公开(公告)号：WO2006073856A2

公开(公告)日：2006-07-13

申请号：PCT/US2005/046526

申请日：2005-12-21

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  WALKER, Christopher, B., Jr. ,  KOLB, Brant, U. ,  GOENNER, Emily, S. ,  JONES, Vivian, W. ,  WANG, Sharon ,  NOYALA, Joan, M.

Inventor： WALKER, Christopher, B., Jr. ,  KOLB, Brant, U. ,  GOENNER, Emily, S. ,  JONES, Vivian, W. ,  WANG, Sharon ,  NOYALA, Joan, M.

CPC classification number: C08J7/047 ,  C08J2433/00 ,  C08K9/04 ,  G02F1/133502 ,  Y10S977/783 ,  Y10S977/834 ,  Y10S977/902 ,  Y10T428/24355 ,  Y10T428/256

Abstract: The present invention includes ultraviolet curable compositions preferably containing discrete, crystalline zirconia nanoparticles with reactive, or copolymerizable, surface modification, in a polymerizable monomer/oligomer resin mixture. It is believed that copolymerizable surface modification provides a functional group that enables the functionalized particle to co-polmerize with the reactive monomers, oligomers, and crosslinkers in the formulation. Relative to surface modifation of the nanoparticles, acrylate functionality is preferred over methacrylate functionality. On the other hand, methacrylate functionality is preferred over non-reactive, or nonpolymerizable, functionality. As the nanocomposite cures, the resultant network is heavily crosslinked by selection of raw materials with substantial acrylate functionality.

Abstract translation: 本发明包括紫外线固化性组合物，其优选地包含在可聚合单体/低聚物树脂混合物中具有反应性或可共聚合的表面改性的离散的结晶氧化锆纳米颗粒。 据信可共聚的表面改性提供了使官能化的颗粒与制剂中的反应性单体，低聚物和交联剂共聚的官能团。 相对于纳米颗粒的表面改性，丙烯酸酯官能度优于甲基丙烯酸酯官能度。 另一方面，甲基丙烯酸酯官能度优于非反应性或不可聚合的官能团。 当纳米复合材料固化时，所得到的网络通过选择具有大量丙烯酸酯官能度的原材料而严重交联。

公开(公告)号：WO2014022643A1

公开(公告)日：2014-02-06

申请号：PCT/US2013/053181

申请日：2013-08-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  HAUPTMANN, Holger ,  SCHMITTNER, Sybille S. ,  SCHECHNER, Gallus ,  KOLB, Brant U. ,  HERRMANN, Andreas

Inventor： HAUPTMANN, Holger ,  SCHMITTNER, Sybille S. ,  SCHECHNER, Gallus ,  KOLB, Brant U. ,  HERRMANN, Andreas

IPC: A61C13/00

CPC classification number: A61C13/0022 ,  A61C5/77 ,  A61C7/00 ,  A61C8/0001 ,  A61C8/005 ,  A61C13/0006 ,  A61C13/01 ,  A61C13/08 ,  B82Y30/00 ,  C04B35/48 ,  C04B35/486 ,  C04B35/6263 ,  C04B35/6269 ,  C04B35/632 ,  C04B35/63424 ,  C04B35/63488 ,  C04B35/638 ,  C04B38/0045 ,  C04B2111/00836 ,  C04B2235/3217 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3248 ,  C04B2235/449 ,  C04B2235/5409 ,  C04B2235/5454 ,  C04B2235/6023 ,  C04B2235/612 ,  C04B2235/6562 ,  C04B2235/6565 ,  C04B2235/6567 ,  C04B2235/781 ,  C04B2235/945 ,  C04B2235/95 ,  C04B2235/96 ,  F04C2270/041 ,  Y10T428/21 ,  Y10T428/24479 ,  Y10T428/2457

Abstract: The invention relates to a dental mill blank comprising a pre-sintered porous zirconia material, the porous pre-sintered zirconia material showing a N2 adsorption of isotherm type IV according to IUPAC classification, the porous pre-sintered zirconia material having a Vickers hardness from about 25 to about 150, the dental mill blank comprising means for reversible attaching it to a machining device. The invention also relates to a process of producing a zirconia dental article comprising the steps of providing a dental mill blank comprising a porous pre-sintered zirconia material, placing the dental mill blank in a machining device, machining the porous zirconia material and to a dental article obtained by such a process.

