公开(公告)号：PT0900782E

公开(公告)日：2002-07-31

申请号：PT98120701

申请日：1995-11-03

Applicant: BASF AG

Inventor： AUMUELLER ALEXANDER ,  TRAUTH HUBERT ,  HOLDERBAUM MARTIN ,  SPERLING KARIN ,  KRAUSE ALFRED ,  GUIDO VOIT DR

IPC: C07D211/14 ,  C07B63/04 ,  C07C253/30 ,  C07C255/19 ,  C07C255/23 ,  C07C255/30 ,  C07C255/41 ,  C07C255/42 ,  C07D211/46 ,  C08K5/315 ,  C08K5/3435 ,  C09D7/12 ,  C09K3/00 ,  C09K15/16 ,  C09K15/20

Abstract: 2-Cyanoacrylic esters (I) of alpha , omega -bis(4-hydroxy-2,2,6,6-tetramethylpiperid-1-yl)alkanes or (cyclo)aliphatic polyols of the given formula (I) are new. R , R = the radical of an iso- or heterocyclic ring system with at least one iso- or heteroaromatic ring and ≥ 1 of R and R is not H, n = 2-10, if n = 2, X = a gp. of formula (II), m = 2-8; if n = 3-10, X = the radical of an n-hydric 3-20C (cyclo)aliphatic polyol, opt. with 1 or 2 heteroatoms in the cycloaliphatic gp. and up to 8 non-adjacent O or S atoms or -NH- or 1-4C alkylimino gps. in the aliphatic chain. Also claimed are various materials stabilised against the action of light, O2 and heat with (I).

公开(公告)号：DE59607052D1

公开(公告)日：2001-07-12

申请号：DE59607052

申请日：1996-10-25

Applicant: BASF AG

Inventor： HOLDERBAUM MARTIN ,  AUMUELLER ALEXANDER ,  SPERLING KARIN ,  WESTENFELDER HORST ,  WUENSCH THOMAS

IPC: A61K8/00 ,  A61K8/40 ,  A61K8/92 ,  A61Q1/04 ,  A61Q17/04 ,  A61K7/42

Abstract: PCT No. PCT/EP96/04637 Sec. 371 Date Apr. 29, 1998 Sec. 102(e) Date Apr. 29, 1998 PCT Filed Oct. 25, 1996 PCT Pub. No. WO97/17054 PCT Pub. Date May 15, 1997A sunscreen-containing cosmetic formulation to protect the human epidermis from UV light in the range from 280 to 400 nm, which formulation includes a cosmetically suitable carrier, together with compounds which absorb in the UV-B region and as photostable UV-A filters effective amounts of compounds of the formula I as defined in the specification.

公开(公告)号：DE59508283D1

公开(公告)日：2000-06-08

申请号：DE59508283

申请日：1995-11-03

Applicant: BASF AG

Inventor： AUMUELLER ALEXANDER ,  HOLDERBAUM MARTIN ,  GOETZE WOLFGANG ,  KROCKENBERGER JUERGEN ,  TRAUTH HUBERT

IPC: C08K5/103 ,  A61K8/81 ,  A61Q17/04 ,  C08K5/10 ,  C08L69/00 ,  C08L75/04 ,  C08L101/00 ,  C09D5/32 ,  C09D7/12 ,  C09D175/00 ,  C09K15/06

Abstract: PCT No. PCT/EP95/04313 Sec. 371 Date May 12, 1997 Sec. 102(e) Date May 12, 1997 PCT Filed Nov. 3, 1995 PCT Pub. No. WO96/15184 PCT Pub. Date May 23, 1996The use of 3-arylacrylic esters I (I) where Ar is an aryl radical which can additionally carry substituents, R1 is the residue of an n-hydric aliphatic polyol having up to 20 carbon atoms, where the carbon chain can be interrupted by up to 9 non-adjacent oxygen atoms, or of an n-hydric cyclo-aliphatic polyol having 5 to 20 carbon atoms in which ring carbon atoms can also be replaced by non-adjacent oxygen atoms, R2 and R3 are hydrogen or C1-C4-alkyl, and n is a number from l to 10, as stabilizers, in particular against the action of light, for non-living organic material.

