公开(公告)号：AU1664076A

公开(公告)日：1978-02-09

申请号：AU1664076

申请日：1976-08-06

Applicant: HOECHST AG

Inventor： BRAUN HELMUT ,  RINNO HELMUT ,  STELZEL WERNER

IPC: C08L31/02 ,  C08F2/00 ,  C08F2/22 ,  C08F2/24 ,  C08F18/00 ,  C08F18/02 ,  C08F218/00 ,  C08F218/02 ,  C08F218/04 ,  C09D131/02 ,  C09D131/04 ,  C09K23/52 ,  C09D5/02

Abstract: An aqueous polymer dispersion which is suitable for the preparation of paints having high wet adhesion is prepared by copolymerisation in aqueous medium of vinyl esters of saturated monocarboxylic acids in the presence of an olefinically unsaturated acetoacetate. The vinyl ester employed is vinyl acetate, vinyl propionate, vinyl butyrate and/or vinyl isobutyrate together with vinyl esters of saturated monocarboxylic acids having 5 to 20 carbon atoms whose carboxyl group is bonded to a tertiary or quaternary carbon atom. The resultant dispersions are suitable for the preparation of gloss emulsion paints having high wet adhesion to non-sorptive substrates and have high resistance to hydrolysis.

公开(公告)号：FI753023A

公开(公告)日：1976-05-01

申请号：FI753023

申请日：1975-10-29

Applicant: HOECHST AG

Inventor： BRAUN HELMUT ,  RINNO HELMUT ,  STELZEL WERNER ,  WINSTEL WOLFGANG

IPC: C08F8/00 ,  C08F8/30 ,  C08F8/32 ,  C08F8/44 ,  C09D5/00 ,  C09D5/02 ,  C09D157/08 ,  C09D201/00 ,  C08J

公开(公告)号：CA881595A

公开(公告)日：1971-09-21

申请号：CA881595D

Applicant: HOECHST AG

Inventor： LAMPE WILHELM ,  RINNO HELMUT

公开(公告)号：CA759541A

公开(公告)日：1967-05-23

申请号：CA759541D

Applicant: HOECHST AG

Inventor： KUHLKAMP ALFRED ,  RINNO HELMUT

公开(公告)号：AU4255796A

公开(公告)日：1996-06-19

申请号：AU4255796

申请日：1995-11-24

Applicant: HOECHST AG

Inventor： HESSEL FRIEDRICH ,  RINNO HELMUT ,  SCHARDT RICHARD ,  ZIMMERSCHIED KLAUS

IPC: C08F2/00 ,  C08F2/22 ,  C08F2/24 ,  C08F212/08 ,  C08F220/10 ,  C08F220/18

Abstract: Described is a method of producing emulsion polymers on an industrial scale from at least partially hydrophobic monomers in an agitator reactor vessel with a useful volume of 2 to 80 m , using a metering technique with a monomer-addition rate of 15 to 60 % by wt. per hour of the total amount of monomer to be added, by polymerizing and distilling a water/monomer mixture under reduced pressure and feeding the condensed water/monomer mixture back to the reactor vessel.

公开(公告)号：AU647250B2

公开(公告)日：1994-03-17

申请号：AU1318492

申请日：1992-03-26

Applicant: HOECHST AG

Inventor： HUTH HANS-ULLRICH ,  RINNO HELMUT ,  MOMPER BERNHARD

IPC: C08F6/00 ,  C08F218/02 ,  C08F218/04 ,  C08F6/10 ,  C08F18/08 ,  C09D131/02 ,  C09J131/02 ,  D21H21/16

Abstract: The preparation of aqueous polymer dispersions containing vinyl ester polymers or vinyl ester copolymers and having reduced contents of undesired residual monomeric vinyl esters present as a consequence of the preparation and possibly of undesired acetaldehyde from corresponding starting dispersions, as are obtainable by conventional polymerisation or copolymerisation methods from ethylenically unsaturated monomers, by selective alkaline saponification (hydrolysis) of the residual monomeric vinyl esters which can be saponified under alkaline conditions, and, if appropriate, oxidation of the acetaldehyde to acetic acid in the aqueous dispersions. The use of the polymer dispersions as binders in low-emission or emission-free aqueous preparations, for example for paint coats, coatings, plaster, adhesives, paper sizes, fibre nonwoven binders, textile assistants, etc., in particular indoor applications or applications in closed spaces.