Abstract translation: 本发明涉及一种包括预烧结多孔氧化锆材料的多孔预烧结氧化锆材料的多孔预烧结氧化锆材料，根据IUPAC分类显示等温线型IV的N 2吸附，多孔预烧结氧化锆材料的维氏硬度约为 25至约150，牙科磨机坯料包括用于可逆地将其附接到加工装置的装置。 本发明还涉及一种生产氧化锆牙科制品的方法，其包括以下步骤：提供包括多孔预烧结氧化锆材料的牙科磨料坯料，将牙科磨料坯料放置在加工装置中，加工多孔氧化锆材料和牙科 通过这样一个过程获得的文章。

公开(公告)号：WO2013116302A1

公开(公告)日：2013-08-08

申请号：PCT/US2013/023794

申请日：2013-01-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  KOLB, William, Blake ,  KOLB, Brant, U. ,  CARPENTER, Samuel, J. ,  CORCORAN, Lindsay, E. ,  HODNE, Taylor, K. ,  LUO, Hui ,  MCGEE, Kari, A. ,  YU, Ta-Hua ,  JINDAL, Karan ,  JING, Naiyong

Inventor： KOLB, William, Blake ,  KOLB, Brant, U. ,  CARPENTER, Samuel, J. ,  CORCORAN, Lindsay, E. ,  HODNE, Taylor, K. ,  LUO, Hui ,  MCGEE, Kari, A. ,  YU, Ta-Hua ,  JINDAL, Karan ,  JING, Naiyong

IPC: C08L101/00 ,  C08K3/36 ,  C08K9/04 ,  C08J3/02 ,  C08J5/00

CPC classification number: G02B5/02 ,  C08J3/245 ,  C08J7/047 ,  C08J7/06 ,  C08J2333/06 ,  C08J2367/02 ,  C08J2433/06 ,  C09D4/00 ,  G02B1/118 ,  Y10T428/24421

Abstract: Material comprising sub-micrometer particles dispersed in a polymeric matrix. The materials are useful in article, for example, for numerous applications including display applications (e.g., liquid crystal displays (LCD), light emitting diode (LED) displays, or plasma displays); light extraction; electromagnetic interference (EMI) shielding, ophthalmic lenses; face shielding lenses or films; window films; antireflection for construction applications; and construction applications or traffic signs.

Abstract translation: 包含分散在聚合物基体中的亚微米颗粒的材料。 这些材料在例如用于包括显示应用（例如液晶显示器（LCD），发光二极管（LED）显示器或等离子体显示器）的许多应用的文章中是有用的; 光提取; 电磁干扰（EMI）屏蔽，眼科镜片; 面罩屏蔽镜片或胶片; 窗膜; 施工应用抗反射; 建筑施工或交通标志。

公开(公告)号：WO2013012587A2

公开(公告)日：2013-01-24

申请号：PCT/US2012045916

申请日：2012-07-09

Applicant: 3M INNOVATIVE PROPERTIES CO ,  KAWATE KOHICHIRO ,  AKIYAMA HIROKO ,  SUGIYAMA NAOTA ,  KOLB BRANT U ,  LARSON ERIC G

Inventor： KAWATE KOHICHIRO ,  AKIYAMA HIROKO ,  SUGIYAMA NAOTA ,  KOLB BRANT U ,  LARSON ERIC G

IPC: C08L63/00 ,  C08G59/18 ,  C08K3/00 ,  C08K5/54 ,  H01L23/29

CPC classification number: H01L23/296 ,  C08K3/36 ,  C08K9/06 ,  C08L63/00 ,  H01L21/563 ,  H01L23/10 ,  H01L23/293 ,  H01L23/295 ,  H01L33/56 ,  H01L2224/16225 ,  H01L2224/32225 ,  H01L2224/48091 ,  H01L2224/48227 ,  H01L2224/73204 ,  H01L2224/92125 ,  H01L2924/12044 ,  H01L2924/00014 ,  H01L2924/00

Abstract: A semiconductor package resin composition of the present invention includes an epoxy resin, a curing agent, inorganic particles, nano-particles surface treated with a silane that contains a photopolymerizable functional group, and a photopolymerization initiator.

Abstract translation: 本发明的半导体封装树脂组合物包括环氧树脂，固化剂，无机颗粒，用含有光聚合官能团的硅烷表面处理的纳米颗粒和光聚合引发剂。

公开(公告)号：WO2012106172A2

公开(公告)日：2012-08-09

申请号：PCT/US2012022663

申请日：2012-01-26

Applicant: 3M INNOVATIVE PROPERTIES CO ,  SHEFELBINE TERRI A ,  ADAIR ERIC W ,  GROOTAERT WERNER M A ,  KOLB BRANT U

Inventor： SHEFELBINE TERRI A ,  ADAIR ERIC W ,  GROOTAERT WERNER M A ,  KOLB BRANT U

IPC: C08L27/12 ,  C08F14/18 ,  C08J5/00 ,  C08K3/22

CPC classification number: C08K3/22 ,  C08F214/18 ,  C08F214/184 ,  C08L27/12 ,  C08L27/18

Abstract: Described herein is a curable fluoropolymer composition comprising: an amorphous perfluoropolymer; and nanoparticles of zirconium oxide.

