公开(公告)号：JPH07165542A

公开(公告)日：1995-06-27

申请号：JP31206593

申请日：1993-12-13

Applicant: KAO CORP

Inventor： YOSHIHARA TORU ,  OGAWA MASAHIKO ,  HORICHI HIROKO

IPC: A61K8/00 ,  A61K8/33 ,  A61K8/89 ,  A61K8/891 ,  A61K8/97 ,  A61Q5/10 ,  C08L83/04 ,  A61K7/13

Abstract: PURPOSE:To obtain a hair-dyeing composition excellent in the dyeing effect and making white hair incapable of distinguishing visually by containing a polyphenol compound and an iron salt in one pack and further containing a silicone oil. CONSTITUTION:This hair-dyeing agent composition contains 0.05-2wt.% of a compound selected from a pyrogallol, tannic acid, gallic acid or an ester thereof, and a vegetable extract containing a polyphenols, 0.01-3wt.% of an iron salt (e.g. ferrous sulfate), 0.1-10wt.% of a silicone oil (e.g. an amino-modified silicone) as active ingredients. The hair-dyeing agent composition is preferably further compounded with a propellant and subsequently charged in a pressure-resistant container under anaerobic atmosphere to produce an aerosol type agent. When produced as the aerosol type agent, the composition is especially not deteriorated with air, can uniformly dye hair, can reduce irregular dyeing, and can dye the hair into a desired color in a short time.

公开(公告)号：JPH0678312B2

公开(公告)日：1994-10-05

申请号：JP41266190

申请日：1990-12-21

Applicant: KAO CORP

Inventor： TAMURA TADASHI ,  KYOMINE AKIRA ,  NISHIZAWA YOSHINORI ,  OGAWA MASAHIKO ,  TAGAMI HIDETOSHI ,  YOSHIHARA TOORU ,  KAWASE JIRO

IPC: A61K8/00 ,  A61K8/49 ,  A61Q5/10 ,  C07D213/64 ,  C07D213/73 ,  C09B53/00 ,  D06P3/16 ,  A61K7/13

公开(公告)号：JPH04247018A

公开(公告)日：1992-09-03

申请号：JP3169691

申请日：1991-01-31

Applicant: KAO CORP

Inventor： TAMURA TADASHI ,  KIYOMINE AKIRA ,  NISHIZAWA YOSHINORI ,  TANAKA MICHIO ,  TAGAMI HIDETOSHI ,  YOSHIHARA TORU ,  OGAWA MASAHIKO ,  MURAOKA TSUTOMU ,  KAWASE JIRO

IPC: A61K8/00 ,  A61K8/40 ,  A61K8/41 ,  A61K8/46 ,  A61Q5/10 ,  C07C217/84

Abstract: PURPOSE:To provide a novel aminophenol derivative or a salt thereof having good dyeability, discoloration resistance, washing resistance and abrasion resistance and useful as a coupling substance for obtaining a color tone having a high chroma. CONSTITUTION:An aminophenol derivative of formula 1 (R is lower alkyl; (n) is 2-4), e.g. 2-amino-4-hydroxy-5-methylphenoxyethanol. A nitrophenyl derivative of formula 2 (R is H, alkylsulfonyl, arylsulfonyl) or a salt thereof as an intermediate, e.g. 5'-nitro-4'-(beta-hydroxyethoxy)-2'-methylphenylmethane sulfonate. The compound of formula I is obtained as follows; reacting a compound of formula III with ethylene oxide or an omegahaloalcohol to form a compound of formula II (R is the groups excluding H), hydrolyzing the formed compound of formula II to form the compound of formula II (R is H), and subsequently reducing the formed compound of formula II.

公开(公告)号：JP2009051856A

公开(公告)日：2009-03-12

申请号：JP2008270377

申请日：2008-10-20

Applicant: Kao Corp ,  花王株式会社

Inventor： FUJINUMA HIROYUKI ,  MATSUO TAKASHI ,  OGAWA MASAHIKO ,  KOJIKA TOMOHITO ,  OKADA KAZUHIRO

IPC: A61K8/00 ,  A61K8/81 ,  A61K8/19 ,  A61K8/22 ,  A61K8/33 ,  A61K8/34 ,  A61K8/41 ,  A61K8/42 ,  A61K8/44 ,  A61K8/46 ,  A61K8/60 ,  A61K8/92 ,  A61Q5/00 ,  A61Q5/08 ,  A61Q5/10

