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公开(公告)号:ES2096831T3
公开(公告)日:1997-03-16
申请号:ES93116281
申请日:1993-10-08
Applicant: BASF AG
IPC: C08F265/04 , C08F265/06 , C08F279/02 , C08L51/00 , C08L51/04 , C08L101/00
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公开(公告)号:DE59107857D1
公开(公告)日:1996-07-04
申请号:DE59107857
申请日:1991-10-19
Applicant: BASF AG
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公开(公告)号:AT137521T
公开(公告)日:1996-05-15
申请号:AT93120855
申请日:1993-12-23
Applicant: BASF AG
Inventor: DECKERS ANDREAS DR , GUENTHERBERG NORBERT DR , NIESSNER NORBERT DR
Abstract: The present invention relates to moulding compositions based on polymethyl methacrylate, essentially containing A) from 99.99 to 95.0% by weight of a mixture essentially comprising a1) from 5 to 95% by weight of polymethyl methacrylate, obtainable by polymerisation of a mixture essentially comprising a11) from 80 to 100% by weight of methyl methacrylate and a12) from 0 to 20% by weight of a C1-C20-alkyl ester of acrylic acid, and a2) from 95 to 5% by weight of a multistep graft copolymer based on a C1-C20-alkyl ester of acrylic and/or methacrylic acid, and B) from 0.01 to 5.0% by weight of a polysiloxane of the formula I in which R is C1-C6-alkyl or C6-C10-aryl, R is hydroxy-C1-C6-alkyl or amino-C1-C6-alkyl, and n is a natural number from 5 to 200. d
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公开(公告)号:DE59400099D1
公开(公告)日:1996-03-14
申请号:DE59400099
申请日:1994-02-10
Applicant: BASF AG
Inventor: NIESSNER NORBERT DR
Abstract: Thermoplastic moulding compositions containing, as essential components, A) from 10 to 90 % by weight of an aromatic polycarbonate, B) from 5 to 50 % by weight of a thermoplastic polyurethane and C) from 5 to 40 % by weight of a copolymer comprising c1) from 70 to 85 % by weight of styrene or substituted styrenes of the formula I where R is an alkyl radical having 1 to 8 carbon atoms or a hydrogen atom and R is an alkyl radical having 1 to 8 carbon atoms, and n has the value 0, 1, 2 or 3, and c2) from 15 to 30 % by weight of (meth)acrylonitrile, (meth)acrylic acid, C1- to C8-alkyl (meth)acrylates, maleic anhydride, acrylamide, vinyl esters of C1-C6-carboxylic acids, maleimides which are substituted on the nitrogen atom by C1- to C8-alkyl or C6-C20-aryl groups, or mixtures thereof. o
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公开(公告)号:DE59204581D1
公开(公告)日:1996-01-18
申请号:DE59204581
申请日:1992-09-05
Applicant: BASF AG
Inventor: NIESSNER NORBERT DR , SEITZ FRIEDRICH DR
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公开(公告)号:ES2073609T3
公开(公告)日:1995-08-16
申请号:ES91104981
申请日:1991-03-28
Applicant: BASF AG
Inventor: SEITZ FRIEDRICH DR , RUPPMICH KARL , GUENTHERBERG NORBERT DR , NIESSNER NORBERT DR
IPC: C08F265/06 , C08F265/00 , C08F265/02 , C08F265/04 , C08F279/00 , C08F279/02 , C08L25/12 , C08L51/00 , C08L51/04 , C08L51/06
Abstract: A particulate graft polymer comprising A: from 30 to 80% by weight of at least one elastomeric polymer A having a mean particle size of from 30 to 1000 nm and made from - based on A - A1: from 85 to 99.8% by weight of at least one alkyl acrylate A1 having 1 to 8 carbon atoms in the alkyl radical, A2: from 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A2 and A3: from 0.1 to 10% by weight of at least one monomer A3 containing one or more acidic groups, or A11: up to 100% by weight of a diene A11, A12: up to 50% by weight of at least one vinyl aromatic monomer A12 A13: up to 10% by weight of at least one monomer A13 containing one or more acidic groups, as the graft base, and B: from 20 to 70% by weight of a graft shell B which is grafted on to the elastomeric polymer A and is made from - based on B - B1: from 50 to 89.9% by weight of at least one vinyl aromatic monomer B1, B2: from 10 to 49.9% by weight of at least one polar, copolymerisable, ethylenically unsaturated monomer B2 and B3: from 0.1 to 10% by weight of at least one monomer B3 containing one or more basic groups. i
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公开(公告)号:DE59105819D1
