ACROLEIN-RELEASING COMPOSITION AND USE THEREOF

    公开(公告)号:CA2205597C

    公开(公告)日:2004-01-20

    申请号:CA2205597

    申请日:1995-10-23

    Applicant: DEGUSSA

    Abstract: The direct handling of acrolein for combating microbial, plant and animal parasites in water and soil is problematic owing to the potential risks posed by acrolein. According to the invention, an easy-to-handle acrolein-releasing composition is used, the acrolein being released at the site of use owing to contact with water. This composition contains (i) an acrolein acetal having a C1 to C6 alcohol with 1 to 4 hydroxyl groups and (ii) a chemically compatible acid which is soluble therein and has a pK s value of less than 4 and (iii) is anhydrous. A preferred composition contains as acetal 2-vinyl-1,3-dioxolane, as acid, anhydrous oxalic acid, furnaric acid or maleic acid or a mixture of mono and di(C1 to C3)alkylphosphate and additionally a nonionic surfactant.

    33.
    发明专利
    未知

    公开(公告)号:ES2133929T3

    公开(公告)日:1999-09-16

    申请号:ES96901342

    申请日:1996-02-01

    Applicant: DEGUSSA

    Abstract: The potential hazards of acraldhyde make its direct handling for combatting microbial, vegetable and animal pests in the water and ground difficult. According to the invention, use is made of a composition releasing acraldhyde in contact with water at the point of use. The composition of the invention contains an acraldehyde acetal, preferably 2-vinyl-2, 3-dioxolane, and a compound hydrolysable to an acide with a pKs of lower than 4, especially one from the range of organic acid anhydrides, organic acid halides and inorganic halogen compounds forming hydrogen halides on hydrolysis.

    35.
    发明专利
    未知

    公开(公告)号:DE59601879D1

    公开(公告)日:1999-06-17

    申请号:DE59601879

    申请日:1996-02-01

    Applicant: DEGUSSA

    Abstract: The potential hazards of acraldhyde make its direct handling for combatting microbial, vegetable and animal pests in the water and ground difficult. According to the invention, use is made of a composition releasing acraldhyde in contact with water at the point of use. The composition of the invention contains an acraldehyde acetal, preferably 2-vinyl-2, 3-dioxolane, and a compound hydrolysable to an acide with a pKs of lower than 4, especially one from the range of organic acid anhydrides, organic acid halides and inorganic halogen compounds forming hydrogen halides on hydrolysis.

    36.
    发明专利
    未知

    公开(公告)号:NO973148D0

    公开(公告)日:1997-07-07

    申请号:NO973148

    申请日:1997-07-07

    Applicant: DEGUSSA

    Abstract: The potential hazards of acraldhyde make its direct handling for combatting microbial, vegetable and animal pests in the water and ground difficult. According to the invention, use is made of a composition releasing acraldhyde in contact with water at the point of use. The composition of the invention contains an acraldehyde acetal, preferably 2-vinyl-2, 3-dioxolane, and a compound hydrolysable to an acide with a pKs of lower than 4, especially one from the range of organic acid anhydrides, organic acid halides and inorganic halogen compounds forming hydrogen halides on hydrolysis.

    39.
    发明专利
    未知

    公开(公告)号:NO950512L

    公开(公告)日:1995-08-14

    申请号:NO950512

    申请日:1995-02-10

    Applicant: DEGUSSA

    Abstract: Acrolein (2-propenal) polymers (I) with an average wt. (Mw) of 2000-6000 (see calculation) and a carbonyl content of 0.5-5 mol/kg are new. Also claimed are:(1) prodn. of (I) by adding acrolein and a catalyst simultaneously to a reaction medium having a temp. of ≤ 25 degrees C and a pH of 10-11, stirring the mixt., and separating (I);(2) preservation of materials by adding (I); and(3) biocidal compsns. contg. (I). Mw = ni Mi / ni Mi where Mw = average weight, ni = molar number and Mi = molecular weight.

    ACROLEIN POLYMER
    40.
    发明专利

    公开(公告)号:CA2142220A1

    公开(公告)日:1995-08-12

    申请号:CA2142220

    申请日:1995-02-10

    Applicant: DEGUSSA

    Abstract: The acrolein polymer is characterised by the physicochemical data: Weight average wherein ni means number of mol and Mi means molecular weight Mw: 2000 - 6000 D Carbonyl content: 0.5 - 5 mol/kg of polymer It is produced by simultaneously adding acrolein and catalyst to a reaction medium in a vessel in such a manner that the temperature of the reaction medium does not exceed 25.degree.C and the pH value of the reaction medium is 10 to 11, the mixture is stirred on completion of addition and the acrolein polymer separated. The acrolein polymer is used in biocidal agents.

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