CPC classification number: A61K8/046 ,  A61K8/19 ,  A61K8/22 ,  A61K8/342 ,  A61K8/345 ,  A61K8/347 ,  A61K8/411 ,  A61K8/415 ,  A61K8/442 ,  A61K8/463 ,  A61K2800/4324 ,  A61K2800/88 ,  A61K2800/882 ,  A61Q5/08 ,  A61Q5/10

Abstract: PROBLEM TO BE SOLVED: To provide a hair cosmetic product which can exhibit a sufficient bleaching power or a hair-dyeing power by preventing bleaching unevenness or dyeing unevenness by spraying a hair bleach or a hair dye in the form of foam from a non-aerosol type foamer container. SOLUTION: The hair cosmetic product comprises a two-component hair cosmetic comprising a first component containing an alkali agent and a second component containing hydrogen peroxide wherein at least either of the first and second components contains a surfactant and a foamer container that sprays a mixture of the first and second components in the form of foam. In another embodiment, the hair cosmetic product comprises a two-component hair cosmetic comprising a first component containing an alkali agent and a second component containing hydrogen peroxide and is used by mixing the first and second components with each other by mixing them just before use and a foamer container that sprays a mixture of the first and second components in the form of foam, wherein the mixture contains 0.1-10 wt.% surfactant and has viscosity of 1-300 mPa s at 25°C. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 待解决的问题：提供一种头发美容产品，其可以通过以下方式喷洒头发漂白剂或泡沫形式的染发剂从而防止漂白不均匀或染色不均匀，从而可以显示出足够的漂白力或染发力 非气溶胶型发泡容器。 解决方案：毛发化妆品包括双组分毛发化妆品，其包含含有碱剂的第一组分和含有过氧化氢的第二组分，其中第一组分和第二组分中的至少一种含有表面活性剂和喷雾剂 泡沫形式的第一和第二组分的混合物。 在另一个实施方案中，毛发化妆品包括双组分毛发化妆品，其包含含有碱剂的第一组分和含有过氧化氢的第二组分，并且通过在使用前混合第一组分和第二组分彼此混合使用而使用， 以泡沫形式喷射第一和第二组分的混合物的起泡容器，其中混合物含有0.1-10重量％的表面活性剂，并且在25℃下具有1-300mPa·s的粘度。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2007314524A

公开(公告)日：2007-12-06

申请号：JP2007115215

申请日：2007-04-25

Applicant: Kao Corp ,  花王株式会社

Inventor： FUJINUMA HIROYUKI ,  MATSUO TAKASHI ,  OGAWA MASAHIKO ,  HANSAKI TSUYOSHI ,  SAIMIYA HIROMI

IPC: A61K8/22 ,  A61K8/34 ,  A61K8/88 ,  A61Q5/08 ,  A61Q5/10

Abstract: PROBLEM TO BE SOLVED: To provide a foam two-pack type hair decolorant or two-pack type hair dye, causing no scalp stimulation even when suppressing the content of a low-nonvolatile hydrophilic solvent and having high hair dying ability and decoloring ability.
SOLUTION: The two-pack type hair cosmetic comprises a first agent containing an alkali agent, a second agent containing hydrogen peroxide and a foamer container for frothily ejecting the mixture liquid of the first agent and the second agent, and contains following ingredients (A) and (B) in the mixture liquid: (A) 1-15 wt.% surfactant, and (B) 0.1-5 wt.% nonvolatile hydrophilic solvent, wherein the weight ratio of the component (A) to the component (B) [content of the component (A)/content of the component (B)] is 1-20.
COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：为了提供泡沫双组分型毛发脱色剂或双组分型染发剂，即使在抑制低挥发性亲水溶剂的含量并具有高染发能力和脱色的情况下也不引起头皮刺激 能力。 解决方案：双组分型毛发化妆品包括含有碱剂的第一试剂，含有过氧化氢的第二试剂和用于使第一试剂和第二试剂混合液体起泡的起泡容器，并含有以下成分 （A）和（B）混合液体中的组分（A）：（A）1-15重量％表面活性剂和（B）0.1-5重量％非挥发性亲水溶剂，其中组分（A） （B）[成分（A）的含量/成分（B）的含量）]为1-20。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2007217293A

