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    PROCESS FOR PRODUCING S-TRIAZINES
    31.
    发明专利
    PROCESS FOR PRODUCING S-TRIAZINES 未知

    公开(公告)号：HU175456B

    公开(公告)日：1980-08-28

    申请号：HUDE000905

    申请日：1976-02-10

    Applicant: DEGUSSA

    Inventor： HASCHKE HEINZ ,  SCHREYER GERD ,  SCHWARZE WERNER ,  SUCHSLAND HELMUT

    IPC: C07D251/50 ,  C07D251/44 ,  C07D251/28

    Abstract: There is provided a process, preferably continuous and in a given case successive, substitution of one or two chlorine atoms of cyanuric chloride by one or two amines, which may be the same or different, in the presence of an acid acceptor and in the presence of an organic solvent, particularly for the production of 2-alkylamino-4,6-dichloro and preferably for the production of 2,4-di(alkylamino)-6-chloro-s-triazines wherein there is added 1.00 to 1.05 mole, preferably 1.00 to 1.03 mole of a first amine to a 4.5 to 50 weight % suspension or solution of cyanuric chloride in a mixture of 65 to 85 weight % of xylene, toluene, ethylbenzene, benzene and/or an aliphatic or cycloaliphatic hydrocarbon with 5 to 10 carbon atoms (toluene being preferred) and 35 to 15 weight % of a ketone with 3 to 8 carbon atoms, preferably acetone, while maintaining the temperature between about 0 and about 20 DEG C, preferably about 10 to 18 DEG C., continuously so regulating the pH value of the reaction mixture obtained in accordance with the reaction time by addition of alkali and in a given case, water so that this corresponds to a point within the area bounded by lines ABCD of FIG. 1, which runs through the area beginning with the reaction time t,(step 1)= 0 until reaching a position in the area bounded by the lines BCEF and after reaching a pH of 7.0, preferably 7.2 maintains a temperature of about 10 DEG to about 60 DEG C., preferably about 25 DEG to 40 DEG C., after addition of 0.96 to 1.05, preferably 0.98 to 1.02 equivalents of alkali per mole of cyanuric chloride, adding at least an equimolar amount, preferably 1.00 to 1.02 mole of the second amine per mole of cyanuric chloride and continuously so adjusting the pH value of the reaction mixture obtained depending on the reaction time by addition of alkali that this corresponds to a point within the area which is defined by lines GHIJ in FIG. 3 which passes through the band beginning with the reaction time t(step 2)= 0 of the second reaction step until reaching a position in the area bounded by the lines HIKL and thereby maintaining a temperature of 40 to 70 DEG C., preferably 45 DEG to 55 DEG C. and thereafter working up the product in known manner wherein t1 is a time of 4 to 10 hours, preferably about 7 hours and t2 is a time of 2 to 8 hours, preferably about 6 hours and wherein the B C corresponds to the equation, pH = -(12.6/t1)+ 14.35 and the line H I corresponds to the equation pH = -(24,857/t2)+ 23.9285. There are also disclosed novel, purified mono and bis alkylamino-cyanoalkylalkylamino - s - triazines.

    PROCESS AND APPARATUS FOR PRODUCING SOLUTIONS OR SUSPENSIONS OF CYANURIC CHLORIDE IN AQUEOUS NIC SOLVENTS
    35.
    发明专利
    PROCESS AND APPARATUS FOR PRODUCING SOLUTIONS OR SUSPENSIONS OF CYANURIC CHLORIDE IN AQUEOUS NIC SOLVENTS 未知

    公开(公告)号：CA1036160A

    公开(公告)日：1978-08-08

    申请号：CA240152

    申请日：1975-11-20

    Applicant: DEGUSSA

    Inventor： BITTNER FRIEDRICH ,  HASCHKE HEINZ ,  SUCHSLAND HELMUT ,  SCHREYER GERD ,  SCHWARZE WERNER

    IPC: C07D251/28

    Abstract: There is provided a process for the production of a solution or suspension of cyanuric chloride in a water containing organic solvent wherein the liquid cyanuric chloride and the organic-aqueous solvent are mixed together while being agitated, the liquid cyanuric chloride at a temperature between its melting point and 200 DEG C. is led into the flowing organic-aqueous solvent with a velocity of Vcy (in kg per hour) wherein where P is the desired concentration of cyanuric chloride in the solution or suspension to be produced in weight %, PLM is the concentration of cyanuric chloride in the solvent used which also includes O, VLM is the velocity of the solvent added in kg/h, AND PLM, VLM and TLM, the temperature of the added solvent, are so selected that the expression does not exceed the boiling temperature in DEG C. of the solvent used and wherein Cp(LM) and Cp(Cy) signify the specific heat capacities in cal. x g 1 x ( DEG degree C) 1 of the solvent and cyanuric chloride respectively, whereupon in a given case within at most 3 minutes after bringing the cyanuric chloride and solvent into contact the flowing mixture is cooled to the desired storage temperature.