公开(公告)号：NO160926C

公开(公告)日：1989-06-14

申请号：NO824393

申请日：1982-12-28

Applicant: HOECHST AG

Inventor： ZIMMERSCHIED KLAUS ,  RINNO HELMUT

IPC: C08F2/00 ,  C08F2/20 ,  C08F2/22 ,  C08F2/24 ,  C08F2/26 ,  C08F2/44 ,  C08F20/00 ,  C08F20/02 ,  C08F220/00 ,  C08F220/04 ,  C08F220/10 ,  C08L1/28 ,  C09D133/04 ,  C09D133/06 ,  C09D133/08 ,  C09D133/10 ,  D21J1/16 ,  C08F220/18 ,  C09D3/80

公开(公告)号：NO160926B

公开(公告)日：1989-03-06

申请号：NO824393

申请日：1982-12-28

Applicant: HOECHST AG

Inventor： ZIMMERSCHIED KLAUS ,  RINNO HELMUT

IPC: C08F2/00 ,  C08F2/20 ,  C08F2/22 ,  C08F2/24 ,  C08F2/26 ,  C08F2/44 ,  C08F20/00 ,  C08F20/02 ,  C08F220/00 ,  C08F220/04 ,  C08F220/10 ,  C08L1/28 ,  C09D133/04 ,  C09D133/06 ,  C09D133/08 ,  C09D133/10 ,  D21J1/16 ,  C08F220/18 ,  C09D3/80

公开(公告)号：CA1225791A

公开(公告)日：1987-08-18

申请号：CA450956

申请日：1984-03-30

Applicant: HOECHST AG

Inventor： ENGEL DIETER ,  RINNO HELMUT ,  ZIMMERSCHIED KLAUS

IPC: C08F2/38 ,  C08F6/00 ,  C08F6/02 ,  C08F8/44 ,  C08F20/00 ,  C08F20/10 ,  C08F20/22 ,  C08F20/26 ,  C08F220/00 ,  C08F220/10 ,  C08F220/12 ,  C08F220/18 ,  C08F220/28 ,  C08F290/00 ,  C08F290/06 ,  C08F299/02 ,  C09D5/00 ,  C09D5/02 ,  C09D7/00 ,  C09K3/00 ,  C11D3/37 ,  D06M13/02 ,  D06M13/248 ,  D06M13/252 ,  D06M15/21 ,  D06M15/277 ,  D06P1/52

Abstract: HOE 83/F 048 of the disclosure: Copolymers prepared by emulsion or solution copolymerization, initiated by free radicals, of unsaturated copolymerizable monomers, the copolymers being built up from a) 1 - 45% by weight of ethylenically unsaturated carboxylic acids, b) 0.5 - 30% by weight of a surface-active crotonic acid ester, c) 30 - 85% by weight of methacrylic acid esters or acrylic acid esters of aliphatic (C1-C18) alcohols, d) 0 - 40% by weight of other ethylenically unsaturated comonomers, e) 0 - 3% by weight of polyethylenically unsaturated compounds and f) 0 - 5% by weight of molecular weight regulators, and, if appropriate, the free acid groups of the copolymers subsequently having been partly or completely neutralized by addition of bases and converted into watersoluble or colloidally water-dispersible copolymer salts. In addition, processes for the preparation of the copolymers by solution or emulsion copolymerization and, if appropriate, subsequent conversion thereof into the copolymer salts, and the use of the products as viscosity increasing and rheology-modifying substances in aqueous systems, in particular aqueous dispersions, preferably for thickening emulsion paints, emulsion gloss lacquers, textile printing pastes and paper printing pastes, and furthermore as sizing agents in the textile industry.

公开(公告)号：CA1217289A

公开(公告)日：1987-01-27

申请号：CA432565

申请日：1983-07-15

Applicant: HOECHST AG

Inventor： EHMANN WERNER ,  HOMANNER ALFONS ,  RINNO HELMUT

IPC: C08L31/00 ,  C08F2/20 ,  C08F2/24 ,  C08F2/44 ,  C08F18/06 ,  C08F18/08 ,  C08L3/00 ,  C08L29/04 ,  C08L31/04 ,  C09J131/04 ,  C08L3/02 ,  C09J3/06

Abstract: of the disclosure: An aqueous polyvinyl ester dispersion having a solids content of 35 to 65 weight % and containing 3 to 12 weight % (relative to the total amount of dispersed particles) of polyvinyl alcohol and 2 to 70 weight % (relative to the total amount of dispersed particles) of a natural starch has excellent adhesive properties. It is manufactured by emulsion polymerization of a vinyl ester optionally together with comonomers, and by subsequent distribution of the starch in the dispersion obtained by the emulsion polymerization. The dispersion is especially suitable for the manufacture of adhesives for porous substrates.