公开(公告)号：US20170130089A1

公开(公告)日：2017-05-11

申请号：US15413703

申请日：2017-01-24

Applicant: MATERIA, INC.

Inventor： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Mark S. TRIMMER ,  Michael A. GIARDELLO

IPC: C09D143/00

CPC classification number: C09D143/00 ,  C09D143/04

Abstract: A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

公开(公告)号：US20080269402A1

公开(公告)日：2008-10-30

申请号：US12082326

申请日：2008-04-10

Applicant: Alvin Michael Maurice ,  David Gerald Speece ,  Jiakuan Sun ,  Huiling Yang

Inventor： Alvin Michael Maurice ,  David Gerald Speece ,  Jiakuan Sun ,  Huiling Yang

IPC: C08F30/02 ,  C08L43/02

CPC classification number: C08F220/14 ,  C08F212/08 ,  C08F212/14 ,  C08F220/18 ,  C08F220/58 ,  C08F230/02 ,  C08F230/08 ,  C08L2201/50 ,  C09D143/00 ,  C09D143/02 ,  C09D143/04

Abstract: An aqueous copolymer dispersion, wherein said copolymer is obtained from a mixture of monomers comprising, in percentage by weight based on the dry weight of copolymer: a) 89 to 99.93% at least one ethylenically unsaturated nonionic monomer, b) 0.05 to 5% at least one ethylenically unsaturated phosphorus containing monomer without phosphonate functional group, or salts thereof, c) 0.01 to 3% at least one ethylenically unsaturated monomer carrying at least one alkoxysilane functionality, and d) 0.01 to 3% at least one ethylenically unsaturated monomer carrying at least one functionality selected from sulfur based acids, or the salts thereof.

Abstract translation: 一种水性共聚物分散体，其中所述共聚物由单体混合物得到，所述单体包括基于共聚物干重的重量百分比：a）89-99.93％至少一种烯属不饱和非离子单体，b）0.05-5％ 至少一种不含膦酸酯官能团的烯属不饱和磷单体或其盐，c）0.01至3％至少一种含有至少一个烷氧基硅烷官能团的烯键式不饱和单体，和d）至少一种含有至少一种烯键式不饱和单体 选自硫酸的至少一种官能团或其盐。

公开(公告)号：US06517910B2

公开(公告)日：2003-02-11

申请号：US09777995

申请日：2001-02-06

Applicant: Robin E. Wright ,  George F. Vesley

Inventor： Robin E. Wright ,  George F. Vesley

IPC: C08F248

CPC classification number: C09J143/04 ,  C08F2/50 ,  C08F290/06 ,  C08F290/061 ,  C08F290/068 ,  C08F290/14 ,  C08F290/141 ,  C08F290/148 ,  C09D4/00 ,  C09D4/06 ,  C09D143/00 ,  C09J2400/228 ,  Y10T428/2839 ,  Y10T428/31504 ,  C08F230/08

Abstract: In one aspect the invention provides an energy efficient polymerization method comprising irradiating a polymerizable composition and a photoinitiator with a source of essentially monochromatic radiation where the photoinitiator and the wavelength of the radiation source are selected such that the extinction coefficient of the photoinitiator at the peak wavelength of the source is greater than about 1000 M−1 cm−1 and such that the photoinitiator absorbs at least two percent of the actinic radiation incident on the coating. In another aspect the invention provides energy efficient methods of polymerizing polymerizable compositions and crosslinking crosslinkable compositions by irradiating the respective compositions with a low power source of essentially monochromatic radiation. The low power energy sources have an input power of less than about 10 W/cm. Articles made from the above methods, including polymer films having release coatings, adhesive coatings, hard coatings and the like thereon, also are provided.

Abstract translation: 在一个方面，本发明提供了一种能量有效的聚合方法，其包括用基本上单色辐射源照射可聚合组合物和光引发剂，其中光引发剂和辐射源的波长被选择为使得光引发剂在峰值波长处的消光系数 的源大于约1000M-1cm -1，并且使得光引发剂吸收入射在涂层上的至少2％的光化辐射。另一方面，本发明提供了聚合可聚合组合物和交联可交联组合物的能量有效的方法 通过用基本上单色辐射的低功率源照射各组合物。 低功率能源的输入功率小于约10W / cm。还提供了由上述方法制成的制品，包括其上具有剥离涂层的聚合物膜，粘合剂涂层，硬涂层等。

