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    CATALYTIC REACTOR
    41.
    发明申请
    CATALYTIC REACTOR 审中-公开
    催化反应器

    公开(公告)号：WO2017009050A1

    公开(公告)日：2017-01-19

    申请号：PCT/EP2016/065239

    申请日：2016-06-30

    Applicant: HALDOR TOPSOE A/S

    Inventor： CHRISTENSEN, Anders Lindhard ,  TJÄRNEHOV, Emil Andreas

    IPC: B01J8/02

    CPC classification number: B01J8/0257 ,  B01J8/003 ,  B01J8/0214 ,  B01J8/0278 ,  B01J8/0292 ,  B01J2208/00132 ,  B01J2208/0084

    Abstract: The invention relates to a catalytic reactor suited for exothermal reactions with a radial process fluid flow and process fluid flow guides which ensures an extended fluid flow path and higher flow velocity and thereby enhanced cooling of the catalyst bed in the reactor.

    Abstract translation: 本发明涉及一种适合于径向过程流体流动的放热反应的催化反应器和工艺流体流动引导件，其确保了延长的流体流动路径和较高的流速，从而增强了反应器中的催化剂床的冷却。

    PROCESS AND APPARATUS FOR SULPHURIC ACID PRODUCTION
    42.
    发明申请
    PROCESS AND APPARATUS FOR SULPHURIC ACID PRODUCTION 审中-公开
    硫酸生产工艺及装置

    公开(公告)号：WO2011147431A1

    公开(公告)日：2011-12-01

    申请号：PCT/EP2010/003223

    申请日：2010-05-27

    Applicant: HALDOR TOPSOE A/S ,  MOLLERHOJ, Martin ,  LYKKE, Mads ,  THELEFSEN, Morten ,  SCHOUBYE, Peter

    Inventor： MOLLERHOJ, Martin ,  LYKKE, Mads ,  THELEFSEN, Morten ,  SCHOUBYE, Peter

    IPC: C01B17/765

    CPC classification number: C01B17/765

    Abstract: In sulphuric acid production by oxidation of SO 2 into SO 3 and subsequent hydration of SO 3 , from feed gases having a varying SO 2 concentration, the stability and thermal efficiency of the sulphuric acid plant can be increased by configuring the catalytic reaction zone to match the requirements for conversion. This can be done by appropriate flow and reactor configuration, such as by-passing one or more sections of catalytically active materials, or leading the feed gas through a limited catalytic reaction zone in the case of low SO 2 concentration. The associated benefits are catalytic reaction zones having fewer, smaller and more predictable temperature gradients compared to a plant in which the varying feed gas is directed through the same reaction zones. The invention also relates to a reactor for carrying out the process, and a sulphuric acid production process comprising the conversion process.

    Abstract translation: 在通过将SO 2氧化成SO 3并随后从SO 2浓度变化的原料气中进行SO 3的水合而产生的硫酸中，通过配置催化反应区以适应转化要求，可以提高硫酸装置的稳定性和热效率 。 这可以通过合适的流动和反应器构造来完成，例如旁路一个或多个催化活性材料部分，或者在低SO 2浓度的情况下引导进料气体通过有限的催化反应区。 与其中变化的进料气体通过相同反应区的设备相比，相关的益处是具有更少，更小和更可预测的温度梯度的催化反应区。 本发明还涉及一种用于进行该方法的反应器和包含该转化方法的硫酸生产方法。

    PURIFICATION OF SULPHIDE-CONTAINING GASES
    44.
    发明申请
    PURIFICATION OF SULPHIDE-CONTAINING GASES 审中-公开
    纯化含硫气体

    公开(公告)号：WO1990014876A1

    公开(公告)日：1990-12-13

    申请号：PCT/DK1990000115

    申请日：1990-05-03

    Applicant: HALDOR TOPSOE A/S ,  NIELSEN, Poul, Erik, Hojlund

    Inventor： HALDOR TOPSOE A/S

    IPC: B01D53/34

    CPC classification number: C01B3/56 ,  B01D53/52 ,  C01B2203/043 ,  C01B2203/0485 ,  C10K1/20

    Abstract: The removal of sulphides from gas streams while using a solid absorbent containing tin, tin oxides or mixtures thereof and optionally a stabilizing component consisting of nickel, copper, cobalt, iron or oxides thereof takes place by contacting the sulphide-containing gas stream with the solid absorbent, which is expediently in the form of a carrier with the tin component and the stabilizing component; hereby the absorbent is sulphided and the gas stream desulphided. Subsequently the sulphided absorbents are regenerated by being contacted with a stream of steam. The regeneration process employed is substantially thermoneutral so that superheating and consequent sintering of the absorbent is avoided; moreover it is not necessary to operate at low temperatures, whereby the formation of sulphates as a by-product is avoided.

