METAL COMPLEX COMPRISING AMIDINE AND THIOPHENE FUSED CYCLOPENTADIENYL LIGANDS

    公开(公告)号:WO2019132687A1

    公开(公告)日:2019-07-04

    申请号:PCT/RU2017/000969

    申请日:2017-12-25

    Abstract: A metal complex of the formula (1) TCyLMX p (1), wherein M is a group 4 metal Z is an anionic ligand, p is number of 1 to 2, preferably 2, TCy is a thiophene fused cyclopentadienyl-type ligand of the formula (2) wherein R 1 and R 2 being individually selected from the group of hydrogen, halogen, C 1 -C 10 alkyl, C 5 -C 10 cycloalkyl, and an unsubstituted or C 1 -C 10 -alkyl or C 1 -C 4 -dialkyl amino substituted С 6 -С 10 aryl, in particular C 1 -C 4 -alkyl substituted phenyl and SiR 3 , OR, NR 2 , SR, PR 2 , wherein R means individually C 1 -C 10 -alkyl, C 5 -С 10 -cycloalkyl, and an unsubstituted or C 1 -C 10 -alkyl or C 1 -C 4 -dialkyl amino substituted C 6 -C 10 -aryl, in particular C 1 -C 4 -alkyl substituted phenyl or R 1 and R 2 together with the 2 double bond carbon atoms of the thiophene ring they are connected to form an unsubstituted or C 1 -C 4 -alkyl substituted aliphatic C 5 -C 6 -cycloalkene ring, R 3 , R 4 and R 5 being individually selected from the group of hydrogen, C 1 -C 4 alkyl, unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10- aryl, in particular C 1 -C 4 -alkyl substituted phenyl, and SiR 3 , OR, NR 2 , SR, PR 2 , wherein R means individually C 1 -C 10 -alkyl, C 5 -C 10 -cycloalkyl, and an unsubstituted or C 1 -C 10 -alkyl or C 1 -C 4 -dialkyl amino substituted C 6 -C 10 -aryl, in particular C 1 -C 4 -alkyl substituted phenyl and, L is an amidinate ligand of the formula (3) wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub 1 is an unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10 -aromatic substituent, in particular phenyl and Sub 2 is a substituent comprising a heteroatom of group 15, through which Sub 2 is bonded to the imine carbon atom or Sub 1 and Sub 2 together with the imino group they are connected to form a ligand of formula (3a) wherein the amidine-containing ligand (3a) is covalently bonded to the metal M via the imine nitrogen atom N 2 , wherein the benzo ring fused to the amidine ring may be unsubstituted or contain further substituents R 7 , which are individually of the index "q" selected from the group of hydrogen, C 1 -C 4 -alkyl and halogen and whereby q is a number of 0 to 4, preferably 0 to 2, most preferably 0, Sub 4 is an aliphatic or aromatic cyclic or linear substituent comprising a group 14 atom through which Sub 4 is bonded to the amino nitrogen atom N 1 , preferably Sub 4 is a C 6 -C 10 aromatic ring, preferably phenyl which is unsubstituted or substituted by one or more substituents from the group selected from halogen, in particular Cl or F and C 1 -C 4 -alkyl.

    CURABLE RUBBER COMPOSITION
    43.
    发明申请
    CURABLE RUBBER COMPOSITION 审中-公开
    可固化橡胶组合物

    公开(公告)号:WO2016156139A1

    公开(公告)日:2016-10-06

    申请号:PCT/EP2016/056339

    申请日:2016-03-23

    Inventor: HOUGH, Philip

    Abstract: A rubber composition containing based upon parts by weight per 100 parts by weight rubber (phr): (A) 20 - 50 phr of a copolymer of ethylene, at least one C3 to C23 α-olefin and a least one polyene monomer, whereby the copolymer unit derived from the polyene is 1 to 5 wt.%, by weight of the copolymer (A) and has a Mooney viscosity ML (1+4) at 100 °C from 51 or greater, in particular from 55 to 90 at 100 °C, (B) 50 - 80 phr of butyl-type rubber and (C) a resin-based curative, containing a phenol formaldehyde resin cross-linker as only curing agent and an activator package comprising of metal oxide and a halogen donor where a halogenated component (B) or halogenated cross-linker as part of component (C) not already present.

    Abstract translation: 含有每100份(重量)橡胶(phr)重量份的橡胶组合物:(A)20-50phr乙烯,至少一种C 3至C 23α-烯烃和至少一种多烯单体的共聚物,其中 衍生自多烯的共聚单元为共聚物(A)的重量比为1〜5重量%,100℃时门尼粘度ML(1 + 4)为51以上,特别优选为55〜90 ℃,(B)50-80phr丁基橡胶和(C)树脂基固化剂,其含有作为固化剂的酚醛树脂交联剂和包含金属氧化物和卤素供体的活化剂包 作为组分(C)的一部分的卤代组分(B)或卤代交联剂不存在。

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