公开(公告)号：US20010031798A1

公开(公告)日：2001-10-18

申请号：US09777995

申请日：2001-02-06

Applicant: 3M Innovative Properties Company

Inventor： Robin E. Wright ,  George F. Vesley

IPC: C08F002/46 ,  C08J007/04 ,  C08J003/28

CPC classification number: C09J143/04 ,  C08F2/50 ,  C08F290/06 ,  C08F290/061 ,  C08F290/068 ,  C08F290/14 ,  C08F290/141 ,  C08F290/148 ,  C09D4/00 ,  C09D4/06 ,  C09D143/00 ,  C09J2400/228 ,  Y10T428/2839 ,  Y10T428/31504 ,  C08F230/08

Abstract: In one aspect the invention provides an energy efficient polymerization method comprising irradiating a polymerizable composition and a photoinitiator with a source of essentially monochromatic radiation where the photoinitiator and the wavelength of the radiation source are selected such that the extinction coefficient of the photoinitiator at the peak wavelength of the source is greater than about 1000 Mnull1 cmnull1 and such that the photoinitiator absorbs at least two percent of the actinic radiation incident on the coating. In another aspect the invention provides energy efficient methods of polymerizing polymerizable compositions and crosslinking crosslinkable compositions by irradiating the respective compositions with a low power source of essentially monochromatic radiation. The low power energy sources have an input power of less than about 10 W/cm. Articles made from the above methods, including polymer films having release coatings, adhesive coatings, hard coatings and the like thereon, also are provided.

Abstract translation: 在一个方面，本发明提供了一种能量有效的聚合方法，其包括用基本上单色辐射源照射可聚合组合物和光引发剂，其中光引发剂和辐射源的波长被选择为使得光引发剂在峰值波长处的消光系数 的源大于约1000M-1cm -1，并且使得光引发剂吸收入射在涂层上的至少2％的光化辐射。 在另一方面，本发明提供了通过用基本上单色辐射的低功率源照射各组合物来聚合可聚合组合物和交联可交联组合物的能量效率方法。 低功率能源的输入功率小于约10W / cm。 还提供了由上述方法制成的制品，包括其上具有剥离涂层的聚合物膜，粘合剂涂层，硬涂层等。

公开(公告)号：US20160046827A1

公开(公告)日：2016-02-18

申请号：US14779902

申请日：2014-04-07

Applicant: MITSUI CHEMICALS, INC.

Inventor： Koju OKAZAKI ,  Takayuki HANAWA ,  Shigetoshi KUMA

IPC: C09D133/26

CPC classification number: C09D133/26 ,  B32B27/283 ,  B32B2307/21 ,  B32B2307/554 ,  B32B2307/712 ,  B32B2307/718 ,  B32B2307/728 ,  B32B2551/00 ,  C09D5/02 ,  C09D5/16 ,  C09D5/1668 ,  C09D7/40 ,  C09D133/068 ,  C09D133/14 ,  C09D143/00 ,  C09D143/04 ,  C09D201/10

Abstract: Provided are a film in which the balance between hydrophilicity and abrasion resistance is superior, decrease in hydrophilicity by water is minimal, and the weather resistance is also superior; as well as a polymer and a polymer composition that can yield such a film. The film of the invention is prepared from a specific copolymer (i) having a sulfonic acid-containing group, an epoxy group, and a specific alkoxysilyl group in a molecule, or from a composition including the copolymer (i).

Abstract translation: 提供亲水性和耐磨性之间的平衡优异的膜，水的亲水性降低最小，耐候性也优异; 以及可产生这种膜的聚合物和聚合物组合物。 本发明的膜由分子中具有含磺酸基，环氧基和特定烷氧基甲硅烷基的特定共聚物（i）或包含共聚物（i）的组合物制备。

公开(公告)号：US07897261B2

公开(公告)日：2011-03-01

申请号：US11178548

申请日：2005-07-11

Applicant: John W. Burgman ,  Simion Coca ,  Edward R. Coleridge ,  Heather L. Lim ,  Karen A. Morow ,  Jane N. Valenta

Inventor： John W. Burgman ,  Simion Coca ,  Edward R. Coleridge ,  Heather L. Lim ,  Karen A. Morow ,  Jane N. Valenta

IPC: B32B27/32 ,  C08F2/00

CPC classification number: C09D143/00 ,  C08L33/068 ,  C08L2312/00 ,  Y10T428/31504 ,  Y10T428/31855 ,  Y10T428/31938 ,  C08L2666/04

Abstract: A coating composition is provided comprising (a) a polymer containing reactive functional groups; (b) a curing agent having reactive functional groups that are reactive with the functional groups in the polymer in (a); and (c) a polymeric material different from (a) and (b) having functional groups. The functional groups in components (a) and (b) are more reactive with each other than with the functional groups in component (c) such that upon curing, at least a portion of the functional groups on component (c) remain unreacted. A coating layer formed from the composition upon application to a substrate has surface regions and a bulk region, and the concentration of component (c) at one or more surface regions is greater than the concentration of component (c) in the bulk region of the coating layer. The composition can be used in multi-layer composites containing two or more coating layers.