公开(公告)日:1995-08-03
申请号:DE59105819
申请日:1991-03-28
Applicant: BASF AG
Inventor: SEITZ FRIEDRICH DR , RUPPMICH KARL , GUENTHERBERG NORBERT DR , NIESSNER NORBERT DR
IPC: C08F265/06 , C08F265/00 , C08F265/02 , C08F265/04 , C08F279/00 , C08F279/02 , C08L25/12 , C08L51/00 , C08L51/04 , C08L51/06
Abstract: A particulate graft polymer comprising A: from 30 to 80% by weight of at least one elastomeric polymer A having a mean particle size of from 30 to 1000 nm and made from - based on A - A1: from 85 to 99.8% by weight of at least one alkyl acrylate A1 having 1 to 8 carbon atoms in the alkyl radical, A2: from 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A2 and A3: from 0.1 to 10% by weight of at least one monomer A3 containing one or more acidic groups, or A11: up to 100% by weight of a diene A11, A12: up to 50% by weight of at least one vinyl aromatic monomer A12 A13: up to 10% by weight of at least one monomer A13 containing one or more acidic groups, as the graft base, and B: from 20 to 70% by weight of a graft shell B which is grafted on to the elastomeric polymer A and is made from - based on B - B1: from 50 to 89.9% by weight of at least one vinyl aromatic monomer B1, B2: from 10 to 49.9% by weight of at least one polar, copolymerisable, ethylenically unsaturated monomer B2 and B3: from 0.1 to 10% by weight of at least one monomer B3 containing one or more basic groups. i
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公开(公告)号:DE4305637A1
公开(公告)日:1994-08-25
申请号:DE4305637
申请日:1993-02-24
Applicant: BASF AG
Inventor: NIESSNER NORBERT DR
Abstract: Thermoplastic moulding compositions containing, as essential components, A) from 10 to 90 % by weight of an aromatic polycarbonate, B) from 5 to 50 % by weight of a thermoplastic polyurethane and C) from 5 to 40 % by weight of a copolymer comprising c1) from 70 to 85 % by weight of styrene or substituted styrenes of the formula I where R is an alkyl radical having 1 to 8 carbon atoms or a hydrogen atom and R is an alkyl radical having 1 to 8 carbon atoms, and n has the value 0, 1, 2 or 3, and c2) from 15 to 30 % by weight of (meth)acrylonitrile, (meth)acrylic acid, C1- to C8-alkyl (meth)acrylates, maleic anhydride, acrylamide, vinyl esters of C1-C6-carboxylic acids, maleimides which are substituted on the nitrogen atom by C1- to C8-alkyl or C6-C20-aryl groups, or mixtures thereof. o
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公开(公告)号:DE4234296A1
公开(公告)日:1994-04-14
申请号:DE4234296
申请日:1992-10-12
Applicant: BASF AG
IPC: C08F265/04 , C08F265/06 , C08F279/02 , C08L51/00 , C08L51/04 , C08L101/00 , C08F291/02 , C08F265/02 , C08F291/06 , C08F291/12
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公开(公告)号:DE4223202A1
公开(公告)日:1994-01-20
申请号:DE4223202
申请日:1992-07-15
Applicant: BASF AG
Inventor: GUENTHERBERG NORBERT DR , FISCHER WOLFGANG DR , NIESSNER NORBERT DR
IPC: C08F285/00 , C08L51/00 , C08F279/02 , C08L51/04
Abstract: A particulate graft polymer A comprising A1: a graft base based on a polydiene rubber A1 comprising, based on A1, A11: from 70 to 100% by weight of a polymerisable diene and A12: up to 30% by weight of a copolymerisable, ethylenically unsaturated monomer, A2: with a first graft shell A2 comprising, based on A2, A21: from 75 to 99.8% by weight of at least one C1-C8-alkyl acrylate A21, A22: from 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A22, A23: from 0.1 to 20% by weight of at least one monomer A23 containing one or more acidic or basic groups, A3: and a second graft shell A3, comprising, based on A3, A31: from 40 to 89.9% by weight of at least one vinylaromatic monomer A31, A32: from 10 to 49.9% by weight of at least one polar, ethylenically unsaturated monomer A32, A33: from 0.1 to 20% by weight of at least one monomer A33 containing one or more basic or acidic groups, and A34: up to 5% by weight of at least one polyfunctional, crosslinking monomer A34, where A23 and A33 are different groups.h
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