公开(公告)号：US09217053B2

公开(公告)日：2015-12-22

申请号：US14386476

申请日：2013-03-19

Applicant: DIC Corporation

Inventor： Etsuko Suzuki ,  Kazuo Arita

IPC: B32B27/08 ,  H05K1/05 ,  C08L63/00 ,  C08G8/32 ,  C08J5/24 ,  H01L23/29 ,  H05K1/03 ,  C08G16/02 ,  C08L61/14 ,  H05K3/00 ,  C08G8/28 ,  C08G16/04

CPC classification number: C08G8/32 ,  C08G8/28 ,  C08G16/0243 ,  C08G16/04 ,  C08G2190/00 ,  C08J5/24 ,  C08L61/14 ,  C08L2201/02 ,  C08L2203/206 ,  H01L23/293 ,  H01L2924/0002 ,  H05K1/0353 ,  H05K1/056 ,  H05K3/0067 ,  H05K2201/012 ,  H05K2201/0145 ,  Y10T428/31529 ,  H01L2924/00

Abstract: A cured product exhibits good heat resistance and flame retardancy as well as low dielectric constant and low loss tangent. A phosphorus-containing compound (i) obtained by a reaction between an aromatic aldehyde (a1) having an alkoxy group as a substituent on a nucleus and an organic phosphorus compound (a2) having a P—H group or a P—OH group in a molecular structure is reacted with a phenolic substance (a3) to obtain a phosphorus-containing phenolic substance (A1). Then the phosphorus-containing phenolic substance (A1) is reacted with an aromatic dicarboxylic acid or an anhydride or dihalide of an aromatic dicarboxylic acid or a C2-6 saturated dicarboxylic acid or an anhydride or dihalide of a C2-6 saturated dicarboxylic acid (A2) so that all or some of hydroxyl groups of the phenolic substance (A1) form ester bonds.

Abstract translation: 固化产物具有良好的耐热性和阻燃性以及低介电常数和低损耗角正切。 通过在核上具有烷氧基作为取代基的芳香醛（a1）与具有P-H基或P-OH基的有机磷化合物（a2）之间的反应获得的含磷化合物（i） 使分子结构与酚类物质（a3）反应，得到含磷酚类物质（A1）。 然后将含磷酚类物质（A1）与芳族二羧酸或芳族二羧酸或C2-6饱和二羧酸的酸酐或二卤化物或C2-6饱和二羧酸的二卤化物（A2 ）使得酚类物质（A1）的全部或部分羟基形成酯键。

公开(公告)号：US20150361263A1

公开(公告)日：2015-12-17

申请号：US14234288

申请日：2012-07-24

Applicant: Frank Peter Theodorus J. Van Der Burgt

Inventor： Frank Peter Theodorus J. Van Der Burgt

IPC: C08L77/06 ,  B29C45/00 ,  C08J5/00

CPC classification number: C08L77/06 ,  B29C45/0001 ,  B29K2077/00 ,  B29L2031/36 ,  C08J5/00 ,  C08J2377/06 ,  C08J2477/06 ,  C08K5/5313 ,  C08K7/14 ,  C08L2201/02 ,  C08L2205/02 ,  C08L2205/025

Abstract: The present invention relates to a flame retardant polyamide composition comprising (A) a semi-crystalline semi-aromatic polyamide having a melting temperature (TmA) and having a number average molecular weight in the range between 7,500 and 30,000 g/mol; (B) a semi-crystalline aliphatic polyamide having a melting temperature (TmB); and having a number average molecular weight in the range between 7,500 and 50,000 g/mol; and (C) a halogen free flame retardant system comprising a metal salt of a phosphinic acid and/or a diphosphinic acid, wherein TmA is higher than TmB and weight ratio of (A):(B) is in the range between 0:50 and 75:25. The invention also relates to a process for moulding the flame retardant polyamide composition, and moulded parts made of the flame retardant polyamide composition.

Abstract translation: 本发明涉及一种阻燃性聚酰胺组合物，其包含（A）半结晶半芳族聚酰胺，其熔融温度（TmA）和数均分子量在7500和30,000g / mol之间; （B）具有熔融温度（TmB）的半结晶脂肪族聚酰胺; 并且其数均分子量在7,500和50,000g / mol之间的范围内; 和（C）无卤阻燃体系，其包含次膦酸和/或二次膦酸的金属盐，其中TmA高于TmB，（A）:( B）的重量比在0:50之间的范围内 和75:25。 本发明还涉及一种模塑阻燃聚酰胺组合物的方法和由阻燃聚酰胺组合物制成的模塑部件。

公开(公告)号：US20150353727A1

公开(公告)日：2015-12-10

申请号：US14655007

申请日：2014-12-04

Applicant: LG CHEM, LTD.