公开(公告)号：AU706868B2

公开(公告)日：1999-06-24

申请号：AU7491996

申请日：1996-10-25

Applicant: BASF AG

Inventor： HOLDERBAUM MARTIN ,  AUMULLER ALEXANDER ,  SPERLING KARIN ,  WESTENFELDER HORST ,  WUNSCH THOMAS

IPC: A61K8/00 ,  A61K8/40 ,  A61K8/92 ,  A61Q1/04 ,  A61Q17/04 ,  A61K7/42

Abstract: PCT No. PCT/EP96/04637 Sec. 371 Date Apr. 29, 1998 Sec. 102(e) Date Apr. 29, 1998 PCT Filed Oct. 25, 1996 PCT Pub. No. WO97/17054 PCT Pub. Date May 15, 1997A sunscreen-containing cosmetic formulation to protect the human epidermis from UV light in the range from 280 to 400 nm, which formulation includes a cosmetically suitable carrier, together with compounds which absorb in the UV-B region and as photostable UV-A filters effective amounts of compounds of the formula I as defined in the specification.

公开(公告)号：BG101460A

公开(公告)日：1998-08-31

申请号：BG10146097

申请日：1997-05-06

Applicant: BASF AG

Inventor： HOLDERBAUM MARTIN ,  AUMUELLER ALEXANDER ,  TRAUTH HUBERT ,  VOIT GUIDO ,  SPERLING KARIN ,  KRAUSE ALFRED

IPC: C07D211/14 ,  C07B63/04 ,  C07C253/30 ,  C07C255/19 ,  C07C255/23 ,  C07C255/30 ,  C07C255/41 ,  C07C255/42 ,  C07D211/46 ,  C08K5/315 ,  C08K5/3435 ,  C09D7/12 ,  C09K3/00 ,  C09K15/16 ,  C09K15/20

Abstract: The esters shall finds application as a device for protectionfrom light. They have the formulawhere R1 & R2 mean hydrogen or residue from iso- or heterocyclicring system having at least one iso- or heteroaromatic nucleuswhere at least one of the R1 or R2 residues should be differentfrom hydrogen, n has the value of 2 to 10, and X when n is 2 shallmean a residue with the formulawhere m has the value from 2 to 8, and X when n 2, shall meanresidue of n-valency aliphatic or cycloaliphatic polyol with 3 to20 carbon atoms. The cycloaliphatic polyol can also conatin 1 or 2heteroatoms and the aliphatic polyol can be broken by to 8nonadjacent oxygen atoms, sulphur atoms of C1-C4 alkylaminogroups.16 claims

公开(公告)号：TR199701451T1

公开(公告)日：1998-03-21

申请号：TR9701451

申请日：1996-05-24

Applicant: BASF AG

Inventor： HOLDERBAUM MARTIN ,  BECK KARL ,  AUMUELLER ALEXANDER ,  WITZEL TOM ,  VOIT GUIDO

IPC: C07C253/30 ,  C07C255/41

Abstract: PCT No. PCT/EP96/02238 Sec. 371 Date Dec. 1, 1997 Sec. 102(e) Date Dec. 1, 1997 PCT Filed May 24, 1996 PCT Pub. No. WO96/38409 PCT Pub. Date Dec. 5, 1996A process for preparing 2-cyano-3,3-diarylacrylic esters of the general formula I where R1 and R2 are hydrogen, C1-C12-alkyl groups, C-C12-alkoxy groups or di(C1-C4-alkyl)amino groups and R3 is a C4-C18-alkyl group which can be interrupted by ether-functional oxygen atoms, by reacting a benzophenone imine of the general formula II with a cyanoacetic ester of the general formula III wherein the reaction is carried out at from 20 to 60 DEG C. and, during this, the liberated ammonia is continuously removed from the reaction mixture with the aid of a stream of gas or by reducing the pressure to from 900 to 100 mbar.

公开(公告)号：ES2107810T3

公开(公告)日：1997-12-01

申请号：ES94905731

申请日：1994-01-29

Applicant: BASF AG

Inventor： HOLDERBAUM MARTIN ,  AUMUELLER ALEXANDER ,  TRAUTH HUBERT

IPC: C07F9/40 ,  C07F9/58 ,  C07F9/59 ,  C08K5/53 ,  C08K5/5353 ,  C08K5/5373 ,  C08K5/5393 ,  C09D7/12 ,  C09K15/32

Abstract: PCT No. PCT/EP94/00254 Sec. 371 Date Aug. 9, 1995 Sec. 102(e) Date Aug. 9, 1995 PCT Filed Jan. 29, 1994 PCT Pub. No. WO94/18210 PCT Pub. Date Aug. 18, 1994Aminovinylphosphonic esters I where R1 is cyano, a radical of the formula -CO-OR6 or a group of the formula R2, R3 and R6 are C1-C20-alkyl, C5-C8-cycloalkyl, C7-C18-aralkyl, phenyl or tolyl, R4 is an unsubstituted or substituted phenyl or heterocyclic group defined below R5 is hydrogen or C1-C12-alkyl, R7 is hydrogen, C1-C6-alkyl, formyl, C2-C6-alkanoyl, C1-C12-alkoxy, C5- or C6-cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula -CR8=CH-CO-OR6, R8 is hydrogen, C1-C6-alkyl or a radical of the formula -CO-OR6, and X is oxygen or NH, are used as light, oxygen and heat stabilizers for organic material.