    A METHOD AND AN APPARATUS FOR CONTINUOUSLY PURIFYING AN OXYGEN-CONTAINING GAS FOR COMBUSTIBLE CONTAMINANTS
    45.
    发明申请
    A METHOD AND AN APPARATUS FOR CONTINUOUSLY PURIFYING AN OXYGEN-CONTAINING GAS FOR COMBUSTIBLE CONTAMINANTS 审中-公开
    用于连续净化可燃污染物的含氧气体的方法和装置

    公开(公告)号：WO1990004742A1

    公开(公告)日：1990-05-03

    申请号：PCT/DK1989000242

    申请日：1989-10-16

    Applicant: HALDOR TOPSOE A/S ,  NIELSEN, Kai, Hasse ,  JENSEN, Frands, Erling

    Inventor： HALDOR TOPSOE A/S

    IPC: F23G07/06

    CPC classification number: F23G7/07 ,  F23G7/068

    Abstract: Combustible impurities in oxygen-containing offgases are burnt according to a method and by an apparatus of the type in which at least some of the heat of combustion is recovered by a regenerative heat exchange in two identical heat exchange zones (10, 11) containing a solid heat exchange material and separated by a combustion chamber (15). The air or gas to be purified flows through both of the heat exchange zones and by means of valves (1, 2, 3, 4) the direction of flow is changed periodically so that the two zones are alternately heated and cooled in periods of 0.1-60 minutes. The risk of discharge of unburnt combustible contaminants to the atmosphere is minimized by dividing the purified gas stream in the first 1-50 % of each period into two part streams of which one is discharged directly from the combustion chamber (15) to a recipient (22) whereas the other is passed through the heat exchange zone (10 or 11) being heated and from there recycled through a line (25 or 24) controlled by a valve (7 or 6) and combined with unpurified gas being passed to the heat exchange zone (11 or 10) being cooled.

    CONDENSING SULFURIC ACID VAPOURS TO PRODUCE SULFURIC ACID
    46.
    发明申请
    CONDENSING SULFURIC ACID VAPOURS TO PRODUCE SULFURIC ACID 审中-公开
    冷凝式硫酸蒸汽生产硫酸

    公开(公告)号：WO1989012025A1

    公开(公告)日：1989-12-14

    申请号：PCT/DK1989000133

    申请日：1989-05-22

    Applicant: HALDOR TOPSOE A/S ,  SCHOUBYE, Peter

    Inventor： HALDOR TOPSOE A/S

    IPC: C01B17/80

    CPC classification number: C01B17/806 ,  B01D53/8609 ,  C01B17/76

    Abstract: When condensing sulfuric acid from gases containing sulfuric acid vapour and steam in excess, e.g. originating from a power station, a substantial decrease of the amount minute droplets of sulfuric acid (the so-called acid mist) escaping to the surroundings is obtained, even in cases where the sulfuric acid plant is equipped with an aerosol filter, if minute nucleation cores are incorporated into the gas in an amount of 10 to 10 solid particles per Nm per 0.1 % H2SO4-vapour in the gas. The nucleation cores may, e.g., be generated by combusting hydrocarbons with >2 carbon atoms or silicones, or added as smoke from an electric arc or welding.

    Abstract translation: 当从含有硫酸蒸气和蒸汽过量的气体中冷凝硫酸， 即使在硫酸装置配备有气溶胶过滤器的情况下，即使是微小的成核，也能够获得大量的硫酸酸滴（所谓的酸性雾）逸出到周边的量 核心以气体中每0.1％H 2 SO 4蒸汽的每Nm 3为10 9至10 12个固体颗粒的量掺入气体中。 成核芯可以例如通过燃烧具有> 2个碳原子的碳氢化合物或硅氧烷，或者由电弧或焊接作为烟添加。

    CARBONYLATION PROCESS
    47.
    发明申请
    CARBONYLATION PROCESS 审中-公开
    碳化过程

    公开(公告)号：WO1986005179A1

    公开(公告)日：1986-09-12

    申请号：PCT/US1986000415

    申请日：1986-02-25

    Applicant: CATALYTICA ASSOCIATES ,  HALDOR TOPSOE A/S

    Inventor： CATALYTICA ASSOCIATES ,  HALDOR TOPSOE A/S ,  GRATE, John, H. ,  HAMM, David, R. ,  VALENTINE, Donald, H.