Abstract translation: 本文描述的是可固化的含氟聚合物组合物，其包含：无定形全氟聚合物; 和氧化锆纳米颗粒。

公开(公告)号：WO2012067936A3

公开(公告)日：2012-08-02

申请号：PCT/US2011060170

申请日：2011-11-10

Applicant: 3M INNOVATIVE PROPERTIES CO ,  SHEFLBINE TERRI A ,  ADAIR ERIC W ,  GROOTAERT WERNER M A ,  JING NAIYONG ,  KOLB BRANT U

Inventor： SHEFLBINE TERRI A ,  ADAIR ERIC W ,  GROOTAERT WERNER M A ,  JING NAIYONG ,  KOLB BRANT U

IPC: C08L27/12 ,  C08F14/18 ,  C08J5/00 ,  C08K3/00

CPC classification number: C08L27/20 ,  C08F6/22 ,  C08F214/16 ,  C08F214/262 ,  C08K3/22 ,  C08L27/18

Abstract: Described herein is a method of coagulating a fluoropolymer latex comprising: providing an amorphous fluoropolymer latex; providing unmodified inorganic nanoparticles; contacting the amorphous fluoropolymer latex with a sufficient amount of unmodified inorganic nanoparticles to coagulate the amorphous fluoropolymer.

Abstract translation: 本文描述了一种凝结含氟聚合物胶乳的方法，包括：提供无定形含氟聚合物胶乳; 提供未改性的无机纳米粒子; 使无定形含氟聚合物胶乳与足够量的未改性的无机纳米粒子接触以凝结无定形含氟聚合物。

公开(公告)号：WO2011082031A1

公开(公告)日：2011-07-07

申请号：PCT/US2010/061539

申请日：2010-12-21

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  KOLB, Brant U. ,  HENDRICKSON, Mark J. ,  MATHERS, James P. ,  HUMPAL, Kathleen M. ,  SHARMA, Neeraj ,  BROSTROM, Myles L.

Inventor： KOLB, Brant U. ,  HENDRICKSON, Mark J. ,  MATHERS, James P. ,  HUMPAL, Kathleen M. ,  SHARMA, Neeraj ,  BROSTROM, Myles L.

IPC: C01G25/00 ,  C01G25/02 ,  C04B35/486

CPC classification number: C01G25/00 ,  B82Y30/00 ,  C01G25/006 ,  C01G25/02 ,  C01P2002/52 ,  C01P2002/60 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2004/64 ,  C04B35/486 ,  C04B35/624 ,  C04B35/6263 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3244 ,  C04B2235/443 ,  C04B2235/449 ,  C04B2235/5454 ,  C04B2235/549 ,  C04B2235/9615 ,  C08K3/22

Abstract: Zirconia-based particles, sols containing the zirconia-based particles, methods of making the sols and the zirconia-based particles, composites containing the zirconia-based particles in an organic matrix, and sintered bodies prepared from the zirconia-based particles are described. The zirconia-based particles are crystalline, have a primary particles size no greater than 100 nanometers, and are doped with a lanthanide element or with both a lanthanide element and yttrium.

Abstract translation: 描述了氧化锆基颗粒，含有氧化锆基颗粒的溶胶，制备溶胶和氧化锆基颗粒的方法，在有机基质中含有氧化锆基颗粒的复合材料，以及由氧化锆基颗粒制备的烧结体。 氧化锆基颗粒是结晶的，具有不大于100纳米的初级颗粒尺寸，并掺杂有镧系元素或镧系元素和钇。

公开(公告)号：WO2010121019A1

公开(公告)日：2010-10-21

申请号：PCT/US2010/031225

申请日：2010-04-15

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  COGGIO, William D., ,  HUIZINGA, John S., ,  STEINER, Michael L., ,  WATKINS, Robert F., ,  HAO, Encai, ,  KOLB, William Blake, ,  ZHU, Peiwang, ,  FREE, Michael Benton, ,  KOLB, Brant U., ,  CHEN-HO, Kui, ,  HUMPAL, Paul E., ,  SMITH, Kenneth L., ,  TAPIO, Scott M.,