公开(公告)号：BG101484A

公开(公告)日：1997-10-31

申请号：BG10148497

申请日：1997-05-14

Applicant: BASF AG

Inventor： AUMUELLER ALEXANDER ,  HOLDERBAUM MARTIN ,  GOETZE WOLFGANG ,  KROCKENBERGER JUERGEN ,  TRAUTH HUBERT

IPC: C08K5/103 ,  A61K8/81 ,  A61Q17/04 ,  C08K5/10 ,  C08L69/00 ,  C08L75/04 ,  C08L101/00 ,  C09D5/32 ,  C09D7/12 ,  C09D175/00 ,  C09K15/06

Abstract: The 3-arylacrylic acid esters are of formula in which Ar is an aryl group, which may carry additional substituents, R1 is an n-valency aliphatic polyol group with up to 20 C-atoms, whereby the carbon chain may be interrupted by up to 9 non-adjacent oxygen atoms, or an n-valency cycloaliphatic polyol group with 5 to 20 C-atoms in which non-adjacent ring carbon atoms may be replaced by oxygen atoms, R2 and R3 are hydrogen or C1-C4 alkyl and n is a number from 1 to 10. The compounds are applicable as protective means again light and stabilizers for non-living organic material.

公开(公告)号：AT158296T

公开(公告)日：1997-10-15

申请号：AT94905731

申请日：1994-01-29

Applicant: BASF AG

Inventor： HOLDERBAUM MARTIN ,  AUMUELLER ALEXANDER ,  TRAUTH HUBERT

IPC: C07F9/40 ,  C07F9/58 ,  C07F9/59 ,  C08K5/53 ,  C08K5/5353 ,  C08K5/5373 ,  C08K5/5393 ,  C09D7/12 ,  C09K15/32

Abstract: PCT No. PCT/EP94/00254 Sec. 371 Date Aug. 9, 1995 Sec. 102(e) Date Aug. 9, 1995 PCT Filed Jan. 29, 1994 PCT Pub. No. WO94/18210 PCT Pub. Date Aug. 18, 1994Aminovinylphosphonic esters I where R1 is cyano, a radical of the formula -CO-OR6 or a group of the formula R2, R3 and R6 are C1-C20-alkyl, C5-C8-cycloalkyl, C7-C18-aralkyl, phenyl or tolyl, R4 is an unsubstituted or substituted phenyl or heterocyclic group defined below R5 is hydrogen or C1-C12-alkyl, R7 is hydrogen, C1-C6-alkyl, formyl, C2-C6-alkanoyl, C1-C12-alkoxy, C5- or C6-cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula -CR8=CH-CO-OR6, R8 is hydrogen, C1-C6-alkyl or a radical of the formula -CO-OR6, and X is oxygen or NH, are used as light, oxygen and heat stabilizers for organic material.

公开(公告)号：BR9509644A

公开(公告)日：1997-09-16

申请号：BR9509644

申请日：1995-11-03

Applicant: BASF AG

Inventor： HOLDERBAUM MARTIN ,  AUMUELLER ALEXANDER ,  TRAUTH HUBERT ,  VOIT GUIDO ,  SPERLING KARIN ,  KRAUSE ALFRED

IPC: C07D211/14 ,  C07B63/04 ,  C07C253/30 ,  C07C255/19 ,  C07C255/23 ,  C07C255/30 ,  C07C255/41 ,  C07C255/42 ,  C07D211/46 ,  C08K5/315 ,  C08K5/3435 ,  C09D7/12 ,  C09K3/00 ,  C09K15/16 ,  C09K15/20

Abstract: 2-Cyanoacrylic esters (I) of alpha , omega -bis(4-hydroxy-2,2,6,6-tetramethylpiperid-1-yl)alkanes or (cyclo)aliphatic polyols of the given formula (I) are new. R , R = the radical of an iso- or heterocyclic ring system with at least one iso- or heteroaromatic ring and ≥ 1 of R and R is not H, n = 2-10, if n = 2, X = a gp. of formula (II), m = 2-8; if n = 3-10, X = the radical of an n-hydric 3-20C (cyclo)aliphatic polyol, opt. with 1 or 2 heteroatoms in the cycloaliphatic gp. and up to 8 non-adjacent O or S atoms or -NH- or 1-4C alkylimino gps. in the aliphatic chain. Also claimed are various materials stabilised against the action of light, O2 and heat with (I).