    SUBSTITUTION OF CHLORINE ATOMS OF CYANURIC CHLORIDE %B<
    36.
    发明专利
    SUBSTITUTION OF CHLORINE ATOMS OF CYANURIC CHLORIDE %B< 未知

    公开(公告)号：AU1103876A

    公开(公告)日：1977-08-18

    申请号：AU1103876

    申请日：1976-02-12

    Applicant: DEGUSSA

    Inventor： HASCHKE HEINZ ,  SCHWARZE WERNER ,  SUCHSLAND HELMUT ,  SCHREYER GERD

    IPC: C07D251/42 ,  C07D251/44 ,  C07D251/50

    Abstract: There is provided a process for the substitution of one or for the successive substitution of two chlorine atoms of cyanuric chloride by one or two amines whch may be the same or different in the presence of an acid binding agent and in the presence of an organic solvent, particularly for the production of 2-alkylamino-4,6-dichloro-, s-triazines and more preferably for the production of 2,4-di-(alkylamino)-6-chloro-s-triazines wherein there is used a 4 to 60 weight % solution or suspension of cyanuric chloride in a mixture of 65 to 85 weight % of one or more aliphatic hydrocarbons or cycloaliphatic hydrocarbons hving 5 to 10 carbon atoms and/or one or more aromatic hydrocarbons and 35 to 15 weight % of one or more ketones having 3 to 8 carbon atoms.

    THIOCARBAMOYLALKYLAMINO-S-TRIAZINES
    40.
    发明专利
    THIOCARBAMOYLALKYLAMINO-S-TRIAZINES 未知

    公开(公告)号：GB1203544A

    公开(公告)日：1970-08-26

    申请号：GB1137269

    申请日：1969-03-04

    Applicant: DEGUSSA

    Inventor： SCHWARZE WERNER ,  WEIGERT WOLFGANG

    IPC: C07D251/50 ,  A01N43/70 ,  A01P13/00 ,  C07D251/52 ,  C07D251/54

    Abstract: 1,203,544. 8-Triazine derivatives. DEUTSCHE GOLD-UND SILBER SCHEIDEANSTALT. 4 March, 1969 [22 March, 1968], No. 11372/69. Heading C2C. [Also in Division A5] Novel 8-triazine derivatives of the general formula wherein X is a halogen atom or an azido, C 1-6 alkoxy or C 1-6 alkylthio group; B 1 and R 2 are each a hydrogen atom or a C 1-6 alkyl or C 2-6 alkenyl group optionally substituted by a halogen atom or a hydroxy, cyano, C 1-6 alkoxy or C 1-6 alkylthio group; R 3 and R 4 are each a C 1-8 alkyl, C 2-8 alkenyl or aralkyl group and either R 3 or R 4 may be a hydrogen atom; or R 3 and R 4 are attached to one another to form a 5-7-membered saturated carbocyclic ring; and R 5 and R 6 are each a hydrogen atom or a C 1-6 alkyl group, are prepared (a) when X is a C 1-6 alkoxy or C 1-6 alkylmercapto group, by reaction of the corresponding 2-(R 1 R 2 N)-4- cyanoalkylamino-6-alkoxy- or alkylthio-s-triazine with hydrogen sulphide in the presence of a base and optionally in the presence of primary amines; (b) when X is a halogen atom, by reaction of a cyanuric halide with an aminoacetic acid thioamide of the general formula followed by reaction of the resulting 2,4-bis-halo- 6 - thiocarbamoylalkylamino - s - triazine with ammonia or an amine of the general formula R 1 R 2 NH; (c) when X is a C 1-6 alkoxy, C 1-6 alkylthio or azido group, by reaction of the corresponding s-triazine derivative of the first general formula above wherein X is a halogen atom with an alcohol or alkylmercaptan in the presence of an acid acceptor or with an alkali metal azide in dimethylformamide or dimethylsulphoxide, respectively; (d) when X is an azido group, by reaction of the corresponding s-triazine derivative of the first general formula above wherein X is a quaternary amino group with an alkali metal azide in water; and (e) when X is a C 1-6 alkylthio group, by alkylation of the corresponding s-triazine derivative of the first general formula above wherein X is a mercapto group.

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