,  Ernest E. Green ,  Charles M. Yarbrough ,  Raphael Frans Caers ,  Carolyn B. Duncan ,  Ramzi Y. Saleh

IPC: C07C2/20

CPC classification number: C07C2/64 ,  C07C2/12 ,  C07C45/28 ,  C07C51/16 ,  C07C2529/70 ,  C08F10/00 ,  C08F210/10 ,  C10G50/00 ,  C10M129/68 ,  C10M129/95 ,  C10M2207/28 ,  C11D1/667 ,  C11D3/2093 ,  C07C15/107 ,  C08F4/12 ,  C08F4/18 ,  C08F2500/02

Abstract: A selectivated molecular sieve, e.g., ZSM-22 or ZSM-23, is used as olefin oligomerization catalyst to provide product, e.g., octenes and dodecenes from butene, having a low degree of branching and hindered double bonds.

Abstract translation: 使用选择性分子筛，例如ZSM-22或ZSM-23作为烯烃低聚催化剂，以提供具有低支化度和受阻双键的产物，例如丁烯中的辛烯和十二碳烯。

公开(公告)号：US06881806B2

公开(公告)日：2005-04-19

申请号：US10789122

申请日：2004-02-27

Applicant: Abhimanyu O. Patil ,  Nicholas V. Smith ,  Jose G. Santiesteban ,  Allen D. Godwin ,  Steven P. Rucker ,  Stephen Zushma

Inventor： Abhimanyu O. Patil ,  Nicholas V. Smith ,  Jose G. Santiesteban ,  Allen D. Godwin ,  Steven P. Rucker ,  Stephen Zushma

IPC: C08L73/00 ,  C08G61/00 ,  C08G67/02 ,  C08L27/06 ,  C08F4/28

CPC classification number: C08G67/02 ,  C08L27/06 ,  C08L73/00 ,  C08L2666/14

Abstract: The invention is related to a geminally disubstituted olefin-carbon monoxide-ethylene polymer. The invention is also related to a method for preparing geminally disubstituted olefin-carbon monoxide-ethylene polymers by reacting a geminally disubstituted olefin feed, a carbon monoxide feed and an ethylene feed under free radical polymerization conditions. The invention is further related to a geminally disubstituted olefin-carbon monoxide-ethylene-X polymer, where monomer X is a free radical polymerizable monomer. The invention is also directed to a method for preparing geminally disubstituted olefin-carbon monoxide-ethylene-X polymers by reacting a geminally disubstituted olefin feed, a carbon monoxide feed, an ethylene feed and a feed containing monomer X under free radical polymerization conditions. The polymers of the invention are useful as polyvinyl chloride plasticizers.

公开(公告)号：US08987499B2

公开(公告)日：2015-03-24

申请号：US13036154

申请日：2011-02-28

Applicant: Brady Compton ,  John Lyford, IV ,  Nicolaas A. De Munk ,  Aad Gerrit Oskam ,  Allen D. Godwin ,  Leendert Johannes Van Dop

Inventor： Brady Compton ,  John Lyford, IV ,  Nicolaas A. De Munk ,  Aad Gerrit Oskam ,  Allen D. Godwin ,  Leendert Johannes Van Dop

IPC: C07C67/08 ,  C07C67/56 ,  C08K5/10

CPC classification number: C07C67/56 ,  C07C2601/14 ,  C08K5/10 ,  Y02P20/582 ,  C07C69/44 ,  C07C69/80 ,  C07C69/78 ,  C07C69/76 ,  C07C69/60 ,  C07C69/75

Abstract: Compositions including a C6 to C13 phthalate ester containing titanium but in an amount less than 0.01 ppm by wt of titanium, prepared by titanium catalyzed esterification, and containing from 0.1 to 2.0 wt % of an antioxidant, are provided.

Abstract translation: 提供了包含通过钛催化酯化制备并含有0.1至2.0重量％抗氧化剂制备的含有钛但小于0.01重量ppm的钛的C6至C13邻苯二甲酸酯的组合物。

公开(公告)号：US08653184B2

公开(公告)日：2014-02-18

申请号：US13599625

申请日：2012-08-30

Applicant: Claudius P. Gosse ,  Thomas M. Larson ,  Pierre J. P. Legrand ,  Raphael F. Caers ,  Paul H. Daniels ,  Allen D. Godwin ,  Didier Naert

Inventor： Claudius P. Gosse ,  Thomas M. Larson ,  Pierre J. P. Legrand ,  Raphael F. Caers ,  Paul H. Daniels ,  Allen D. Godwin ,  Didier Naert

IPC: C08K5/12

CPC classification number: C08K5/12 ,  C08K3/22 ,  C08K3/26 ,  C08K3/36 ,  C08K5/0016 ,  C08K5/57 ,  C08L27/06

Abstract: Esters of cyclohexane polycarboxylic acids are used as plasticisers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticisers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticisers may also be included. The formulations and processes of making these formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials, toys, and food contact articles.