Inventor： Su Kyoung LEE ,  Min Ji KIM ,  Ryul LEE ,  Sung Ho LEE

IPC: C08L69/00 ,  C08J5/00

CPC classification number: C08L33/08 ,  C08J5/00 ,  C08J2369/00 ,  C08K3/22 ,  C08L23/00 ,  C08L33/04 ,  C08L51/06 ,  C08L69/00 ,  C08L83/04 ,  C08L91/06 ,  C08L2201/02 ,  C08L2201/10 ,  C08L2207/53

Abstract: The present invention relates to a polycarbonate resin composition including both of silicone oil and olefin-based wax at a proper ratio and thus having improved dispersibility of titanium dioxide in the composition as well as high impact strength and melt index (moldability), and also relates to a polycarbonate molded article made of the polycarbonate resin composition. The polycarbonate resin composition according to the present invention includes silicone oil and olefin-based wax at a proper ratio and thus improves dispersibility of titanium dioxide which is added to the composition to give whiteness, while preserving high impact strength and melt index (moldability), so that crawling which is generated on the surface of a final product of polycarbonate molded article is prevented and the appearance property of the molded article is improved. Therefore, the polycarbonate resin composition according to the present invention has characteristics of high whiteness as well as high impact strength and melt index (moldability), and thus is easily applicable to industries in need of the polycarbonate resin.

Abstract translation: 本发明涉及一种聚碳酸酯树脂组合物，其特征在于包括硅油和烯烃类蜡均以适当的比例，因此具有改善的二氧化钛在组合物中的分散性以及高的冲击强度和熔体指数（成型性），并且还涉及 涉及由聚碳酸酯树脂组合物制成的聚碳酸酯模制品。 本发明的聚碳酸酯树脂组合物以适当的比例含有硅油和烯烃类蜡，从而提高了添加到组合物中以提供白度的二氧化钛的分散性，同时保持了高冲击强度和熔体指数（成型性）， 从而防止在聚碳酸酯成型体的最终产品的表面产生的爬行，并且改善了模塑制品的外观性能。 因此，本发明的聚碳酸酯树脂组合物具有白度高，冲击强度高，熔体指数（成型性）高的特点，因此容易适用于需要聚碳酸酯树脂的工业。

公开(公告)号：US09200122B2

公开(公告)日：2015-12-01

申请号：US14305062

申请日：2014-06-16

Applicant: Trupti Dave ,  Wolfgang Wehner

Inventor： Trupti Dave ,  Wolfgang Wehner

IPC: C07D251/54 ,  C08G79/04 ,  C08L85/02 ,  C08L77/00 ,  C08L75/04 ,  C08L25/06 ,  C08L77/02 ,  C08L77/06 ,  C08K5/00 ,  C08K5/5353 ,  C08K5/5317 ,  C08G18/50 ,  C08K5/3492

CPC classification number: C08K5/5317 ,  A61K8/416 ,  B01J43/00 ,  C07D251/54 ,  C07F9/3873 ,  C08G18/509 ,  C08G79/04 ,  C08K5/0091 ,  C08K5/3492 ,  C08K5/34922 ,  C08K5/34924 ,  C08K5/34928 ,  C08K5/5353 ,  C08L25/06 ,  C08L75/04 ,  C08L77/00 ,  C08L77/02 ,  C08L77/06 ,  C08L85/02 ,  C08L2201/02 ,  C11D1/62

Abstract: The present invention relates to phosphorus-containing triazine compounds of the formula (I) and (III) and to the polymers obtainable from the water-eliminating polycondensation of a compound of the formula (II), and to the use thereof as flame retardants.

Abstract translation: 本发明涉及式（I）和（III）的含磷三嗪化合物和由式（II）化合物的除水缩聚得到的聚合物及其作为阻燃剂的用途。

公开(公告)号：US20150322252A1

公开(公告)日：2015-11-12

申请号：US14651236

申请日：2013-12-05

Applicant: Robert ARECHEDERRA ,  POLYAD SERVICES LLC

Inventor： Robert Arechederra

IPC: C08L23/12 ,  C08K13/02

CPC classification number: C08L23/12 ,  C08K3/01 ,  C08K3/20 ,  C08K5/0008 ,  C08K5/0066 ,  C08K5/02 ,  C08K5/3435 ,  C08K13/02 ,  C08L2201/02 ,  C08L2201/08 ,  C09K21/08

