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公开(公告)号：CH534005A
公开(公告)日：1973-02-28
申请号：CH1922768
申请日：1968-12-23
Applicant: BAYER AG
Inventor： KROENIG WALTER , SCHARFE GERHARD
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公开(公告)号：DE2135155A1
公开(公告)日：1973-02-22
申请号：DE2135155
申请日：1971-07-14
Applicant: BAYER AG
Inventor： THELEN HERMANN DR , SCHWERDTEL WULF DR , HALCOUR KURT DR , SWODENK WOLFGANG DR
Abstract: A Pd catalyst for the redn. of nitro cpds. has an Al spinel support. The support pref. has a specific surface of 20-120 m2/g. and an av. pore dia. of 200-800 angstroms. the spinel-forming metal is pref. Co, Mg, Li, Ni, or Zn. The catalyst pref. contains 0.1-10, esp. 0.5-5wt.% Pd. It can be used (a) for the redn. of nitro cpds. in the presence of a liquid diluent, pref. recycled amine prodt., by trickling the reaction mixt. over the fixed catalyst at 50-240 degrees C under H2 pressure in a tube reactor, the heat of reation being removed by coolant surrounding the tube; (b) for the gas-phase redn. of mononitro cpds.; or (c) for the reductive alkylation of nitro cpds., by adding an aldehyde or ketone, pref. acetone, during hydrogenation. The catalyst is highly active and allows low reaction temps. to be used. the prodts. can be used, e.g., for the prodn. of isocyanates and plant-protection agents.
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公开(公告)号：AU3179071A
公开(公告)日：1973-02-01
申请号：AU3179071
申请日：1971-07-29
Applicant: SOLVAY
Inventor： DEGUELDRE LOUIS , GOBILLON YVES , CLERBOIS LUCIEN , BOURGEOIS LOUIS
Abstract: 1358926 Electrocatalysts; coated electrodes SOLVAY ET CIE 29 July 1971 [29 July 1970] 35747/71 Headings B1E and B2E [Also in Divisions C7 and H1] Electrodes comprise a coating of catalytic material on a support made at least superficially of titanium or a titanium alloy, the catalytic material comprising one or more elements of the platinum group in the metallic and/or oxidised state and tellurium in the oxidised state. The tellurium may be partially replaced by molybdenum or tungsten and the catalytic material may also comprise chromium lead, bismuth, antimony, tin, cadmium, titanium, tantalum and/or niobium in the oxidised state. In the examples the compounds of the catalytic elements are applied in solution in an organic solvent to form a coating and the coated structure is heat-treated. The electrodes are tested in the electrolysis of brine with a flowing mercury cathode to produce chlorine. They can also be used in cathodic protection, water purification, other electrolytic processes and as fuel cell electrodes.
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公开(公告)号：FI46327B
公开(公告)日：1972-11-30
申请号：FI307766
申请日：1966-11-22
Applicant: LAPORTE CHEMICAL
IPC: B01J31/08 , C01B15/023 , B01J11/08 , C01B15/02
Abstract: 1,146,437. Hydrogen peroxide. LAPORTE CHEMICALS Ltd: 14 Nov., 1966 [25 Nov., 1965], No. 50184/65. Heading C1A. [Also in Division B1] H 2 O 2 is made in a cyclic process including alternate hydrogenation and' oxidation of anthraquinone derivatives in the presence of a catalyst comprising a macroreticular ion exchange resin, having a surface area of at least 5 m 2 /gm. carrying a deposit of one or more of Ru, Rh, Pd, Os, Ir and Pt.
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Patent Agency Ranking
公开(公告)号：NL7018435A
公开(公告)日：1971-06-24
申请号：NL7018435
申请日：1970-12-17
IPC: B01J23/52 , C07C69/155 , C07C67/04 , B01J11/08
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公开(公告)号：DE2042815A1
公开(公告)日：1971-03-11
申请号：DE2042815
申请日：1970-08-28
IPC: B01J23/648 , C07C45/34 , C07C45/35 , B01J11/08
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公开(公告)号：DE1938079A1
公开(公告)日：1970-03-19
申请号：DE1938079
申请日：1969-07-26
Applicant: CATALYSTS & CHEM INC
IPC: B01J23/70 , B01J23/755 , B01J35/08 , B01J37/00 , C01B3/58 , C07B61/00 , C07C1/00 , C07C1/02 , C07C9/04 , C07C67/00 , B01J11/08
Abstract: 1278424 Methanation catalysts CATALYSTS & CHEMICALS Inc 22 July 1969 [26 July 1968] 36673/69 Heading B1E [Also in Division C5] A catalyst precursor in the form of porous spheres which on calcination and reduction promotes reactions between carbon oxides and hydrogen to form methane comprises 5-40% NiO, 15-75% of a binder which is either an activated transition alumina, e.g. rho or eta alumina, or a calcium silicater or aluminate cement or mixture of these cements and 0-75% alumina other than the transition alumina. The ingredients are tumbled and sprayed with water to form spheres and parameters such as bulk densities, specific gravity, ratios of pore volumes to sphere volume, &c, are fixed within specified ranges by adjusting the proportion of water to obtain a loss of 20-40% when the spheres are ignited to be rendered porous.
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公开(公告)号：CH462118A
公开(公告)日：1968-09-15
申请号：CH728964
申请日：1964-06-04
Applicant: HOFFMANN LA ROCHE
Inventor： CHARLES WILLIAM DEN HOLLANDER
IPC: B01J23/40 , B01J32/00 , C07D213/50 , C07D261/20 , B01J11/08 , C07D31/24 , C07C97/10
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公开(公告)号：US4124538A
公开(公告)日：1978-11-07
申请号：US371879
申请日：1964-05-28
Applicant: Warren E. Armstrong , Lloyd B. Ryland , Hervey H. Voge
Inventor： Warren E. Armstrong , Lloyd B. Ryland , Hervey H. Voge
CPC classification number: C06D5/04 , B01J23/468
Abstract: 1. A catalyst for hydrazine decomposition consisting essentially of a carrier having a pore volume of at least 0.1 cubic centimeters per gram and a specific surface area, measured in square meters per gram, equal to 195 (C.sub.p + 0.013 + 0.736 V.sub.p) where C.sub.p is the specific heat capacity of the carrier at about 25.degree. C in calories per gram per degree and V.sub.p is the pore volume of the carrier in cubic centimeters per gram and metal of the group consisting of iridium, and mixtures consisting of iridium and ruthenium deposited on said carrier in an amount between 20% and about 40% by weight of the catalyst and distributed through the pores thereof in discrete particles sufficiently separated from each other so that they do not sinter or fuse together when the catalyst is at hydrazine decomposition temperature.
Abstract translation: 1.一种用于肼分解的催化剂，其基本上由具有至少0.1立方厘米每克的孔体积和比表面积（以平方米/克计）等于195（Cp + 0.013 + 0.736Vp）的载体组成，其中Cp 是载体在约25℃下的比热容，每克/卡的热量，Vp是载体的孔体积，以立方厘米每克为单位，金属由铱组成，铱和钌组成的混合物沉积 在载体上的量为催化剂的20重量％至40重量％，并通过其分散的颗粒分散在彼此充分分离的颗粒中，使得当催化剂处于肼分解温度时，它们不会烧结或熔合在一起。
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