公开(公告)号：EP2225192A2

公开(公告)日：2010-09-08

申请号：EP08854428.3

申请日：2008-11-13

Applicant: BASF SE

Inventor： HEYDRICH, Gunnar ,  GRALLA, Gabriele ,  RAULS, Matthias ,  SCHMIDT-LEITHOFF, Joachim ,  EBEL, Klaus ,  KRAUSE, Wolfgang ,  OEHLENSCHLÄGER, Steffen ,  JÄKEL, Christoph ,  FRIEDRICH, Marko ,  BERGNER, Eike Johannes ,  KASHANI-SHIRAZI, Nawid ,  PACIELLO, Rocco

IPC: C07C29/17

CPC classification number: C07C29/56 ,  C07B2200/07 ,  C07C29/172 ,  C07C29/78 ,  C07C45/62 ,  C07C45/82 ,  C07C2601/14 ,  C07C2601/16 ,  C07C47/21 ,  C07C35/12 ,  C07C35/17

Abstract: The invention relates to a particularly economic, complete method for producing menthol, especially for the production of optically active, essentially enantiomerically and diastereomerically pure L-menthol and of racemic menthol starting from the commercially accessible, inexpensive parent material citral. The method comprises the following steps: a.1 ) catalytic hydrogenation of neral and/or geranial to form citronellal, b.1 ) cyclisation of citronellal to form isopulegol in the presence of an acidic catalyst, c.1 ) purification of isopulegol by crystallisation and d.1 ) catalytic hydrogenation of isopulegol to form menthol.

公开(公告)号：EP1965879A1

公开(公告)日：2008-09-10

申请号：EP06841344.2

申请日：2006-12-13

Applicant: BASF SE

Inventor： ECK, Bernd ,  RAULS, Matthias ,  FEISE, Hermann Josef ,  LETZELTER, Thomas ,  GUTH, Josef

IPC: B01D9/02 ,  C07C29/70 ,  C07C29/78

CPC classification number: B01D9/0031 ,  C07C29/78 ,  C07C31/30

Abstract: Alkoxides are obtained by crystallizing an alkoxide from a solution in the corresponding alcohol, wherein the alcohol is crystallized out at a pressure of at least 3 bar abs. and a temperature of at least 120°C.

公开(公告)号：EP1937071A2

公开(公告)日：2008-07-02

申请号：EP06762088.0

申请日：2006-06-19

Applicant: BASF SE

Inventor： ZIEGLER , Hans ,  MAYER, Winfried ,  KRÖHL, Thomas ,  SCHNEIDER, Karl-Heinrich ,  COX, Gerhard ,  ERK, Peter ,  VOGELBACHER, Uwe, Josef ,  NOACK, Rainer ,  GÖTZ, Roland ,  WUCKELT, Jörg ,  RAULS, Matthias

IPC: A01N47/24 ,  C07D231/22

CPC classification number: A01N47/24 ,  C07D231/22 ,  A01N25/04 ,  A01N25/02 ,  A01N2300/00

Abstract: The invention relates to novel crystalline modifications to pyraclostrobin, methods for production and use of the novel modifications for the production of plant protection agents.

公开(公告)号：EP4417594A3

公开(公告)日：2024-11-20

申请号：EP24180102.6

申请日：2019-08-14

Applicant: BASF SE

Inventor： WLOCH, Sebastian ,  HEYDRICH, Gunnar ,  TEBBEN, Gerd ,  RAULS, Matthias

IPC: C07C29/76 ,  C07C35/12 ,  C07C29/78

Abstract: Die Erfindung betrifft ein Verfahren zur Erzeugung von Kristallen von Menthol, insbesondere L-Menthol, dadurch gekennzeichnet, dass man eine Menthol-Schmelze durch einen Extruder führt. Die Erfindung betrifft auch Verfahren zur Herstellung von Menthol-Partikeln, bei dem man
a. eine Menthol Schmelze, welche Impfkristalle von Menthol enthält, erzeugt, indem man eine Menthol Schmelze durch einen Extruder führt und
b. die so erhaltene Menthol Schmelze mit mindestens einer gekühlten Oberfläche in Kontakt bringt.