Abstract translation: 环己烷多元羧酸的酯用作聚氯乙烯的增塑剂，以使得能够使用较少聚氯乙烯获得具有相当机械性能的产品。 这些酯的使用还产生具有增加的紫外光稳定性，改进的低温性能，较低粘度和改进的加工性以及燃烧时减少的烟雾的配方。 当环己烷多元羧酸的酯可以作为粘度降低剂时，环己烷多羧酸的酯可以单独使用或与其它增塑剂混合使用。 还可以包括快速熔化增塑剂。 制备这些制剂的制剂和方法特别可用于生产从半刚性到高度柔性材料的一系列商品，并且在生产医疗材料，玩具和食品接触制品方面特别有用。

公开(公告)号：US08653172B2

公开(公告)日：2014-02-18

申请号：US13579672

申请日：2011-03-03

Applicant: Didier Naert ,  Allen D. Godwin

Inventor： Didier Naert ,  Allen D. Godwin

IPC: C08K5/11 ,  C08K5/12

CPC classification number: C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  H01B3/443 ,  C08L27/06

Abstract: Plasticizer blends of C10 to C14 dialkyl phthalates or C8 to C10 trimellitates and C11 to C14 dialkyl adipates are provided. The blends may be used in the manufacture of flexible PVC formulations, for example, as wire and cable coatings, having in several embodiments, good performance over a wide temperature range and are particularly useful for automotive cables.

Abstract translation: 提供了C10至C14邻苯二甲酸二烷基酯或C8至C10偏苯三酸酯和C 11至C 14二烷基己二酸酯的增塑剂共混物。 共混物可以用于制造柔性PVC制剂，例如作为电线和电缆涂层，在几个实施方案中，在宽的温度范围内具有良好的性能，并且对汽车电缆特别有用。

公开(公告)号：US08389625B2

公开(公告)日：2013-03-05

申请号：US12653742

申请日：2009-12-17

Applicant: Margaret May-Som Wu ,  Karla Schall Colle ,  Ramzi Yanni Saleh ,  Allen D. Godwin ,  Jon Edmond Randolph Stanat

Inventor： Margaret May-Som Wu ,  Karla Schall Colle ,  Ramzi Yanni Saleh ,  Allen D. Godwin ,  Jon Edmond Randolph Stanat

IPC: C08K5/09

CPC classification number: C07D317/36 ,  C08L21/00 ,  C10G3/44 ,  C10G3/48 ,  C10G29/205 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1092 ,  C10G2300/30 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/06 ,  C10G2400/10 ,  C10M107/10 ,  C10M2205/0285 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2270/00 ,  Y02P30/20

Abstract: This disclosure is directed to an integrated method for making synthetic hydrocarbon fluids, plasticizers and polar synthetic lubricant base stocks from a renewable feedstock. More particularly, the disclosure is directed to a metathesis reaction of natural oil or its derivative ester and ethylene in the presence of an effective amount of a metathesis catalyst to form linear alpha-olefins, internal olefins and reduced chain length triglycerides. The linear alpha-olefins and/or internal olefins are polymerized to produce synthetic hydrocarbon fluids in the presence of a suitable catalyst. The reduced chain length triglycerides are converted into polar synthetic lubricant base stocks or plasticizers by hydrogenation, isomerization, followed by hydrogenations, or by hydroisomerization processes. Alternatively, the reduced chain length triglycerides can also be epoxidized to form epoxidized triglyceride plasticizers, optionally followed by carbonation, to form carbonated triglyceride plasticizers.

Abstract translation: 本发明涉及从可再生原料制备合成烃流体，增塑剂和极性合成润滑剂基础油的综合方法。 更具体地，本公开涉及天然油或其衍生物酯和乙烯在有效量的复分解催化剂存在下的复分解反应，以形成线性α-烯烃，内烯烃和还原链长度甘油三酯。 在合适的催化剂存在下，将线性α-烯烃和/或内烯烃聚合以产生合成烃流体。 还原的链长度甘油三酯通过氢化，异构化，随后氢化或通过加氢异构化方法转化为极性合成润滑剂基础油料或增塑剂。 或者，还原链长度甘油三酯也可以被环氧化以形成环氧化甘油三酯增塑剂，任选地随后碳酸化形成碳酸化甘油三酯增塑剂。

公开(公告)号：US20110021680A1

公开(公告)日：2011-01-27

申请号：US12934294

申请日：2009-03-18

Applicant: Karla S. Colle ,  Phillippe Louis Buess ,  Eddy Theophile Van Driessche ,  Allen D. Godwin ,  Ramzi Yanni Saleh ,  Jon E.R. Stanat ,  Raphael Frans Caers

Inventor： Karla S. Colle ,  Phillippe Louis Buess ,  Eddy Theophile Van Driessche ,  Allen D. Godwin ,  Ramzi Yanni Saleh ,  Jon E.R. Stanat ,  Raphael Frans Caers

IPC: C08L91/00 ,  C07C69/66 ,  C07C69/76 ,  C07C69/34

CPC classification number: C08K5/11 ,  C07B41/12 ,  C07C45/50 ,  C07C51/235 ,  C07C67/08 ,  C07C69/30 ,  C08K5/0016 ,  C08K5/103 ,  C08K5/12 ,  C07C69/78 ,  C08L27/06 ,  C07C47/02

Abstract: Triglyceride and other polyol ester PVC plasticizers can be produced by recovery of branched C6 to C9 aldehydes from a hydroformylation product, optional hydrogenation to the alcohol, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, ethylene glycol, propylene glycol or mixtures thereof. The branched alkyl chains comprise at least 10% methyl branching. Special triglycerides are derived from branched aliphatic acids having alkyl chains with average carbon numbers from 6 to 9 and at least 10% methyl branching. These triglycerides are fast fusing plasticisers if before esterification with glycerol, an aryl acid is introduced together with the aliphatic acids.

