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    BLOWING AGENT ADDITIVE
    31.
    发明专利
    BLOWING AGENT ADDITIVE 未知

    公开(公告)号：ZA72303B

    公开(公告)日：1972-10-25

    申请号：ZA72303

    申请日：1972-01-17

    Applicant: BAYER AG

    Inventor： ROOS E ,  DAMMAN G ,  ABELE M ,  KEMPERMANN T

    IPC: C08J9/10 ,  B29C ,  B29D

    Abstract: 1380961 Azodicarbonamide/sulphinic acid or salt as blowing agents BAYER AG 18 Jan 1972 [18 Jan 1971] 2281/72 Headings C3C and C3R Cellular natural or synthetic rubber or synthetic resins are made using as blowing agent azodicarbonamide together with an activator which is an aromatic sulphinic acid or salt of Formula (I) where M is H, a metal or an ammonium radical which may be substituted, n is the valency of M, and R 1-5 are H, C 1-4 alkyl or halogen. The polymer may be derived from butadiene, chlorobutadiene, dimethylbutadiene, isoprene, styrene, α-methylstyrene, acrylonitrile, methacylonitrile, acrylates, methacrylates, ethylene, propylene, vinyl chloride, and/or vinyl acetate; or may be a polyurethane. The activator may be a benzene sulphinate or sodium, zinc, lead cadmium, magnesium; a p-chlorobenzene sulphinate of zinc or sodium; a toluene sulphinate of cadmium or sodium; or p-chlorobenzene sulphinic acid.

    NOVEL BENZTHIAZOLONES,A PROCESS FOR THEIR PREPARATION AND THEIR USE INSECTICIDES,ACARICIDES AND FUNGICIDES
    32.
    发明专利
    NOVEL BENZTHIAZOLONES,A PROCESS FOR THEIR PREPARATION AND THEIR USE INSECTICIDES,ACARICIDES AND FUNGICIDES 未知

    公开(公告)号：ZA72178B

    公开(公告)日：1972-09-27

    申请号：ZA72178

    申请日：1972-01-11

    Applicant: BAYER AG

    Inventor： WAGNER K ,  UNTERSTANHOEFER G ,  ROOS E ,  HAMMANN I

    IPC: C07D277/68 ,  A01N

    Abstract: 1340824 Benzthiazolone derivatives and their preparation BAYER AG 12 Jan 1972 [12 Jan 1971(2)] 1387/72 Heading C2C Benzthiazolones of the formula wherein R 1 is an electronegative radical, R 2 is alkyl or an electronegative radical, R 3 is hydrogen, hydroxyl, alkoxy or an aliphatic or cycloaliphatic hydrocarbon radical, R 4 is a radical of the formula -COR 5 , -COOR 6 -CONR 7 R 8 , -SO 2 R 9 or hydrogen, R 5 is hydrogen, optionally substituted alkyl, alkenyl or optionally substituted phenyl, R 6 is alkyl or phenyl, R 7 is hydrogen, alkoxyalkyl, alkenyl or other aliphatic hydrocarbon radical, aralkyl, aryl, cycloalkyl or hydroxy alkyl, R 8 is hydrogen (except when R 7 is hydrogen), alkyl or alkenyl, or R 7 and R 8 , together with the nitrogen to which they are attached, form a heterocyclic ring (which may be interrupted by at least one further heteroatom), R 9 is optionally substituted alkyl, optionally substituted phenyl or dimethylamino, and a is 1 or 2, may be prepared, in the case where R 4 is other than hydrogen, by reacting a benzthiazolone of the formula with (a) an acid chloride of the formula R 6 -CO-Cl, (b) a chloroformic acid alkyl or phenyl ester of the formula R 6 O-CO-Cl, or (c) a sulphonyl chloride of the formula R 9 -SO 2 -Cl, or by reacting a 2-carbamylbenzthiazole-N-oxide of the formula with phosphorus oxychloride. The above reactions may be carried out at -10‹ to +80‹ C. employing the reactants in substantially stoichiometric proportions and reactions (a), (b) and (c) are preferably effected in the presence of an acid-binding agent in an inert organic solvent. Compounds of Formula (I) wherein R 4 is hydrogen may be obtained by reacting a compound of formula with phosphorus oxychloride, preferably at 20-160‹ C. in an inert organic solvent. Electronegative radicals specified are nitro, trifluoromethyl, trifluoromethoxy, chlorine, bromine, iodine, fluorine, cyano, aldehyde, keto, carboxyl and radicals of the formula -SO 2 Y, wherein Y denotes an aliphatic, cycloaliphatic, araliphatic or aromatic radical, fluorine, or an optionally substituted amino group. The compounds of Formula (I) possess insecticidal, acaricidal and fungicidal properties and they may be formulated in compositions of the conventional type and applied in a known manner.

    34.
    发明专利
    未知

    公开(公告)号：BR8001843A

    公开(公告)日：1980-11-18

    申请号：BR8001843

    申请日：1980-03-27

    Applicant: BAYER AG

    Inventor： ABELE M ,  JEBLICK W ,  KEMPERMANN T ,  ROOS E

    IPC: C08J9/06 ,  C07C67/00 ,  C07C313/00 ,  C07C317/28 ,  C07C325/00 ,  C07C335/08 ,  C08J9/10 ,  C08L21/00 ,  C09K3/00 ,  C08K5/23

    Abstract: A mixture of azodicarbonamide and an alpha -amidosulphone corresponding to the general formula: in which R represents hydrogen, a C1-C4-alkyl residue and/or halogen, x represents numbers from 0 to 5, y represents numbers from 1 to 3, corresponding to the valency of R1, R1 represents an aromatic carboxylic acid residue or sulphonic acid residue with 6 carbon atoms, which is optionally substituted once or several times by halogen, C1-C4 alkyl residues, C1-C4 alkoxy residues, nitro and/or cyano, or represents an aliphatic carboxylic acid residue or a sulphonic acid residue with 1-4 carbon atoms, a carbonic acid residue, a thiocarbonic acid residue or a phosphoric acid residue which, corresponding to the numerical value of y, contains 0-2 phenoxy residues or C1-C4 alkoxy residues optionally substituted with C1-C4 alkyl or halogen, R2 represents R1, or hydrogen, a C1-C4 alkyl residue, a C5-C7 cycloalkyl residue, a phenyl residue, which is optionally substituted once or several times by C1-C4-alkyl or halogen, a phenyl alkyl residue whose phenyl group is optionally substituted once or several times by C1-C4-alkyl or halogen and whose alkyl group has 1-3 carbon atoms or R1 and R2 together with the nitrogen atom form a cyclic lactam ring which has 4-6 carbon atoms, can be used as a blowing agent for rubber.

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