公开(公告)号：EP3837233A1

公开(公告)日：2021-06-23

申请号：EP19752514.0

申请日：2019-08-14

Applicant: BASF SE

Inventor： WLOCH, Sebastian ,  HEYDRICH, Gunnar ,  TEBBEN, Gerd ,  RAULS, Matthias

IPC: C07C29/76 ,  C07C35/12

公开(公告)号：EP3523267A1

公开(公告)日：2019-08-14

申请号：EP17777918.8

申请日：2017-10-05

Applicant: BASF SE

Inventor： WLOCH, Sebastian ,  HEYDRICH, Gunnar ,  RAULS, Matthias

IPC: C07B57/00

公开(公告)号：EP3044202B1

公开(公告)日：2017-08-09

申请号：EP14758971.7

申请日：2014-09-05

Applicant: BASF SE

Inventor： REINOSO GARCIA, Marta ,  HARTMANN, Markus ,  SCHMIDT, Kati ,  RAULS, Matthias ,  SCHMIDT, Thomas ,  KLINGELHOEFER, Paul ,  OFTRING, Alfred ,  KADAM, Somnath Shivaji

IPC: C07C227/18 ,  C07C227/36 ,  C07C229/16

CPC classification number: C07C229/24 ,  C07C227/18 ,  C07C227/36 ,  C07C229/16 ,  C07C253/00 ,  C11D3/33

Abstract: Mixture of L- and D-enantiomers of methyl glycine diacetic acid (MGDA) or its respective mono-, di or trialkali metal or mono-, di- or triammonium salts, said mixture containing predominantly the respective L-isomer with an enantiomeric excess (ee) in the range of from 10 to 75%.

Abstract translation: 甲基甘氨酸二乙酸（MGDA）或其各自的单，二或三碱金属或单，二或三铵盐的L-和D-对映体的混合物，所述混合物主要含有各自的L-异构体和对映体过量 ee）在10到75％的范围内。

公开(公告)号：EP2970082A1

公开(公告)日：2016-01-20

申请号：EP14710549.8

申请日：2014-03-14

Applicant: BASF SE

Inventor： DIENES, Christian ,  RAULS, Matthias ,  BEY, Oliver ,  WEICKERT, Mathias

IPC: C07C51/43 ,  C07C55/10 ,  C07C55/14 ,  C07C63/26

CPC classification number: C07C51/43 ,  B01D9/0004 ,  B01D9/0018 ,  B01D9/0022 ,  B01F7/162 ,  B01F7/1675 ,  B01F7/168 ,  B01F7/22 ,  B01F15/0203 ,  B01F2215/0422 ,  B01F2215/0431 ,  B01J19/006 ,  B01J19/0066 ,  B01J19/1875 ,  B01J2219/00182 ,  B01J2219/00189 ,  B01J2219/00243 ,  C07C55/10 ,  C07C55/14 ,  C07C63/26

Abstract: The invention relates to methods for producing free flowing dicarboxylic acid crystalline crops from an aqueous solution or suspension of the dicarboxylic acid in a crystallizer.

公开(公告)号：EP1883623B1

公开(公告)日：2011-04-20

申请号：EP06754975.8

申请日：2006-05-03

Applicant: BASF SE

Inventor： OFTRING, Alfred ,  JUDAT, Bernd ,  RAULS, Matthias ,  FRIESE, Katrin

IPC: C07C253/34 ,  C07C255/24 ,  C07C255/25

CPC classification number: C07C253/34 ,  C07C255/24 ,  C07C255/25

Abstract: The invention relates to a method for isolating methyl glycine nitrile-N,N-diacetonitriles (MGDN) from an MGDN-containing aqueous emulsion with an MGDN content of 3 - 50% by weight in a crystallizer. The inventive method is characterized by (a) cooling the aqueous emulsion, starting from a temperature above the solidification point, to a temperature below the solidification point, the cooling rate in the temporal mean not exceeding 5 K/h, until substantially the total amount of the emulsified MGDN has solidified; and (b) continuing to cool the aqueous suspension obtained and/or concentrating it, the cooling rate being higher than that in step (a).

Abstract translation: 本发明涉及在结晶器中从MGDN含量为3-50重量％的含MGDN的含水乳液中分离甲基甘氨酸腈-N，N-二乙腈（MGDN）的方法。 本发明的方法的特征在于（a）从高于凝固点的温度开始将水性乳液冷却至低于凝固点的温度，冷却速率的时间平均值不超过5K / h，直到基本上达到总量 的乳化MGDN固化; 和（b）继续冷却所得到的含水悬浮液和/或浓缩它，冷却速率高于步骤（a）中的冷却速率。

公开(公告)号：EP2155638A1

公开(公告)日：2010-02-24

申请号：EP08760702.4

申请日：2008-06-09

Applicant: BASF SE

Inventor： RAULS, Matthias ,  BAYER, Robert ,  HEYDRICH, Gunnar ,  FRYE, Lars ,  WISNIEWSKI, Thomas

IPC: C07C29/76 ,  C07C35/12 ,  B01J2/24

CPC classification number: B01J2/24 ,  C07B2200/07 ,  C07C29/76 ,  C07C35/12 ,  C07C2601/14

Abstract: The invention relates to a method for producing L-menthol in solid form, especially in the form of flakes, by contacting melted L-menthol with two interspaced cooled surfaces. The invention further relates to the L-menthol in solid form obtainable by the above method, and to the use thereof for incorporation into commodities and articles of consumption of all kinds.