Abstract translation: 提供涂料组合物，其包含（a）含有反应性官能团的聚合物; （b）具有与（a）中的聚合物中的官能团反应的反应性官能团的固化剂; 和（c）不同于具有官能团的（a）和（b）的聚合物材料。 组分（a）和（b）中的官能团与组分（c）中的官能团相比更具反应性，使得在固化后，组分（c）上至少一部分官能团保持未反应。 由涂布到基材上的组合物形成的涂层具有表面区域和体积区域，并且在一个或多个表面区域的组分（c）的浓度大于组分（c）在本体区域中的浓度 涂层。 该组合物可用于含有两层或多层涂层的多层复合材料。

公开(公告)号：US20100243221A1

公开(公告)日：2010-09-30

申请号：US12600198

申请日：2008-05-15

Applicant: Sumiaki Yamasaki ,  Satoshi Tanaka ,  Yuichiro Murayama ,  Yoshiaki ` Kondo

Inventor： Sumiaki Yamasaki ,  Satoshi Tanaka ,  Yuichiro Murayama ,  Yoshiaki ` Kondo

IPC: F28F19/02 ,  C08L83/05 ,  C08K5/05 ,  C08L67/00 ,  C08L75/04 ,  C08L63/00 ,  B32B15/08 ,  B32B15/092

CPC classification number: C09D143/04 ,  C09D5/00 ,  C09D5/165 ,  C09D143/00 ,  C09D201/10 ,  Y10T428/31529 ,  Y10T428/31605 ,  Y10T428/31678

Abstract: To provide a hydrophilic coating composition excellent in hydrophilicity, wear resistance, transparency, storage stability, antifogging properties, antifouling properties, visible light transmittivity, adhesion properties, chemical resistance, weather resistance, and water resistance and a hydrophilic member using the composition. The hydrophilic coating composition has (A) a ternary copolymer having a1) a repeating unit having a hydrophilic group, a2) a repeating unit having a hydroxyl group, an epoxy group, an isocyanato group, a blocked isocyanato group, a carboxylic acid anhydride group, or an amino group, and a3) a repeating unit having a hydrolyzable silyl group; and (B) a metal complex catalyst, wherein a content of the repeating unit a1) having a hydrophilic group is 50 mol % or greater.

Abstract translation: 提供亲水性，耐磨性，透明性，保存稳定性，防雾性，防污性，可见光透过性，粘合性，耐化学性，耐候性和耐水性以及使用该组合物的亲水性成分优异的亲水性涂料组合物。 亲水性涂料组合物具有（A）具有a1）具有亲水基团的重复单元的三元共聚物，a2）具有羟基的重复单元，环氧基，异氰酸基，封端异氰酸酯基，羧酸酐基 或氨基，和a3）具有可水解甲硅烷基的重复单元; 和（B）金属配合物催化剂，其中亲水基团的重复单元a1）的含量为50摩尔％以上。

公开(公告)号：US20070009740A1

公开(公告)日：2007-01-11

申请号：US11178548

申请日：2005-07-11

Applicant: John Burgman ,  Simion Coca ,  Edward Coleridge ,  Heather Lim ,  Karen Morow ,  Jane Valenta

Inventor： John Burgman ,  Simion Coca ,  Edward Coleridge ,  Heather Lim ,  Karen Morow ,  Jane Valenta

IPC: B32B27/00

CPC classification number: C09D143/00 ,  C08L33/068 ,  C08L2312/00 ,  Y10T428/31504 ,  Y10T428/31855 ,  Y10T428/31938 ,  C08L2666/04

Abstract: A coating composition is provided comprising (a) a polymer containing reactive functional groups; (b) a curing agent having reactive functional groups that are reactive with the functional groups in the polymer in (a); and (c) a polymeric material different from (a) and (b) having functional groups. The functional groups in components (a) and (b) are more reactive with each other than with the functional groups in component (c) such that upon curing, at least a portion of the functional groups on component (c) remain unreacted. A coating layer formed from the composition upon application to a substrate has surface regions and a bulk region, and the concentration of component (c) at one or more surface regions is greater than the concentration of component (c) in the bulk region of the coating layer. The composition can be used in multi-layer composites containing two or more coating layers.