公开(公告)日：2007-08-30

申请号：JP2006036194

申请日：2006-02-14

Applicant: Kao Corp ,  花王株式会社

Inventor： NAOI YUKI ,  SAITO YOSHINORI ,  MIYABE SO ,  OGAWA MASAHIKO ,  MATSUO TAKASHI

IPC: A61K8/22 ,  A61K8/06 ,  A61Q5/08 ,  A61Q5/10

Abstract: PROBLEM TO BE SOLVED: To provide a second agent composition for hair dyeing or hair bleaching, excellent in preservation stability and mixing property with a first agent, without sticking on applying to the hair after mixing, excellent in extensibility and having a good compatibility with the hair and excellent in bleaching property.
SOLUTION: This second agent for hair-dyeing or hair-bleaching, used by mixing with the first agent composition containing an alkaline agent is provided by containing the following components (a) to (c): (a) 2 to 18 wt.% of a surfactant; (b) 10 to 50 wt.% of an oily component; and (c) 0.1 to 12 wt.% of an oxidant based on hydrogen peroxide. Further, the agent contains (a1) 1.5 to 9.5 wt.% of a non-ionic surfactant having at least 12 to 17 HLB as the component (a) in the second agent, and has the weight ratio of the (b)/(a) in the range of 1 to 10 and ≤50 μm volume-average particle diameter of emulsion particles.
COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 待解决的问题：为了提供用于染发或脱毛的第二药剂组合物，与第一药剂的保存稳定性和混合性优异，不粘附于混合后的毛发上，具有优异的延展性和良好的 与头发兼容，漂白性能优异。 通过含有以下组分（a）至（c）：（a）2至18（a）至（c））来提供通过与含有碱性试剂的第一试剂组合物混合使用的用于染发或毛发漂白的第二试剂： 重量％的表面活性剂; （b）10〜50重量％的油性成分; 和（c）0.1至12重量％的基于过氧化氢的氧化剂。 此外，该试剂含有（a1）1.5〜9.5重量％的第二试剂中具有至少12-17个HLB作为组分（a）的非离子表面活性剂，其重量比（b）/（ a）在乳液颗粒的体积平均粒径为1至10和≤50μm的范围内。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2005194202A

公开(公告)日：2005-07-21

申请号：JP2003435728

申请日：2003-12-26

Applicant: Kao Corp ,  花王株式会社

Inventor： OGAWA MASAHIKO ,  FUJINUMA HIROYUKI ,  NOBEMOTO KAZUNORI ,  MIYABE SO ,  SAKAMOTO KEIJI

IPC: A61K8/00 ,  A61K8/22 ,  A61K8/34 ,  A61Q5/08 ,  A61Q5/10 ,  A61K7/13

Abstract: PROBLEM TO BE SOLVED: To prepare a two-pack type hair cosmetic which uses an aerosol container comprising an outer can and a plurality of resin-made flexible inner containers stored in the outer can, inhibits the decomposition of hydrogen peroxide contained in the second agent, when receiving the first agent containing an evaporable alkali agent in one of the resin-made flexible inner containers and receiving the second agent containing the hydrogen peroxide in the other, and exhibits good dyeability and bleachability.
SOLUTION: This two-pack type hair cosmetic comprises the first agent comprising an aqueous medium and an evaporable alkali agent contained in the aqueous medium, and the second agent comprising an aqueous medium and hydrogen peroxide contained in the aqueous medium. The second agent contains an acid compound having an acid dissociation index pKa of 2 to 5 at 25°C and its salt in a total amount of 0.001 to 1 mol/kg, and has pH 2 to 5, and the first agent and the second agent are separately received in the resin-made flexible containers, respectively, stored in the outer can of the aerosol container to be simultaneously discharged.
COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：为了制备使用包含外罐和存储在外罐中的多个树脂制柔性内容器的气溶胶容器的双组分型毛发化妆品，抑制包含在其中的过氧化氢的分解 第二剂，当在其中一个树脂制柔性内容器中接收含有可蒸发碱剂的第一试剂并且另外接收含有过氧化氢的第二试剂时，显示出良好的可染性和漂白性。 解决方案：这种双组分型毛发化妆品包括第一试剂，其包含水性介质和包含在水性介质中的可蒸发碱性试剂，第二试剂包含水性介质中所含的水性介质和过氧化氢。 第二试剂含有在25℃下酸解离指数pKa为2〜5的酸性化合物，其盐的总量为0.001〜1mol / kg，pH为2〜5，第1剂和第2剂 药剂分别容纳在树脂制柔性容器中，储存在气溶胶容器的外罐中以同时排出。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2002179539A