Abstract: The present disclosure is aimed at flame retardant thermoplastic polymer compositions. The flame retardant compositions are advantageously antimony free. The compositions contain an effective flame retarding amount of a combination of one or more bismuth compounds selected from the group consisting of bismuth oxychloride, bismuth oxyfluoride, bismuth oxybromide, bismuth oxyiodide and bismuth oxynitrate and one or more organobromine flame retardants, for instance decabromodiphenyl ether (decabromodiphenyl oxide) or tris[3-bromo-2,2-bis(bromomethyl)propyl]phosphate. The thermoplastic polymer is for instance polypropylene, polyethylene, polystyrene, polypropylene/polyethylene copolymer or thermoplastic olefin. The present formulations advantageously contain no antimony trioxide and achieve V0 according to the UL 94 flammability test.

Abstract translation: 本发明旨在阻燃热塑性聚合物组合物。 阻燃组合物有利地是无锑的。 所述组合物含有有效的阻燃量的一种或多种铋化合物的组合，所述铋化合物选自氯氧化铋，氟氧化铋，溴氧化铋，氧化铋和硝酸铋，以及一种或多种有机溴阻燃剂，例如十溴二苯醚（ 十溴二苯醚）或三[3-溴-2,2-双（溴甲基）丙基]磷酸酯。 热塑性聚合物例如是聚丙烯，聚乙烯，聚苯乙烯，聚丙烯/聚乙烯共聚物或热塑性烯烃。 本发明的配方有利地不含三氧化锑，并根据UL 94可燃性试验达到V0。

公开(公告)号：US09156978B1

公开(公告)日：2015-10-13

申请号：US14297900

申请日：2014-06-06

Applicant: TEKNOR APEX COMPANY

Inventor： Kevin Cai ,  Roland Ruprecht

IPC: C08K5/49 ,  C08K5/53 ,  C08L53/00 ,  C08L23/16 ,  H01B3/44

CPC classification number: H01B3/442 ,  C08K5/49 ,  C08K5/523 ,  C08K2201/014 ,  C08L23/10 ,  C08L31/04 ,  C08L53/025 ,  C08L2201/02 ,  C08L2205/03

Abstract: Halogen free flame retardant thermoplastic elastomer compositions including a hydrogenated styrenic block copolymer having relatively high styrene or mono alkenyl arene content and styrene or mono alkenyl arene in each block. Surprisingly, the compositions contain low amounts or are free of plasticizing softeners. The compositions include a blend of non-halogen flame retardants including a liquid phosphorous-containing component and a solid secondary component. The compositions are suitable for extrusion or molding and are useful for films or wire and cable applications.

Abstract translation: 无卤阻燃热塑性弹性体组合物，其包括在每个嵌段中具有相对高的苯乙烯或单烯基芳烃含量的苯乙烯或单烯基芳烃的氢化苯乙烯嵌段共聚物。 令人惊奇的是，组合物含有少量或不含增塑软化剂。 组合物包括包含含有液态磷的组分和固体二级组分的非卤素阻燃剂的混合物。 组合物适用于挤出或模塑，并且可用于膜或电线和电缆应用。

公开(公告)号：US20150284546A1

公开(公告)日：2015-10-08

申请号：US14439107

申请日：2013-10-29

Applicant: RHODIA OPERATIONS

Inventor： Laurent Guy ,  Dominique Dupuis ,  Emmanuelle Allain

IPC: C08L7/00

CPC classification number: C08L7/00 ,  C08K5/53 ,  C08K13/02 ,  C08L9/00 ,  C08L2201/02 ,  C08L19/006

Abstract: The invention concerns the combined use, in an elastomer composition preferably comprising an isoprene elastomer, a precipitated silica containing titanium and a specific conjugated diene compound, such as a conjugated diene phosphonate or phosphinate compound. It also concerns the elastomer compositions obtained and the items produced from said compositions.

Abstract translation: 本发明涉及组合使用的弹性体组合物，优选包括异戊二烯弹性体，含钛的沉淀二氧化硅和特定共轭二烯化合物如共轭二烯膦酸盐或次膦酸盐化合物。 它还涉及获得的弹性体组合物和由所述组合物产生的物品。

公开(公告)号：US09145498B2

公开(公告)日：2015-09-29

申请号：US14379373

申请日：2013-03-04

Applicant: Stefan Ultsch

Inventor： Stefan Ultsch

IPC: C08L23/14 ,  C08K3/20 ,  C08L53/00 ,  B32B27/32 ,  D06M15/227 ,  D06N3/00 ,  D06N3/04 ,  E04D5/10 ,  B32B5/02 ,  B32B7/12 ,  B32B27/12

