公开(公告)号：DE3921451A1

公开(公告)日：1991-01-03

申请号：DE3921451

申请日：1989-06-30

Applicant: BASF AG

Inventor： HELWIG REINHARD DR ,  HOCH HELMUT DR ,  EPPLE GERHARD DR

IPC: C07C1/32 ,  C09B1/467

Abstract: PCT No. PCT/EP90/01030 Sec. 371 Date Oct. 22, 1991 Sec. 102(e) Date Oct. 22, 1991 PCT Filed Jun. 27, 1990 PCT Pub. No. WO91/00317 PCT Pub. Date Jan. 10, 1991.Anthraquinone dyes I I (Ar = aryl, A = anthraquinonyl) are prepared by reacting a aryldihalotriazine II II (Hal = chlorine or bromine) with an aminoanthraquinone III A-NH2 in an N-C1-C4 -alkylpyrrolid-2-one or -piperid-2-one, N-di-C1-C4 -alkylacetamide or -propionamide or urea derivatives of the formula IV IV (R = identical or different alkyl groups of from 1 to 4 carbon atoms which can also be linked together to form a 5- or 6-membered ring containing the urea group) as solvent.

公开(公告)号：DE3811635A1

公开(公告)日：1989-10-26

申请号：DE3811635

申请日：1988-04-07

Applicant: BASF AG

Inventor： HOCH HELMUT DR ,  KILPPER GERHARD DR ,  MIEDERER PETER DR

IPC: C07C45/86 ,  C07C45/00 ,  C07C49/665 ,  C07C67/00

公开(公告)号：DE3731809A1

公开(公告)日：1989-03-30

申请号：DE3731809

申请日：1987-09-22

Applicant: BASF AG

Inventor： HELWIG REINHARD DR ,  HOCH HELMUT DR

IPC: C09B3/36

Abstract: A process for the preparation of bisalkoxy(iso)violanthrenediones involves alkylating the corresponding bishydroxyl compounds in an organic reaction medium with methyl benzoate as the reaction medium. The ester can easily be regenerated and is stable under the reaction conditions.

公开(公告)号：DE3705386A1

公开(公告)日：1988-09-01

申请号：DE3705386

申请日：1987-02-20

Applicant: BASF AG

Inventor： MICHAELIS EBERHARD DR ,  HOCH HELMUT DR

IPC: C09B5/62 ,  C09B5/24

公开(公告)号：DE3060649D1

公开(公告)日：1982-08-26

申请号：DE3060649

申请日：1980-05-27

Applicant: BASF AG

Inventor： HOCH HELMUT DR ,  HILLER HEINRICH DR

IPC: C09B3/06 ,  C09B3/10 ,  C09B5/28 ,  C09B5/40

Abstract: A vat dye obtained by heating a condensation product, which itself has been prepared by heating 3,9-di-(1-anthraquinonylamino)-benz[d,e]anthrone in an aluminum chloride/picoline or aluminum chloride/quinoline melt in the presence of sulfuryl chloride or thionyl chloride, in a melt of an alkali metal hydroxide in an alcohol or glycol or aqueous glycol. The dye gives deep clear brown dyeings having good fastness characteristics.

公开(公告)号：DE2213568A1

公开(公告)日：1973-09-27

申请号：DE2213568

申请日：1972-03-21

Applicant: BASF AG

Inventor： HOCH HELMUT DR ,  QUADBECK-SEEGER HANS-JUERGEN D

IPC: C07C205/22 ,  C07C79/26

Abstract: 3-Nitro-4-methylphenol (I) is produced in high purity and high yields by reacting p-cresol carbonate with HNO3, pptg. the resulting 3-nitro-4-methylphenyl carbonate by diluting with H2O at 85-100 degrees C, and saponifying the prodt. with aq. NH4OH at 65-80 degrees C. (I) is an inter. for dyes and herbicides.

公开(公告)号：DE19743434A1

公开(公告)日：1999-04-08

申请号：DE19743434

申请日：1997-10-01

Applicant: BASF AG

Inventor： LEITER HERBERT DR ,  HOCH HELMUT DR ,  HENSEL KURT ,  EGEL-HESS WOLFGANG DR

IPC: A01N41/04 ,  C08J3/03 ,  C08L61/10 ,  C09K5/10 ,  C11D1/06 ,  C11D1/44 ,  C11D1/65 ,  C11D3/33 ,  C11D3/37 ,  C11D3/48 ,  C08L61/18 ,  C08J3/02 ,  C09K5/00

Abstract: Aqueous formulations (I) contain: (a) 0.1-10, preferably 0.5-7 wt.% arylsulfonic acid-formaldehyde and/or phenol-formaldehyde condensate(s), (b) 0.1-10, preferably 0.5-7 wt.% nonionic and/or anionic surfactant(s) and (c) 0.1-10, preferably 0.5-7 wt.% organic chelant(s) and/or anionic polymeric dispersant(s) based on non-aromatic monomers.

公开(公告)号：DE4338487A1

公开(公告)日：1995-05-18

申请号：DE4338487

申请日：1993-11-11

Applicant: BASF AG

Inventor： BERGMANN UDO DR ,  HOCH HELMUT DR ,  KOHLHAUPT REINHOLD DR

IPC: C07D277/84 ,  C07C231/02 ,  C07C233/76 ,  C07C233/80 ,  C07D221/18 ,  C07C233/75 ,  C07C231/12 ,  C09B1/42 ,  C09B5/24 ,  C09B5/40

公开(公告)号：DE3876915D1

公开(公告)日：1993-02-04

申请号：DE3876915

申请日：1988-09-17

Applicant: BASF AG

Inventor： HELWIG REINHARD DR ,  HOCH HELMUT DR

IPC: C09B3/36

Abstract: Prodn. of bisalkoxy-(iso) -violanthrenediones of formula (IA) and (IB) (R = 1-4C alkyl) is carried out by alkylating the corresp. bishydroxy cpds. (II) (R = G) in an organic liq. medium (III) in the presence of alkali metal salts (IV) of weak acids and tert. aliphatic and/or opt. tert. aromatic amines (V) at 100-200 deg.C. The novelty is that (III) is methyl benzoate. Pref. the alkylating agent is dialkyl sulphate, alkyl o- and/or p-toluenesulphonate, alkyl benzenesulphonate and/or dialkyl methanephosphonate. Pref. (IV) is Na2CO2 and/or K2CO3.

公开(公告)号：DE3773811D1

公开(公告)日：1991-11-21

申请号：DE3773811

申请日：1987-09-09

Applicant: BASF AG

Inventor： HELWIG REINHARD DR ,  HOCH HELMUT DR

IPC: C09B3/22 ,  C09B3/30

Abstract: The dye C.I. Vat Blue 16 (C.I. No. 71200), is prepd. by alkylating 16,17-dihydroxy-violanthrene dione-5,10 in a tert. (cyclo)aliphatic amine as solvent, at 100-230 deg.C. Alkylation is pref. in tri-n-butylamine solvent, in presence of alkali metal salts of weak acids, using 2-chloroethyl o- or p-toluene sulphonate, 2-chloroethyl benzene sulphonate and/or 1,2-dibromoethane as alkylating agent.