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    COMPOSITE MATERIAL NOT USING BINDER LAYER AS INTERMEDIARY
    34.
    发明专利
    COMPOSITE MATERIAL NOT USING BINDER LAYER AS INTERMEDIARY 失效

    公开(公告)号：JPH10329280A

    公开(公告)日：1998-12-15

    申请号：JP14395297

    申请日：1997-06-02

    Applicant: DAIKIN IND LTD

    Inventor： ARAKI TAKAYUKI ,  TANAKA YOSHITO ,  KUMEGAWA MASAHIRO ,  OKA NORITOSHI ,  SANEMASA HISATO ,  SHIMIZU TETSUO

    IPC: B32B27/30

    Abstract: PROBLEM TO BE SOLVED: To provide a composite material which is prepared by applying to a base directly a material constituted of a fluorine-containing polymer excellent in the adhesion to the base, without necessitating complicated processes of formation of a binder layer, surface treatment and others and to provide the composite material which is excellent in bonding properties, transparency and design properties in addition to weather resistance, stainproof properties, non- tackiness, chemical resistance and sliding properties. SOLUTION: This composite material is prepared by a method wherein a material constituted of a functional-group-containing and fluorine-containing ethylene polymer prepared by copolymerization of (a) at least one kind of monomer of 0.05-30 mol.% out of functional-group-containing and fluorine-containing ethylene monomers each having at least one kind of functional group selected from the group comprising a hydroxyl group, a carboxyl group, a carboxylic acid salt, a carboxyester group and an epoxy group and (b) at least one kind of monomer of 70-99.95 mol.% out of fluorine-containing ethylene monomers not having the aforesaid functional group is applied to a base directly.

    WEATHER RESISTANT COMPOSITE MATERIAL
    35.
    发明专利
    WEATHER RESISTANT COMPOSITE MATERIAL 失效

    公开(公告)号：JPH10272719A

    公开(公告)日：1998-10-13

    申请号：JP8151897

    申请日：1997-03-31

    Applicant: DAIKIN IND LTD

    Inventor： ARAKI TAKAYUKI ,  TANAKA YOSHITO ,  KUMEGAWA MASAHIRO ,  OKA NORITOSHI ,  SHIMIZU TETSUO

    IPC: B32B9/00 ,  B32B27/30

    Abstract: PROBLEM TO BE SOLVED: To give excellent wear resistance, flaw resistance, transparency (design property) and sufficient hardness by providing a film, in which copolymer fine particles of specific fluorine-containing ethylenic monomer is dispersed in a metal oxide layer on a surface of a base material. SOLUTION: The weather resistant composite material is provided by forming a film in which fine particles obtained by copolymerizing 0.05 to 50 mol.% of a functional group-containing fluoroethylenic monomer having a functional group represented by a formula 1 selected from a hydroxyl group, and 50 to 99.95 mol.% of fluoroethylenic monomer containing no functional group represented by a formula II on a surface of a base material. In the formula I, Y indicates CH2 OH X and X indicate the same or different, hydrogen atom or fluorine atom, and Rf indicates alkylene group including 1-40C bivalent fluoroalkylene group. In the formula II, Rf indicates CF3 or ORf (Rf indicates 1-5C perfluoroalkyl group).

    COMPOSITE MATERIALS FOR BUILDING MATERIAL
    36.
    发明专利
    COMPOSITE MATERIALS FOR BUILDING MATERIAL 失效

    公开(公告)号：JPH10264326A

    公开(公告)日：1998-10-06

    申请号：JP7634897

    申请日：1997-03-27

    Applicant: DAIKIN IND LTD

    Inventor： ARAKI TAKAYUKI ,  TANAKA YOSHITO ,  KUMEGAWA MASAHIRO ,  OKA NORITOSHI ,  SANEMASA HISATO ,  SHIMIZU TETSUO

    IPC: B32B27/30

    Abstract: PROBLEM TO BE SOLVED: To provide a composite materials for building material which are excellent in weather resistance, thermal resistance, stain resistance, anti-adhesion, transparency (design property), anti-corrosion, water resistance, anti-weathering, flame retardancy, and abrasion resistance by a method wherein the composite materials for building material are provided by applying materials composed of polymer containing fluorine which is excellent in adhesion to a base material without requiring a complicated process. SOLUTION: The composite materials for building material is provided by applying materials composed of fluorine-containing ethylene polymer having a functional group of polymerizing (a) 0.0530 mol% of at least one kind of monomer of fluoroethylene monomer containing at least one kind of a functional group selected from a group composed of hydroxyl group, carboxyl group, carboxylic acid, carboxyester group, and epoxy group, and (b) 70-99.5 mol% at least one kind of monomer of fluorine-containing ethylene monomer without containing the abovementioned functional group in (c), to a base material.

