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    METAL COMPLEX COMPRISING AMIDINE AND INDOLE FUSED CYCLOPENTADIENYL LIGANDS
    1.
    发明申请
    METAL COMPLEX COMPRISING AMIDINE AND INDOLE FUSED CYCLOPENTADIENYL LIGANDS 审中-公开

    公开(公告)号：WO2019203676A1

    公开(公告)日：2019-10-24

    申请号：PCT/RU2018/000237

    申请日：2018-04-16

    Applicant: ARLANXEO NETHERLANDS B.V. ,  LOMONOSOV MOSCOW STATE UNIVERSITY

    Inventor： GORYUNOV, Georgy Pavlovich ,  SAMSONOV, Oleg Vladimirovich ,  UBORSKY, Dmitry Vadimovich ,  VOSKOBOYNIKOV, Alexander Zel'manovich ,  BERTHOUD, Alexandra ,  VALLA, Maxence

    IPC: C07F17/00 ,  C07F7/00 ,  C07F7/28 ,  C08F210/16 ,  C08F4/6592

    Abstract: A metal complex of the formula (1) InCyLMZ p (1), wherein M is a group 4 metal Z is an anionic ligand, p is number of 1 to 2, preferably 2, InCy is an indole fused cyclopentadienyl-type ligand of the formula (2) wherein R 1 means for each index m individually a C 1 -C 4 -alkyl that substitutes a hydrogen atom of the benzene ring, m is a number of 0 to 4, preferably 0 to 2, in particular 0, R 2 means C 1 -C 10 -alkyl, C 5 -C 10 -cycloalkyl, and an unsubstituted or C 1 -C 10 -alkyl or C 1 -C 4 -dialkyl amino substituted C 6 -C 10 -aryl, in particular С 1 -С 4 -alkyl substituted phenyl, more preferably methyl, phenyl or di-C 1 -C 4 -alkyl substituted phenyl, in particular di-tert.-butyl-phenyl, R 3 , R 4 and R 5 being individually selected from the group of hydrogen, С 1 -С 4 -alkyl, unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10 -aryl, in particular unsubstituted or C 1 -C 4 -alkyl substituted phenyl whereby preferably R 3 , R 4 and R 5 being individually selected from the group of hydrogen, C 1 -C 4 -alkyl, unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10 -aryl, in particular C 1 -C 4 -alkyl substituted phenyl, more preferably at least one of the radicals R 3 to R 5 shall mean C 1 -C 4 -alkyl, in particular methyl, i-propyl and phenyl and, L is an amidinate ligand of the formula (3) wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub 1 is an unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10 -aromatic substituent, in particular phenyl and Sub 2 is a substituent comprising a heteroatom of group 15, through which Sub 2 is bonded to the imine carbon atom or Sub 1 and Sub 2 together with the imino group they are connected to form a ligand of formula (3a) wherein the amidine-containing ligand (3a) is covalently bonded to the metal M via the imine nitrogen atom N 2 , wherein the benzo ring fused to the amidine ring may be unsubstituted or contain further substituents R 7 , which are individually of the index "q" selected from the group of hydrogen, C 1 -C 4 -alkyl and halogen and whereby q is a number of 0 to 4, preferably 0 to 2, most preferably 0, Sub 4 is an aliphatic or aromatic cyclic or linear substituent comprising a group 14 atom through which Sub 4 is bonded to the amino nitrogen atom N 1 , preferably Sub 4 is a C 6 -C 10 -aromatic ring, preferably phenyl which is unsubstituted or substituted by one or more substituents from the group selected from halogen, in particular Cl or F and C 1 -C 4 -alkyl, preferably Sub4 is a 2,6-di-fluorophenyl.

    METAL COMPLEX COMPRISING AMIDINE AND INDOLE FUSED CYCLOPENTADIENYL LIGANDS
    2.
    发明申请
    METAL COMPLEX COMPRISING AMIDINE AND INDOLE FUSED CYCLOPENTADIENYL LIGANDS 审中-公开

    公开(公告)号：WO2019201838A1

    公开(公告)日：2019-10-24

    申请号：PCT/EP2019/059634

    申请日：2019-04-15

    Applicant: ARLANXEO NETHERLANDS B.V.

    Inventor： GORYUNOV, Georgy, Pavlovich ,  SAMSONOV, Oleg, Vladimirovich ,  UBORSKY, Dmitry, Vadimovich ,  VOSKOBOYNIKOV, Alexander, Zel´Manovich ,  BERTHOUD, Alexandra ,  VALLA, Maxence

