公开(公告)号：BR8501947A

公开(公告)日：1985-12-24

申请号：BR8501947

申请日：1985-04-24

Applicant: STANDARD OIL CO OHIO

Inventor： TENHOVER MICHAEL ALAN ,  GRASSELLI ROBERT KARL ,  HARRIS JONATHAN H ,  WARD MICHAEL D

IPC: C22C45/00 ,  H01M4/86 ,  H01M4/92 ,  C25B11/08 ,  C25C7/02 ,  C25D17/10

公开(公告)号：IN171851B

公开(公告)日：1993-01-23

申请号：IN547DE1986

申请日：1986-06-24

Applicant: STANDARD OIL CO OHIO

Inventor： HARRIS JONATHAN HENRY ,  TENHOVER MICHAEL ALAN ,  GRASSELLI ROBERT KARL

IPC: C25B11/10 ,  C22C45/00 ,  C25B11/04 ,  C25B11/08 ,  C22C28/00

Abstract: Novel rhodium based amorphous metal alloys having the formula RhrAa where: A is B, P, As and mixtures thereof; r is from about 50 to 96 percent; and a is from about 4 to 50 percent. Novel rhodium based amorphous metal alloys are also based on the formula RhrBbDd where: D is Ir, Pd, Ru, Ti, Zr, Nb, Ta, Y, Hf and mixtures thereof; r is from about 50 to 96 percent; b is from about 4 to 50 percent; and d is from about 0 to 60 percent; and r + b + d = 100. Novel process for the generation of halogens from halide-containing solutions can be performed by employing the rhodium based metal alloys of the present invention.

公开(公告)号：IN167302B

公开(公告)日：1990-10-06

申请号：IN272DE1986

申请日：1986-03-21

Applicant: STANDARD OIL CO OHIO

Inventor： HENDERSON RICHARD SCOTT ,  GRASSELLI ROBERT KARL ,  TENHOVER MICHAEL ALAN ,  HARRIS JONATHAN HENRY

IPC: H01M4/38 ,  C01B3/00 ,  C22C45/10 ,  C22C24/00

Abstract: Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formula A8MbM min c wherein A is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt; M is at least one element selected from the group consisting of: Ru, Pb, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; and M min is at least one element selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; and wherein a ranges from about 0.005 to about 0.80; b ranges from about 0.05 to about 0.70; and c ranges from about 0.08 to about 0.95.

公开(公告)号：DE3577817D1

公开(公告)日：1990-06-28

申请号：DE3577817

申请日：1985-03-01

Applicant: STANDARD OIL CO OHIO

Inventor： TENHOVER MICHAEL ALAN ,  FOX JOSEPH ROBERT ,  HENDERSON RICHARD SCOTT

IPC: B22F1/00 ,  B22F3/00 ,  B22F9/00 ,  B22F9/24 ,  C22C1/04

Abstract: Amorphous metal alloy powders are synthesised by a solid state reaction. Such reaction may comprise disposing at least one metal-bearing compound in a liquid medium and reducing the metal-bearing compound so as to obtain a substantially amorphous metal alloy. Precursor components that include the elements of the amorphous alloy are chemically reduced to yield an intimate mixture. The resultant intimate mixture, as obtained or after heat-treating, exhibits amorphous characteristics. These powders are suitable for forming solid amorphous shapes.

公开(公告)号：IN166147B

公开(公告)日：1990-03-17

申请号：IN260DE1986

申请日：1986-03-20

Applicant: STANDARD OIL CO OHIO

Inventor： TENHOVER MICHAEL ALAN ,  HENDERSON RICHARD SCOTT ,  GRASSELLI ROBERT KARL

IPC: B22F9/20 ,  B22F9/00 ,  B22F9/16 ,  C22C1/00 ,  C22C33/00 ,  C22C45/00 ,  C22C29/00

Abstract: Amorphous metal alloy compositions are synthesized by solid state incorporation/reduction reactions wherein a high-surface area support is brought in contact with a precursor metal-bearing compound in such a manner that the compound is incorporated into the support or caused to deposit metal onto the surface of the support. The composition obtained is an amorphous alloy composition or can be made so by heat treating at a temperature below the crystallization temperature of the amorphous metal alloy desired to be formed.

