Abstract:
Lubricant compositions are provided which contain: oleaginous media, and an antiwear improving amount of a product formed by reacting (a) a compound having the formula: ##STR1## where R' is a substantially unbranched paraffinic alkyl group containing from about 10 to about 36 carbon atoms, and R is a hydrocarbyl group containing from 1 to about 4 carbon atoms with at least one hydrogen atom present on the carbon atom which is bonded to the oxygen; with (b) a substituted imidazoline of the formula: ##STR2## where one of the R.sup.2 and R.sup.3 substituents must be a substantially unbranched paraffinic or olefinic hydrocarbyl group containing from about 12 to about 35 carbon atoms; and the other R.sup.2 or R.sup.3 substituent is selected from the group consisting of: paraffinic alkyl containing from 1 to about 35 carbon atoms, alkenyl containing from 1 to about 35 carbon atoms, and hydroxy-, alkoxy-, alkoxymethoxy-, and oxo-substituted alkyl and alkenyl containing from 1 to about 20 carbon atoms; at proportions which are most preferably stoichiometric and at temperatures greater than 150.degree. C. Particularly contemplated are compositions in the form of lubricating oils and greases.
Abstract:
Lubricant compositions are provided, comprising oils of lubricating viscosity, and greases prepared therefrom, containing a minor antiwear improving amount of an alkyl beta-thiopropionic acid ester.
Abstract:
Organic lubricant compositions are provided containing a lubricating improving amount of a salt of (a) an alkyl, long chain alkyl acid phosphonate having the formula: ##STR1## where R' is a substantially unbranched paraffinic alkyl group containing from about 10 to about 36 carbon atoms, and R is a hydrocarbyl group containing from 1 to about 4 carbon atoms with at least one hydrogen atom present on the carbon atom which is bonded to oxygen and (b) a substituted imidazoline of the formula: ##STR2## where one of the R.sup.2 and R.sup.3 substituents must be a substantially unbranched paraffinic or olefinic hydrocarbyl group containing from about 12 to about 35 carbon atoms; and the other R.sup.2 or R.sup.3 substituent is selected from the group consisting of: paraffinic alkyl containing from 1 to about 35 carbon atoms, alkenyl containing from 1 to about 35 carbon atoms, and hydroxy, alkoxy, alkoxymethoxy, and oxo-substituted alkyl and alkenyl containing from 1 to about 20 carbon atoms. Particularly contemplated are lubricating oils and greases containing the aforementioned alkylamine salts as anti-wear agents and friction modifiers.
Abstract:
Known higher dialkyl dimethyl ammonium clays can be surprisingly used as thixotropic agents in reinforced thermoset resins containing a major proportion of an unsaturated polyester and a minor proportion of styrene type monomer by employing a novel pregel process. In this process, the quaternary ammonium clay is pregelled in the styrene and the resulting pregel is then mixed with the unsaturated polyester to produce the final gel which is usually combined with glass fiber as a reinforcing agent for the production of thermoplastics. The novel clay gel compositions of the present invention have surprisingly advantageous properties, compared to the presently used fumed silica gel compositions.
Abstract:
Organic compositions, which are normally susceptible of corroding copper, are provided, containing, in an amount sufficient to inhibit such corrosion, benzotriazole derivatives said derivatives having been prepared by reacting (A) benzotriazole and (B) a reactant selected from the group consisting of hydrocarbyl carboxylic acids having at least 18 carbon atoms, mono and di-substituted organic phosphates, and mono and di-substituted phosphonates wherein the organic substituent contains at least 15 carbon atoms and wherein said reaction is conducted at a temperature from about 100.degree.C to about 200.degree.C and in a mole ratio of (A) to (B) from about 1:1 to about 1:0.5.
Abstract:
1. A GREASE COMPOSITION HAVING SUPERIOR SHEAR STABILITY, WATER-RESISTANCE AND EXTREME PRESSURE PROPERTIES, COMPRISING FROM ABOUT 65 TO 90 WEIGHT PERCENT OF LUBRICATING MINERAL IOL FROM ABOUT 35 TO 10 WEIGHT PERCENT OF A THICKENING SYSTEM MADE UP OF 25 TO 9 WEIGHT PERCENT OF FIBROUS ASBESTOS AND ABOUT 10 TO 1 WEIGHT PERCENT OF POLYMERIC COATIG AGENT HAVING RECURRING UNITS INCLUDED WITHIN THE STRUCTURES:
(1,2,2,3,4-PENTA(R)-1,2-DIHYDRO-QUINOLINYL-R)N
WHEREIN THE AVERAGE DEGREE OF POLYMERIZATION RANGES FROM 2 TO ABOUT 10, AND R IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, ALKYL RADICALS AND HYDROXYLATD ALKYL RADICALS, SAID ALKYL RADICALS CONTAINING FROM 1 TO 6 CARBON ATOMS.
Abstract:
A highly corrosion resistant lubricating grease cmposition comprising a lubricating oil thickened with a gelling agent wherein the lubricating oil is prepared by intimately admixing a synthetic halogen containing polymeric lubricating oil and a fluorocarbon resin, freezing the mixture and thawing the frozen product.
Abstract:
GREASE THICKNESS WITH SYNERGISTIC PROPORTIONS OF BENTONITE CLAY HAVING 30-40 CARBON ATOMS AND POLYETHYLENE HAVING A MOLECULAR WEIGHT OF 10,000-30,000 AND CONTAINS SMALL AMOUNTS OF ALKALI METAL NITRITE AND AROMATIC AMINE SELECTED FROM DIPHENYLAMINE, N-OLEYTRIMETHYLENE DIAMINE, AND MIXTURES THEREOF.
Abstract:
SYNTHETIC HECTORITE-TYPE CLAY MATERIALS ARE PREPARED BY CALCINING A MIXTURE OF LI2CO3 AND TALC, MIXING WITH AN AQUEOUS SOLUTION OF A SODIUM SILICATE AND NA2CO3, AND HYDROTHERMALLY TREATING THE RESULTING MISTURE, SUBSEQUENT DRYING IS OPTIONALLY PROVIDED.
Abstract:
REACTION PRODUCT FORMED BY THE CONDENSATION OF A POLYAMINE CONTAINING AT LEAST TWO PRIMARY AND/OR SECONDARY NITROGENS, POLYHALOPOLYHYDROPOLYCYCLICDICARBOXYLIC ACID OR DERIVATIVE AND HALOGEN-FREE DICARBOXYLIC ACID OR DERIVATIVE. IN ONE EMBODIMENT THE REACTION PRODUCT IS USED AS AN ADDITIVE IN HYDROCARBON OILS AND LUBRICANTS. IN ANOTHER EMBODIMENT IT IS USED AS AN ADDITIVE IN PLASTICS.