    IPC: C07C125/065

    CPC classification number: C07C273/1836 ,  C07C269/00 ,  C07C269/04 ,  C07C271/28 ,  C07C275/28

    Abstract: Process for carbonylating a nitrogen-containing organic compound, selected from the group consisting of nitro, nitroso, azo, and azoxy compounds, by reacting said nitrogen-containing organic compound, with carbon monoxide, wherein the improvement comprises the step of : (a) reacting said nitrogen-containing compound with carbon monoxide, in the presence of a primary amine and a catalyst, essentially free of redox active metal components selected from the group consisting of rhodium and ruthenium.

    Abstract translation: 通过使所述含氮有机化合物与一氧化碳反应来羰基化选自硝基，亚硝基，偶氮和偶氮氧化合物的含氮有机化合物的方法，其中所述改进包括以下步骤：（a） 在伯胺和催化剂的存在下使所述含氮化合物与一氧化碳反应，基本上不含选自铑和钌的氧化还原活性金属组分。

    PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM SYNTHESIS GAS
    48.
    发明申请
    PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM SYNTHESIS GAS 审中-公开
    从合成气中制备碳氢化合物的方法

    公开(公告)号：WO2010149263A1

    公开(公告)日：2010-12-29

    申请号：PCT/EP2010/003368

    申请日：2010-06-03

    Applicant: HALDOR TOPSOE A/S ,  SØRENSEN, Esben Lauge ,  JOENSEN, Finn ,  NIELSEN, Poul Erik HØJLUND

    Inventor： SØRENSEN, Esben Lauge ,  JOENSEN, Finn ,  NIELSEN, Poul Erik HØJLUND

    IPC: C07C1/04 ,  C07C1/12

    CPC classification number: C10G2/32 ,  C10G3/49 ,  C10G2300/4012 ,  C10G2300/4081 ,  C10G2400/02 ,  Y02P30/20

    Abstract: A process for the preparation of hydrocarbon products comprising the steps of (a) providing a synthesis gas comprising hydrogen, carbon monoxide and carbon dioxide; (b) reacting the synthesis gas to an oxygenate mixture comprising methanol and dimethyl ether in presence of one or more catalysts which together catalyse a reaction of hydrogen and carbon monoxide to oxygenates at a pressure of at least 4 MPa; (c) withdrawing from step (b) the oxygenate mixture comprising amounts of methanol, dimethyl ether, carbon dioxide and water together with unreacted synthesis gas and introducing the entire amount of the oxygenate mixture without further treatment into a catalytic oxygenate conversion step (d); (d) reacting the oxygenate mixture in presence of a catalyst being active in the conversion of oxygenates to higher hydrocarbons; (e) withdrawing an effluent from step (d) and separating the effluent into a tail gas, a liquid hydrocarbon phase containing the higher hydrocarbons produced in step.(d) and a liquid aqueous phase, wherein the pressure employed in steps (c) to (e) is substantially the same as employed in step (b).

    Abstract translation: 一种用于制备烃产物的方法，包括以下步骤：（a）提供包含氢气，一氧化碳和二氧化碳的合成气; （b）在一种或多种催化剂的存在下使合成气与包含甲醇和二甲醚的含氧混合物反应，所述催化剂在至少4MPa的压力下一起催化氢和一氧化碳与含氧化合物的反应; （c）从步骤（b）中取出含有甲醇，二甲醚，二氧化碳和水的含氧化合物混合物以及未反应的合成气，并将全部量的含氧化合物混合物引入催化氧化合物转化步骤（d）中， ; （d）在含氧化合物转化为高级烃的催化剂存在下使含氧化合物混合物反应; （e）从步骤（d）中取出流出物并将流出物分离成尾气，包含步骤（d）中产生的高级烃的液体烃相和液体水相，其中步骤（c）中使用的压力 至（e）基本上与步骤（b）中使用的相同。

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