公开(公告)号：BR8606251A

公开(公告)日：1988-01-12

申请号：BR8606251

申请日：1986-12-17

Applicant: STANDARD OIL CO OHIO

Inventor： TENHOVER MICHAEL ALAN ,  HARRIS JONATHAN HENRY ,  GRASSELLI ROBERT KARL

IPC: C22C5/04 ,  C22C45/00 ,  C25B11/04 ,  C25B1/24

Abstract: Anodes comprising substrate materials coated with iridium based amorphous metal alloys having the formulae IriDdEeFf and IriYyDdEeFf where D is Ti, Zr, Nb, Ta, Ru, W, Mo and mixtures thereof; E is C, B, Si, P, Al, Ge, As, N, Sb and mixtures thereof; F is Rh, Pt, Pd, and mixtures thereof; i is from about 35 to 96 or 50 to 95, respectively; y is 4 to 40; d is 0 to 40; e is 4 to 40; f is 0 to 45; and i + d + e + f = 100, i + y + d + e + f = 100 and if E is Si and/or P, then B is also present. A process for the use of the foregoing iridium based alloys as anodes for the electrolysis of halide-containing electrolyte solutions is also provided.

公开(公告)号：NO863240L

公开(公告)日：1987-11-30

申请号：NO863240

申请日：1986-08-12

Applicant: STANDARD OIL CO OHIO

Inventor： TENHOVER MICHAEL ALAN ,  GRASSELLI ROBERT KARL ,  HARRIS JONATHAN HENRY

IPC: C22C5/04 ,  C22C45/00 ,  C25B11/04 ,  C25B11/00 ,  C22C

Abstract: Anodes comprising substrate materials coated with iridium based amorphous metal alloys having the formulae IriDdEeFf and IriYyDdEeFf where D is Ti, Zr, Nb, Ta, Ru, W, Mo and mixtures thereof; E is C, B, Si, P, Al, Ge, As, N, Sb and mixtures thereof; F is Rh, Pt, Pd, and mixtures thereof; i is from about 35 to 96 or 50 to 95, respectively; y is 4 to 40; d is 0 to 40; e is 4 to 40; f is 0 to 45; and i + d + e + f = 100, i + y + d + e + f = 100 and if E is Si and/or P, then B is also present. A process for the use of the foregoing iridium based alloys as anodes for the electrolysis of halide-containing electrolyte solutions is also provided.

公开(公告)号：ZA8606508B

公开(公告)日：1987-04-29

申请号：ZA8606508

申请日：1986-08-27

Applicant: STANDARD OIL CO OHIO

Inventor： TENHOVER MICHAEL ALAN ,  HARRIS JONATHAN HENRY ,  GRASSELLI ROBERT KARL

IPC: C22C5/04 ,  C22C45/00 ,  C25B11/04 ,  C25B ,  C01B

CPC classification number: C22C45/003 ,  C25B11/0478 ,  C25B11/0494

公开(公告)号：ZA8503216B

公开(公告)日：1987-01-28

申请号：ZA8503216

申请日：1985-04-30

Applicant: STANDARD OIL CO OHIO

Inventor： HARRIS JONATHAN H ,  TENHOVER MICHAEL ALAN ,  GRASSELLI ROBERT KARL ,  WARD MICHAEL D

IPC: C25B11/08 ,  C25B20060101 ,  C25B1/46 ,  C25B11/02 ,  C25B11/04 ,  C25C20060101 ,  H01M20060101 ,  C25B ,  C25C ,  H01M

公开(公告)号：BR8501997A

公开(公告)日：1985-12-31

申请号：BR8501997

申请日：1985-04-26

Applicant: STANDARD OIL CO OHIO

Inventor： TENHOVER MICHAEL ALAN ,  GRASSELLI ROBERT KARL

IPC: C02F1/461 ,  C02F1/467 ,  C22C45/00 ,  C25B11/04 ,  C25B11/08 ,  H01M4/86 ,  H01M4/90 ,  H01M4/92 ,  C25B1/24

Abstract: A process for the generation of halogens from halide-containing solutions includes the step of conducting electrolysis of the solutions in an electrolytic cell having a platinum based amorphous metal alloy anode having the formulawhereA is Cr, Mo, W, Fe, Os, Cu, Ni, Ag, V, Au and mixtures thereof;D is B, Si, Al, Ge, P, As, Sb, Sn and mixtures thereof;P ranges from about 40 to 92;a ranges from about 0 to 40; andd ranges from about 8 to 60, with the proviso thatSuch amorphous metal alloy anodes are also based on the formulawhereE is Cr, Mo, W, Fe, Os, Ir, Cu, Ni, Rh, Pd, Ag, Ti, Ru, Nb, V, Ta, Au and mixtures thereof;F is B, AI, Ge, As, Sb, Sn and mixtures thereof;P ranges from about 40 to 92;e ranges from about 0 to 40; andf ranges from about 8 to 60, with the proviso that