CPC classification number: C08L53/00 ,  B32B5/02 ,  B32B7/12 ,  B32B27/12 ,  B32B27/32 ,  B32B2255/02 ,  B32B2255/26 ,  B32B2262/0253 ,  B32B2262/101 ,  B32B2262/106 ,  B32B2307/3065 ,  B32B2307/54 ,  B32B2307/704 ,  B32B2307/7265 ,  B32B2419/06 ,  C08K3/016 ,  C08K5/005 ,  C08K5/0066 ,  C08K2003/2224 ,  C08K2003/2241 ,  C08L23/14 ,  C08L2201/02 ,  D06M15/227 ,  D06M2200/30 ,  D06N3/0063 ,  D06N3/045 ,  E04D5/10 ,  C08K3/0058

Abstract: The invention provides halogen-free, flame-retardant flexible polyolefin-based formulations.

Abstract translation: 本发明提供无卤阻燃的基于柔性聚烯烃的制剂。

公开(公告)号：US20150259521A1

公开(公告)日：2015-09-17

申请号：US14432907

申请日：2013-10-17

Applicant: VERSALIS S.P.A

Inventor： Antonio Ponticiello ,  Attilio Arienti ,  Francesco Pasquali

IPC: C08L25/08 ,  C08J9/20

CPC classification number: C08L25/08 ,  C08J9/0019 ,  C08J9/0061 ,  C08J9/0066 ,  C08J9/0095 ,  C08J9/141 ,  C08J9/16 ,  C08J9/20 ,  C08J9/224 ,  C08J9/232 ,  C08J2201/022 ,  C08J2201/03 ,  C08J2201/036 ,  C08J2203/14 ,  C08J2203/182 ,  C08J2325/04 ,  C08J2325/08 ,  C08J2425/04 ,  C08J2425/14 ,  C08J2433/14 ,  C08J2463/04 ,  C08K3/04 ,  C08K5/0066 ,  C08L25/06 ,  C08L25/14 ,  C08L2201/02

Abstract: The present invention relates to a concentrated polymeric composition which comprises: a) vinyl aromatic polymers and/or copolymers in an amount ranging from 10% to 90% by weight, calculated with respect to the overall composition, with respect to the overall composition, b) at least one compound containing epoxy functional groups in an amount ranging from 0.01% to 5% by weight, calculated with respect to the overall composition, with respect to the overall composition, c) at least one infrared absorbing agent, in an amount ranging from 10% to 90% by weight, calculated with respect to the overall composition, with respect to the overall composition.

Abstract translation: 本发明涉及一种浓缩聚合物组合物，其包含：a）相对于总体组合物，相对于总组合物计算的量为10重量％至90重量％的乙烯基芳族聚合物和/或共聚物，b ）至少一种含有环氧官能团的化合物，所述化合物的含量相对于整个组合物为0.01-5重量％，相对于整个组合物计算，c）至少一种红外吸收剂，其量为 相对于整体组合物计算，相对于总体组成计算为10重量％至90重量％。

公开(公告)号：US20150259440A1

公开(公告)日：2015-09-17

申请号：US14435312

申请日：2013-10-17

Applicant: BROMINE COMPOUNDS LTD.

Inventor： Bertha Croitoru ,  Dov Beruben ,  Michael Peled ,  Yaakov Rachmilevitch ,  Yaniv Hirschsohn ,  Yelena Epshtein Assor ,  Ella Rapaport ,  Dan Kopel

IPC: C08F2/10 ,  D06M15/263 ,  C08L33/16 ,  C08L23/14 ,  C08L25/06

CPC classification number: C08F2/10 ,  C08F212/08 ,  C08F220/24 ,  C08L23/14 ,  C08L25/06 ,  C08L33/14 ,  C08L33/16 ,  C08L2201/02 ,  C08L2203/12 ,  D06M15/263 ,  D06M2101/06 ,  D06M2101/32 ,  D06M2200/30

Abstract: The invention provides a solution polymerization process, comprising polymerizing pentabromobenzyl acrylate or pentabromobenzyl methacrylate in a mixture of water-miscible aprotic solvent and water, in the presence of a water-soluble free radical initiator and preferably also chain length regulator. The polymers obtained and their uses as flame retardants in polypropylene, HIPS, ABS and textile products are also disclosed.

Abstract translation: 本发明提供一种溶液聚合方法，其包括在水溶性自由基引发剂和优选链长度调节剂的存在下，在水混溶性非质子传递溶剂和水的混合物中聚合丙烯酸五溴苄酯或甲基丙烯酸五溴苄酯。 获得的聚合物及其在聚丙烯，HIPS，ABS和纺织品中的阻燃剂的用途也被公开。