Abstract translation: 甘油三酯和其它多元醇酯类PVC增塑剂可以通过从加氢甲酰化产物回收支链C6至C9醛，任选的氢化成醇，用氧气和/或空气氧化成酸，回收所得酸，并用甘油酯化 ，乙二醇，丙二醇或其混合物。 支链烷基链包含至少10％的甲基支链。 特别的甘油三酸酯衍生自具有平均碳数为6至9和至少10％甲基支链的烷基链的支链脂族酸。 如果在用甘油酯化之前，这些甘油三酯是快速熔化增塑剂，芳基酸与脂肪酸一起引入。

公开(公告)号：US20100305250A1

公开(公告)日：2010-12-02

申请号：US12742505

申请日：2008-10-23

Applicant: Karla S. Colle ,  Jon E.R. Stanat ,  Juan J. Reinoso ,  Allen D. Godwin

Inventor： Karla S. Colle ,  Jon E.R. Stanat ,  Juan J. Reinoso ,  Allen D. Godwin

IPC: C08K5/1539 ,  C08K5/12

CPC classification number: C08K5/0016 ,  C08K5/12 ,  C08L15/02

Abstract: C7-C12 secondary alcohol esters of cyclohexanecarboxylic acids are especially useful as plasticizers for PVC and other plasticizable polymers. In embodiments, these plasticizers are useful in plastisol formulations to help improved processability of flexiblePVC material. In other embodiments these same plasticizers can be used in blends with other plasticizers to improve processability. In preferred embodiments these same plasticizers can be used to prepare flexible PVC compounds with enhanced low temperature flexibility, low toxicity, and improved resistance to outdoor aging.

Abstract translation: 环己烷羧酸的C7-C12仲醇酯特别适用于PVC和其他可塑化聚合物的增塑剂。 在实施方案中，这些增塑剂可用于增塑溶胶配方以有助于改善柔性PVC材料的可加工性。 在其它实施方案中，这些相同的增塑剂可以与其它增塑剂混合使用以改善加工性能。 在优选实施方案中，这些相同的增塑剂可用于制备具有增强的低温柔韧性，低毒性和改善的耐室外老化性能的柔性PVC化合物。

公开(公告)号：US20100298477A1

公开(公告)日：2010-11-25

申请号：US12745959

申请日：2008-11-20

Applicant: Allen D. Godwin

Inventor： Allen D. Godwin

IPC: C08K5/10 ,  C09K3/00

CPC classification number: C08K5/10 ,  C08K2201/014 ,  C08L27/06

Abstract: Compositions based on slow fusing cyclohexanecarboxylic acid esters and at least one fast fusing plasticizer are useful as plasticizers for plasticizable polymers, particularly PVC.

Abstract translation: 基于慢融合环己烷羧酸酯和至少一种快速熔融增塑剂的组合物可用作可塑化聚合物，特别是PVC的增塑剂。

公开(公告)号：US20090291304A1

公开(公告)日：2009-11-26

申请号：US12511781

申请日：2009-07-29

Applicant: Claudius Gosse ,  Thomas Marshall Larson ,  Pierre Jean Paul Legrand ,  Raphael Frans Caers ,  Paul H. Daniels ,  Allen D. Godwin ,  Didier Naert

Inventor： Claudius Gosse ,  Thomas Marshall Larson ,  Pierre Jean Paul Legrand ,  Raphael Frans Caers ,  Paul H. Daniels ,  Allen D. Godwin ,  Didier Naert

IPC: B32B1/00 ,  C08K5/12

CPC classification number: C08K5/12 ,  C08K5/0016 ,  Y10T428/2933 ,  Y10T428/31797 ,  Y10T428/3192 ,  C08L27/06

Abstract: Esters of cyclohexane polycarboxylic acids are used as plasticisers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticisers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticisers may also be included. The formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials such as blood bags and tubing.

Abstract translation: 环己烷多元羧酸的酯用作聚氯乙烯的增塑剂，以使得能够使用较少聚氯乙烯获得具有相当机械性能的产品。 这些酯的使用还产生具有增加的紫外光稳定性，改进的低温性能，较低粘度和改进的加工性以及燃烧时减少的烟雾的配方。 当环己烷多元羧酸的酯可以作为粘度降低剂时，环己烷多羧酸的酯可以单独使用或与其它增塑剂混合使用。 还可以包括快速熔化增塑剂。 制剂特别可用于生产从半刚性到高度柔性材料的一系列商品，并且特别可用于生产诸如血袋和管材之类的医疗材料。