Abstract:
A process for the efficient transfer of molecules between phases employing mesoporous poly (aryl ether ketone) hollow fiber membranes is provided. The method addresses the controlled transfer of reactants into and removal of reaction products from a reaction media and the removal and separation of target molecules from process streams by membrane-assisted liquid-liquid extraction. A number of possible modes of liquid-liquid extraction are possible according to the invention by utilizing porous poly (aryl ether ketone) hollow fiber membranes of Janus-like structure that exhibit a combination of hydrophilic and hydrophobic surface characteristics. The method of the present invention can address the continuous manufacture of chemicals in membrane reactors and is useful for a broad range of separation applications, including separation and recovery of active pharmaceutical ingredients.
Abstract:
Provided are porogen compositions and methods of using such porogen compositions in the manufacture of porous materials, for example, porous silicone elastomers. The porogens generally include comprising a core material and shell material different from the core material. The porogens can be used to form a scaffold for making a resulting porous elastomer when the scaffold is removed.
Abstract:
The present specification discloses porous materials, methods of forming such porous materials, materials and devices comprising such porous materials, and methods of making such materials and devices.
Abstract:
Polymeric particles are provided that have pores (i.e., free volume or voids). The polymeric particles can be used to store or deliver active agents that are adsorbed in the pores of the polymeric particles. In many embodiments, the active agents are hydrophobic. Reaction mixtures and methods of forming the polymeric particles from the reaction mixtures are also provided.
Abstract:
Functionalized porous poly(aryl ether ketone) articles are prepared by reacting ketone groups in the backbone of poly(aryl ether ketone) polymer with a primary amine reagent. Preferred functional primary amines are primary aliphatic amines or substituted hydrazines containing one or more target functional groups including polar groups, such as hydroxyl groups, ˜OH, amino groups, ˜NH2, ˜NHR, ˜NRR′, and ethylene oxide groups, ˜OCH2CH2—, negatively or positively charged ionic groups, such as ˜SO3−, ˜COO−, and ˜NH4+ groups, hydrophobic groups such as siloxane or perfluorcarbone groups, and non-polar groups, such as linear or branched hydrocarbon groups. The functionalized porous poly(aryl ether ketone) article can be prepared by reacting primary amine with a pre-formed, shaped porous poly(aryl ether ketone) article or by functionalizing the surface of a non-porous precursor article that is subsequently converted into a porous article.
Abstract:
A method for removing hydrocarbon products from water surfaces, which entails contacting the hydrocarbon products with a crystalline polypropylene, which when observed under a microscope of 2500 magnetization, exhibits a spongy surface having relatively homogeneous intercommunicating pores, with dimensions of between about 3 &mgr;m and 20 &mgr;m in diameter.
Abstract:
A process is provided which allows economical production of polyolefin separation membranes having various structures, porosities and pore sizes. The process involves using a melt blend solution consisting of a polyolefin such as polypropylene or polyethylene and a diluent selected from the group consisting of natural soybean oil, pure linoleic acid, or a mixtures of oleic acid, linoleic acid and palmitic acid.
Abstract:
Targets for high energy beams, such as laser beams, produced in laser fusion apparatus are described. The targets are porous spheres of deuterated hydrocarbon material, particularly deuterated polyethylene. The spheres are small and have diameters in the range of 50 to 300 microns. Higher neutron yields are obtained from these targets than from solid targets of similar materials, (viz., spherical targets of much higher density). Methods of fabricating the targets by forming them into solid spheres, cross linking their molecules and causing them to swell such that the resultant targets have a microscopically small sponge-like structure, are also described. These micro-sponge targets may be treated by being exposed to tritium gas so as to undergo tritium deuterium exchange which is of enhanced efficiency by virtue of their porous, sponge-like structure. The porous sponge-like targets of deuterated, tritiated material may be stored under liquid to enhance their stability by absorption of their own beta radiation.
Abstract:
Polymeric particles are provided that have pores (i.e., free volume or voids). The polymeric particles can be used to store or deliver active agents that are adsorbed in the pores of the polymeric particles. In many embodiments, the active agents are hydrophobic. Reaction mixtures and methods of forming the polymeric particles from the reaction mixtures are also provided.