PYRIDINE BORANE COMPLEXES
    31.
    发明专利

    公开(公告)号:CA2663677C

    公开(公告)日:2014-01-14

    申请号:CA2663677

    申请日:2007-09-20

    Applicant: BASF SE

    Abstract: The present invention relates to new borane complexes with substituted pyridines, a process for the synthesis of new borane complexes with substituted pyridines, solutions comprising new borane complexes with substituted pyridines and a method of using new borane complexes with substituted pyridines for organic reactions.

    Pyridine borane complexes
    32.
    发明专利

    公开(公告)号:AU2007298924B2

    公开(公告)日:2012-08-16

    申请号:AU2007298924

    申请日:2007-09-20

    Applicant: BASF SE

    Abstract: The present invention relates to new borane complexes with substituted pyridines, a process for the synthesis of new borane complexes with substituted pyridines, solutions comprising new borane complexes with substituted pyridines and a method of using new borane complexes with substituted pyridines for organic reactions.

    ACCELERATED REDUCTION OF ORGANIC SUBSTANCES WITH BORANES

    公开(公告)号:NZ584008A

    公开(公告)日:2011-11-25

    申请号:NZ58400808

    申请日:2008-09-18

    Applicant: BASF SE

    Abstract: A process for the accelerated reduction of organic ester substrates by reacting with an amine borane, sulfide borane or ether borane complex as a borane source in the presence of organic accelerator compounds containing both Lewis acidic and Lewis basic sites in their structure, of which the Lewis acidic site can coordinate with the carbonyl group of the substrate and the Lewis basic site can coordinate with the borane wherein the organic accelerator compound contains a structural element of the formula N-B or is an oxazaborolidine or cyclic compound containing a structural element of the formula N-B-O where N- and O- are connected by a carbon chain or is derived from secondary amino alcohol via reaction with boranes or borates and wherein the esters are reduced to give alcohols.

    Process for synthesis of dialkoxyorganoboranes

    公开(公告)号:AU2006259086B2

    公开(公告)日:2011-05-26

    申请号:AU2006259086

    申请日:2006-06-09

    Applicant: BASF SE

    Abstract: The invention relates to a process for the synthesis of organo-oxazaborolidines of the structural formula wherein R 4 to R 8 is hydrogen, C 1 -C 20 alkyl, C 6 -C 14 aryl, C 7 -C 24 aralkyl, C 7 -C 24 alkaryl, substituted C 1 -C 20 alkyl or the two groups R 4 and R 5 together are a divalent group selected from the group consisting of -CH 2 CH 2 -, -CH(CH 3 )CH 2 -, -CH 2 CH 2 CH 2 -, -CH(CH 3 )CH(CH 3 )-, -CH(CH 2 CH 3 )CH 2 -, -C(CH 3 ) 2 C(CH 3 ) 2 -, -CH 2 C(CH 3 )2CH2- to form with the -NH-CR 6 - moiety a cyclic structure.

    PROCEDIMIENTO PARA LA SINTESIS DE ORGANO-OXAZABOROLIDINAS.

    公开(公告)号:ES2357375T3

    公开(公告)日:2011-04-25

    申请号:ES09156309

    申请日:2006-06-09

    Applicant: BASF SE

    Abstract: Procedimiento para la preparación de órgano-oxazaborolidinas de la estructura general (6) que comprende las etapas de a) reaccionar un 1,2-aminoalcohol de fórmula (5) HNR 4 -CR 5 R 6 CR 7 R 8 -OH (5) en donde R 4 a R 8 es hidrógeno, alquilo C1-C20, arilo C6-C14, aralquilo C7-C24, alcarilo C7-C24, alquilo C1-C20 sustituido o los dos grupos R 4 y R 5 juntos son un grupo divalente seleccionado del grupo consistente en -CH2CH2-, -CH(CH3)CH2-, - CH2CH2CH2-, -CH(CH3)CH(CH3)-, -CH(CH2CH3)CH2-, -C(CH3)2C(CH3)2-, -CH2C(CH3)2CH2- para formar con la mitad - NH-CR 6 una estructura cíclica, con un dialcoxiorganoborano (3) de fórmula R 1 -B(OR 2 )2 en donde R 1 es alquilo C1-C20, cicloalquilo C3-C10, arilo C6-C14, aralquilo C7-C24, alcarilo C7-C24, alquenilo C2-C20, cicloalquenilo C5-C15, alquinilo C2-C20, CH2SiMe3, alquilo C1-C20 sustituido y R 2 es alquilo C1-C20, o los dos grupos R 2 en el compuesto (3) junto con la mitad -BO2- forman una estructura cíclica de fórmula con el grupo divalente R 3 seleccionado del grupo consistente en -CH2CH2-, -CH(CH3)CH2-, -CH2CH2CH2-, - CH(CH3)CH(CH3)-, -CH(CH2CH3)CH2-, C(CH3)2C(CH3)2-, -CH2C(CH3)2CH2-, -(CH2)6-, orto-C6H4 u orto-C6H3 alquilo y b) calentar la mezcla de reacción para completar la reacción de cierre de anillo y separar por destilación el alcohol formado.

    PYRIDINE BORANE COMPLEXES
    38.
    发明专利

    公开(公告)号:NZ575485A

    公开(公告)日:2010-11-26

    申请号:NZ57548507

    申请日:2007-09-20

    Applicant: BASF SE

    Abstract: Disclosed are borane complexes with substituted pyridines having the formula (1), wherein R1 and R2 represent independently from each other C1-C8-alkyl, C1-C8-alkoxy, C1-C8-alkoxy-C1-C8-alkyl or halogen, and a process for their synthesis. The complexes are useful as reagents in organic reactions.

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