    SLIDABLE COMPOSITE MATERIAL
    37.
    发明专利
    SLIDABLE COMPOSITE MATERIAL 失效

    公开(公告)号：JPH10305516A

    公开(公告)日：1998-11-17

    申请号：JP11587497

    申请日：1997-05-06

    Applicant: DAIKIN IND LTD

    Inventor： ARAKI TAKAYUKI ,  TANAKA YOSHITO ,  KUMEGAWA MASAHIRO ,  OKA NORITOSHI ,  SHIMIZU TETSUO

    IPC: B32B9/00 ,  B32B27/30 ,  C09D127/12

    Abstract: PROBLEM TO BE SOLVED: To manufacture a slidable composite material with a superior anti- scratching property and transparency, and having a sufficient hardness by providing on the surface of material a skin film having minute particles of a polymer polymerized with a functional group-containing or uncontaining fluoroethylene monomer copolymerized respectively by a specific quantity, dispersed in a metallic compound layer. SOLUTION: At least one kind of a 0.05-50 mol.% monomer of a functional group-containing fluoroethylene monomer is prepared, which is selected from groups consisting of a hydroxyl group, a carboxyl group, a carboxylic acid salt, a carboxylic ester group, and an expoxy group. Then, a skin film is formed on the surface of a base material, in which this and minute particles of a fluorine-containing ethylenic polymer having a functional group consisting of being polymerized with at least one kind of 50-99.95 mol.% of aforementioned fluorine-containing ethylenic polymer having no function group are dispersed in a metallic oxide layer being a matrix.

    ANTIFOULING COMPOSITE MATERIAL
    38.
    发明专利
    ANTIFOULING COMPOSITE MATERIAL 失效

    公开(公告)号：JPH10272718A

    公开(公告)日：1998-10-13

    申请号：JP8151797

    申请日：1997-03-31

    Applicant: DAIKIN IND LTD

    Inventor： ARAKI TAKAYUKI ,  TANAKA YOSHITO ,  KUMEGAWA MASAHIRO ,  OKA NORITOSHI ,  SHIMIZU TETSUO

    IPC: B32B9/00 ,  B32B27/30

    Abstract: PROBLEM TO BE SOLVED: To provide an antifouling composite material obtained by rigidly adhering a film having excellent antifouling, heat resistance, water repellence, wear resistance, flaw resistance and transparency, and high hardness to a base material. SOLUTION: A film in which fine particles of a functional group-containing fluoroethylenic polymer obtained by copolymerizing 0.05 to 50 mol.% of functional group-containing fluoroethylenic monomer having at least one type of hydroxy group, carboxyl group, carboxylate and carboxyester group and 50 to 99.95 mol.% of fluoroethylenic monomer having no functional group are dispersed in a metal oxide layer is provided on a surface of a base material.

    NON-ADHESIVE COMPOSITE MATERIAL
    39.
    发明专利
    NON-ADHESIVE COMPOSITE MATERIAL 失效

    公开(公告)号：JPH10264328A

    公开(公告)日：1998-10-06

    申请号：JP7761897

    申请日：1997-03-28

    Applicant: DAIKIN IND LTD

    Inventor： ARAKI TAKAYUKI ,  TANAKA YOSHITO ,  KUMEGAWA MASAHIRO ,  OKA NORITOSHI ,  SHIMIZU TETSUO

    IPC: B32B9/00 ,  B32B27/30 ,  C08F214/18

    Abstract: PROBLEM TO BE SOLVED: To realize a non-adhesive composite material having excellent wear resistance and transparency by providing a film in which fine particles of polymer containing specific mol% of a functional group and fluoroethylenic monomer containing no functional group are dispersed in a metal oxide layer on a surface of a base material. SOLUTION: 0.05 to 30 mol% of at least one type of monomer of functional group-containing fluoroethylenic monomer having at least one type of functional group selected from a group consisting of hydroxyl group, carboxyl group, carboxylate, carboxyester group and epoxy group is contained. Further, particles of fluoroethylenic polymer having a functional group copolymerized with it and 70 to 99.95 mol% of at least one type of monomer of nitrogen-containing ethylenic monomer having no functional group are formed. A film obtained by dispersing it in a metal oxide layer of a matrix is formed on a surface of the base material as a non-adhesive composite material.

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