    IPC: C07F17/00 ,  C07F7/00 ,  C07F7/28 ,  C08F210/16 ,  C08F4/6592

    Abstract: A metal complex of the formula (1) InCyLMZ p (1), wherein M is a group 4 metal Z is an anionic ligand, p is number of 1 to 2, preferably 2, InCy is an indole fused cyclopentadienyl-type ligand of the formula (2) wherein R 1 means for each index m individually a C 1 -C 4 -alkyl that substitutes a hydrogen atom of the benzene ring, m is a number of 0 to 4, preferably 0 to 2, in particular 0, R 2 means C 1 -C 10 -alkyl, C 5 - C 10 -cycloalkyl, and an unsubstituted or C 1 -C 10 -alkyl or C 1 -C 4 -dialkyl amino substituted C 6 -C 10 -aryl, in particular C 1 -C 4 -20 alkyl substituted phenyl, more preferably methyl, phenyl or di-C 1 -C 4 -alkyl substituted phenyl, in particular di-tert.-butyl-phenyl, R 3 , R 4 and R 5 being individually selected from the group of hydrogen, C 1 -C 4 -alkyl, unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10 -aryl, in particular unsubstituted or C 1 -C 4 -alkyl substituted phenyl whereby preferably R 3 , R 4 and R 5 being individually selected from the group of hydrogen, C 1 -C 4 -alkyl, unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10 -aryl, in particular C 1 -C 4 -alkyl substituted phenyl, more preferably at least one of the radicals R 3 to R 5 shall mean C 1 -C 4 -alkyl, in particular methyl, i-propyl and phenyl and, L is an amidinate ligand of the formula (3) (3) wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub 1 is an unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10 -aromatic substituent, in particular phenyl and Sub 2 is a substituent comprising a heteroatom of group 15, through which Sub 2 is bonded to the imine carbon atom or Sub 1 and Sub 2 together with the imino group they are connected to form a ligand of formula (3a) wherein the amidine-containing ligand (3a) is covalently bonded to the metal M via the imine nitrogen atom N 2 , wherein the benzo ring fused to the amidine ring may be unsubstituted or contain further substituents R 7 , which are individually of the index "q" selected from the group of hydrogen, C 1 -C 4 -alkyl and halogen and whereby q is a number of 0 to 4, preferably 0 to 2, most preferably 0, Sub 4 is an aliphatic or aromatic cyclic or linear substituent comprising a group 14 atom through which Sub4 is bonded to the amino nitrogen atom N 1, preferably Sub4 is a C 6 -C 10 -aromatic ring, preferably phenyl which is unsubstituted or substituted by one or more substituents from the group selected from halogen, in particular Cl or F and C 1 -C 4 -alkyl, preferably Sub4 is a 2,6-di-fluorophenyl.

    METAL COMPLEX COMPRISING AMIDINE AND THIOPHENE FUSED CYCLOPENTADIENYL LIGANDS
    3.
    发明申请
    METAL COMPLEX COMPRISING AMIDINE AND THIOPHENE FUSED CYCLOPENTADIENYL LIGANDS 审中-公开

    公开(公告)号：WO2019132687A1

    公开(公告)日：2019-07-04

    申请号：PCT/RU2017/000969

    申请日：2017-12-25

    Applicant: ARLANXEO NETHERLANDS B.V. ,  LOMONOSOV MOSCOW STATE UNIVERSITY

    Inventor： GORYUNOV, Georgy Pavlovich ,  MLADENTSEV, Dmitry Yur'evich ,  SAMSONOV, Oleg Vladimirovich ,  UBORSKY, Dmitry Vadimovich ,  VOSKOBOYNIKOV, Alexander Zel'manovich ,  BERTHOUD, Alexandra ,  VALLA, Maxence

    IPC: C07F7/28 ,  C08F4/659 ,  C08F10/02 ,  C08F10/06

    CPC classification number: C07F7/28 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/00 ,  C08F2410/01 ,  C08F2420/04 ,  C08F2420/06 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/03 ,  C08F2500/01 ,  C08F210/18 ,  C08F236/20 ,  C08F4/6592

    Abstract: A metal complex of the formula (1) TCyLMX p (1), wherein M is a group 4 metal Z is an anionic ligand, p is number of 1 to 2, preferably 2, TCy is a thiophene fused cyclopentadienyl-type ligand of the formula (2) wherein R 1 and R 2 being individually selected from the group of hydrogen, halogen, C 1 -C 10 alkyl, C 5 -C 10 cycloalkyl, and an unsubstituted or C 1 -C 10 -alkyl or C 1 -C 4 -dialkyl amino substituted С 6 -С 10 aryl, in particular C 1 -C 4 -alkyl substituted phenyl and SiR 3 , OR, NR 2 , SR, PR 2 , wherein R means individually C 1 -C 10 -alkyl, C 5 -С 10 -cycloalkyl, and an unsubstituted or C 1 -C 10 -alkyl or C 1 -C 4 -dialkyl amino substituted C 6 -C 10 -aryl, in particular C 1 -C 4 -alkyl substituted phenyl or R 1 and R 2 together with the 2 double bond carbon atoms of the thiophene ring they are connected to form an unsubstituted or C 1 -C 4 -alkyl substituted aliphatic C 5 -C 6 -cycloalkene ring, R 3 , R 4 and R 5 being individually selected from the group of hydrogen, C 1 -C 4 alkyl, unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10- aryl, in particular C 1 -C 4 -alkyl substituted phenyl, and SiR 3 , OR, NR 2 , SR, PR 2 , wherein R means individually C 1 -C 10 -alkyl, C 5 -C 10 -cycloalkyl, and an unsubstituted or C 1 -C 10 -alkyl or C 1 -C 4 -dialkyl amino substituted C 6 -C 10 -aryl, in particular C 1 -C 4 -alkyl substituted phenyl and, L is an amidinate ligand of the formula (3) wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub 1 is an unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10 -aromatic substituent, in particular phenyl and Sub 2 is a substituent comprising a heteroatom of group 15, through which Sub 2 is bonded to the imine carbon atom or Sub 1 and Sub 2 together with the imino group they are connected to form a ligand of formula (3a) wherein the amidine-containing ligand (3a) is covalently bonded to the metal M via the imine nitrogen atom N 2 , wherein the benzo ring fused to the amidine ring may be unsubstituted or contain further substituents R 7 , which are individually of the index "q" selected from the group of hydrogen, C 1 -C 4 -alkyl and halogen and whereby q is a number of 0 to 4, preferably 0 to 2, most preferably 0, Sub 4 is an aliphatic or aromatic cyclic or linear substituent comprising a group 14 atom through which Sub 4 is bonded to the amino nitrogen atom N 1 , preferably Sub 4 is a C 6 -C 10 aromatic ring, preferably phenyl which is unsubstituted or substituted by one or more substituents from the group selected from halogen, in particular Cl or F and C 1 -C 4 -alkyl.

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