Abstract translation: 提供涂料组合物，其包含（a）含有反应性官能团的聚合物; （b）具有与（a）中的聚合物中的官能团反应的反应性官能团的固化剂; 和（c）不同于具有官能团的（a）和（b）的聚合物材料。 组分（a）和（b）中的官能团与组分（c）中的官能团相比更具反应性，使得在固化后，组分（c）上至少一部分官能团保持未反应。 由涂布到基材上的组合物形成的涂层具有表面区域和体积区域，并且在一个或多个表面区域的组分（c）的浓度大于组分（c）在本体区域中的浓度 涂层。 该组合物可用于含有两层或多层涂层的多层复合材料。

公开(公告)号：US06916860B2

公开(公告)日：2005-07-12

申请号：US10375005

申请日：2003-02-28

Applicant: Masaaki Oya ,  Naoya Nakamura ,  Makoto Tsuboi

Inventor： Masaaki Oya ,  Naoya Nakamura ,  Makoto Tsuboi

IPC: B63B59/04 ,  C08K5/09 ,  C09D5/16 ,  C09D143/00 ,  C09D143/04

CPC classification number: C09D5/1656 ,  C08K5/09 ,  C09D5/1668 ,  C09D143/00

Abstract: An antifouling coating composition comprising (A) a silyl ester copolymer containing constituent units derived from a polymerizable unsaturated carboxylic acid silyl ester; (B) a carboxylic acid; (C) a bivalent or trivalent metal compound; and (D) a dehydrating agent. It is preferred that the component (C) be contained in an amount of 1.2 equivalents or more, in terms of the number of equivalents of metal as a constituent of the component (C), per equivalent of carboxyl group of the carboxylic acid (B); that the component (C) be a bivalent metal compound; and that the component (C) be a compound of at least one metal selected from the group consisting of zinc, copper, magnesium, calcium and barium. From the antifouling coating composition, there can be obtained an antifouling coating film which exhibits less cracking tendency, excellent adherence so as to ensure less peeling tendency and desirably controlled hydrolysis rate so as to be excellent in antifouling performance, in particular, antifouling properties in highly fouling environment and long-term antifouling properties. With respect to the provided antifouling coating composition, its storage stability is high, its concentration can be increased, the amount of solvent used therefor can be reduced, and its applicability is high.

Abstract translation: 一种防污涂料组合物，其包含（A）含有衍生自可聚不饱和羧酸甲硅烷基酯的构成单元的甲硅烷基酯共聚物; （B）羧酸; （C）二价或三价金属化合物; 和（D）脱水剂。 相对于作为（C）成分的成分的金属的当量数，羧酸（B）的羧基的当量，优选为1.2当量以上 ）; 组分（C）是二价金属化合物; 并且组分（C）是选自锌，铜，镁，钙和钡中的至少一种金属的化合物。 从防污涂料组合物可以获得防污涂层，其具有较小的开裂倾向，优异的粘附性，以确保较低的剥离倾向和所需的控制水解速率，从而具有优异的防污性能，特别是高防污性 污染环境和长期防污性能。 对于所提供的防污涂料组合物，其保存稳定性高，其浓度可以提高，因此可以降低其用量，适用性高。

公开(公告)号：US20040069634A1

公开(公告)日：2004-04-15

申请号：US10269535

申请日：2002-10-11

Inventor： David K. Hanzel

IPC: G01N027/26 ,  G01N027/447

CPC classification number: B05D1/60 ,  B01J2219/005 ,  B01J2219/00527 ,  B01J2219/00605 ,  B01J2219/0061 ,  B01J2219/00626 ,  B01J2219/00637 ,  C09D143/00 ,  G01N27/44704 ,  G01N27/44752

Abstract: A method for coating a substrate with silane that comprises contacting in an inert environment a substrate with a vapor containing a bifunctional silane, preferably a bifunctional silane containing an acrylic functionality. The method may further comprise the step of attaching a coating of polyacrylamide to the acrylic functionality by in-situ polymerization or the step of immobilizing acrylic-modified molecules by copolymerization with the acrylic functionality of the bifunctional silane. The substrate may be a capillary, a microchip, a bead, or a slide, preferably of glass. A substrate coated using the instant method, as well as a method for reducing EOF in capillaries used for electrophoresis are also disclosed.

Abstract translation: 一种用硅烷涂覆基材的方法，该方法包括在惰性环境中使底物与含有双官能硅烷的蒸气接触，优选含有丙烯酸官能度的双官能硅烷。 该方法可以进一步包括通过原位聚合将聚丙烯酰胺涂层附着到丙烯酸官能团上的步骤或通过与双官能硅烷的丙烯酸官能团共聚来固定丙烯酸改性分子的步骤。 基底可以是毛细管，微芯片，珠或玻片，优选玻璃。 还公开了使用本方法包被的底物，以及用于降低用于电泳的毛细血管中的EOF的方法。