公开(公告)号：DE3804523A1

公开(公告)日：1989-08-24

申请号：DE3804523

申请日：1988-02-13

Applicant: HOECHST AG

Inventor： FELDHUES MICHAEL DR ,  KAEMPF GUENTHER DR ,  MECKLENBURG THOMAS DR

IPC: C08G61/10 ,  C08G61/12 ,  C09D5/00 ,  C09D5/24 ,  C09D5/30 ,  D06M15/21 ,  H01B1/12

公开(公告)号：DE3736114A1

公开(公告)日：1989-07-13

申请号：DE3736114

申请日：1987-10-26

Applicant: HOECHST AG

Inventor： FELDHUES MICHAEL DR ,  KAEMPF GUENTHER DR ,  MECKLENBURG THOMAS DR

IPC: C08F2/58 ,  C08G61/10 ,  C08G61/12 ,  C25B3/23 ,  H01B1/12

Abstract: In conventional electrically conducting polymers in the oxidised (doped) form, the anions can be replaced as desired if the polymer in solution is combined with a salt which contains the proposed anion and the solution equilibrium is adjusted taking into account the solubility products of the salts present. In this way, the properties of the electrically conducting polymers can be tailored to various applications.

公开(公告)号：DE3628895A1

公开(公告)日：1988-03-10

申请号：DE3628895

申请日：1986-08-26

Applicant: HOECHST AG

Inventor： FELDHUES MICHAEL DR ,  MECKLENBURG THOMAS DR ,  WEGENER PETER DR

IPC: C08F2/58 ,  C08G61/12 ,  H01B1/12 ,  C25B3/10 ,  B01J31/06 ,  C08F34/04 ,  C08L45/00 ,  C09D5/24 ,  C09D5/30 ,  C09D5/32 ,  H01B1/06

Abstract: The invention relates to intrinsically electrically conductive polymers which are completely soluble in the oxidised form in dipolar aprotic solvents at room temperature and which contain structural units derived from at least one monomer of the general formula (I) below: in which at least one of the two radicals R and R is an alkoxy group and the other radical is optionally (C1-C6)-alkyl or hydrogen. Furthermore, the invention relates to a process for producing said polymer by electrochemical polymerisation of at least one monomer of said formula (I) in the presence of an electrolyte solvent and conducting salt. In this process the anode has a specific surface of at least 0.01 m /g, the electrolyte solvent is dipolarly aprotic and the electrolyte system is not displaced relative to the anode or is only slightly displaced. The polymers according to the invention are well suited, in particular, for coating purposes.