公开(公告)日：2002-06-26

申请号：JP2000378806

申请日：2000-12-13

Applicant: KAO CORP

Inventor： OGAWA MASAHIKO ,  HORI TAKASHI ,  MATSUO TAKASHI

IPC: A61K8/00 ,  A61Q5/08 ,  A61Q5/10 ,  A61K7/13

Abstract: PROBLEM TO BE SOLVED: To obtain a hair dye agent composition having a slight pungent odor, a low irritation, with which the hair can be made in a light color tone in a short time and excellently dyed from a light color to a deep color and the obtained color tone has an excellent color duration. SOLUTION: This hair dye agent composition comprises (A) 0.01-3 mol/kg of ammonia or an ammonium salt, (B) 0.001-1 mol/kg of a carbonate (except the ammonium salt), (C) 0.1-10,000 ppm of a transition metal salt and (D) a chelating agent in the molar ratio of the component [(A)/(B)] of the component A to the component of 0.1-5 and has pH 8.5-12.

公开(公告)号：JPH1129443A

公开(公告)日：1999-02-02

申请号：JP18363497

申请日：1997-07-09

Applicant: KAO CORP

Inventor： KAWAAI TETSUYA ,  OGAWA MASAHIKO ,  GO NAOHISA

IPC: A61K8/00 ,  A61K8/34 ,  A61K8/41 ,  A61K8/43 ,  A61Q5/00 ,  A61Q5/08 ,  A61Q5/10 ,  A61K7/06 ,  A61K7/13

Abstract: PROBLEM TO BE SOLVED: To obtain the subject hair treatment composition that can readily brighten the color tone of hair in a shortened time with sufficient docoloring power or dye the hair in a good hue with extremely reduced irritant odor and reduced irritation to the scalp. SOLUTION: This hair-treatment composition contains (A) an alkaline agent as ammonia, alkanolamine, guanidium salt and (B) an aromatic alcohol of the formula (n is 0, 1; if n=0, X is a 2-6C alkylene; if n=1, X, Y are each a 1-6C alkylene) in a proportion of 0. 01-20 wt.% (A) and 0.1-30 wt.% (B). In addition an intermediate of oxidation dye may be added thereto. The objective composition is used in combination with an oxidizing agent as hydrogen peroxide, and shows excellent color fastness to shampoo with excellent color retention.

公开(公告)号：JPH0733630A

公开(公告)日：1995-02-03

申请号：JP17808293

申请日：1993-07-19

Applicant: KAO CORP

Inventor： OGAWA MASAHIKO ,  ASAMI MICHIKO ,  YOSHIHARA TORU

IPC: A61K8/00 ,  A61K8/40 ,  A61K8/41 ,  A61K8/89 ,  A61K8/891 ,  A61K8/893 ,  A61Q5/00 ,  A61Q5/08 ,  A61Q5/10 ,  C08K5/17 ,  C08L83/08 ,  A61K7/135

Abstract: PURPOSE:To obtain the composition by combining an oxidizing agent, a specific silicone derivative, a specific long-chain monoalkyl type quaternary ammonium salt and a specific longchain dialkyl type quaternary ammonium salt and/or a branched alkyl type quaternary ammonium salt, CONSTITUTION:The hair treatment agent is prepared by combining an oxidizing agent with (A) a silicone derivative selected from modified silicones having alkoxy groups in their molecules and melting over 30 deg.C, dimethylpolysiloxanes having more than 1,000,000cs viscosity at 25 deg.C and methylphenylpolysiloxanes, (B) a long-chain monoalkyl type quaternary ammonium salt of formula I (R is alkyl; R to R are alkyl, benzyl; X is halogen, alkylsulfate), (C) a compound selected from long-chain dialkyl type quaternary ammonium salts of formula II (R , R are 8 to 22C alkyl; R , R is 1 to 3C alkyl) and branched alkyl type quaternary ammonium salts of formula III (R , R are 2 to 16 C alkyl; R is formula IV, alkyl; R , R are 1 to 3C alkyl). The composition can protect hairs from being damaged and provide nice touch feeling.