Inventor： COGGIO, William D., ,  HUIZINGA, John S., ,  STEINER, Michael L., ,  WATKINS, Robert F., ,  HAO, Encai, ,  KOLB, William Blake, ,  ZHU, Peiwang, ,  FREE, Michael Benton, ,  KOLB, Brant U., ,  CHEN-HO, Kui, ,  HUMPAL, Paul E., ,  SMITH, Kenneth L., ,  TAPIO, Scott M.,

IPC: B32B3/00

CPC classification number: G02B5/124 ,  G02B2207/107

Abstract: Retroreflecting optical constructions are disclosed. A disclosed retroreflecting optical construction includes a retroreflecting layer that has a retroreflecting structured major surface, and an optical film that is disposed on the retroreflecting structured major surface of the retroreflecting layer. The optical film has an optical haze that is not less than about 30%. Substantial portions of each two neighboring major surfaces in the retroreflecting optical construction are in physical contact with each other.

Abstract translation: 公开了反射光学结构。 公开的回射光学构造包括具有回射结构主表面的回射层和设置在回射层的回射结构化主表面上的光学膜。 光学膜具有不小于约30％的光学雾度。 回射光学结构中的每两个相邻主表面的实质部分彼此物理接触。

公开(公告)号：WO2010120864A1

公开(公告)日：2010-10-21

申请号：PCT/US2010/031010

申请日：2010-04-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  HAO, Encai ,  KOLB, William Blake ,  KOLB, Brant U. ,  OSTILIE, Brian W. ,  JING, Naiyong ,  FREE, Michael Benton ,  REN, Hui ,  BROTT, Robert L. ,  LU, Fei ,  SHERMAN, Audrey A. ,  TAPIO, Scott M. ,  HOYLE, Charles D. ,  WHEATLEY, John A.

Inventor： HAO, Encai ,  KOLB, William Blake ,  KOLB, Brant U. ,  OSTILIE, Brian W. ,  JING, Naiyong ,  FREE, Michael Benton ,  REN, Hui ,  BROTT, Robert L. ,  LU, Fei ,  SHERMAN, Audrey A. ,  TAPIO, Scott M. ,  HOYLE, Charles D. ,  WHEATLEY, John A.

IPC: G02B1/11 ,  H01J29/89

CPC classification number: G02B5/0247 ,  G02B5/0242 ,  G02B5/0268 ,  G02B5/0278 ,  H01J2211/44 ,  Y10T428/249921 ,  Y10T428/249953 ,  Y10T428/25

Abstract: Optical film is disclosed. The optical film includes a binder, a plurality of particles, and a plurality of interconnected voids. The volume fraction of the plurality of interconnected voids in the optical film is not less than about 20%. The weight ratio of the binder to the plurality of the particles is not less than about 1:2.

Abstract translation: 公开了光学膜。 光学膜包括粘合剂，多个颗粒和多个相互连接的空隙。 光学膜中多个相互连接的空隙的体积分数不小于约20％。 粘合剂与多个颗粒的重量比不小于约1:2。

公开(公告)号：WO2009085926A3

公开(公告)日：2010-08-26

申请号：PCT/US2008087385

申请日：2008-12-18

Applicant: 3M INNOVATIVE PROPERTIES CO ,  KOLB BRANT U ,  ANDERSON DANNY B ,  DAVIDSON ROBERT S ,  HENDRICKSON MARK J ,  LEACH JAMES J ,  MCKENZIE TAUN L

Inventor： KOLB BRANT U ,  ANDERSON DANNY B ,  DAVIDSON ROBERT S ,  HENDRICKSON MARK J ,  LEACH JAMES J ,  MCKENZIE TAUN L

IPC: C01G25/02 ,  C04B35/119

CPC classification number: B01J19/0053 ,  B82Y30/00 ,  C01G25/02 ,  C04B35/486 ,  C04B35/6263 ,  C04B2235/3225 ,  C04B2235/449 ,  C04B2235/5454 ,  C04B2235/72

Abstract: A method of preparing zirconia-containing nanoparticles and a method of preparing a composite material that includes the zirconia-containing nanoparticles are provided. A method of treating a zirconium carboxylate salt solution to remove alkali metal ions and alkaline earth ions is provided. The treated solution can be used as a feedstock to prepare the zirconia-containing nanoparticles. Additionally, a continuous hydrothermal reactor system is provided that can be used, for example, to prepare the zirconia-containing nanoparticles.

Abstract translation: 提供了制备含氧化锆的纳米粒子的方法和制备包含含氧化锆的纳米粒子的复合材料的方法。 提供了一种处理羧酸锆盐溶液以除去碱金属离子和碱土离子的方法。 经处理的溶液可用作制备含氧化锆的纳米颗粒的原料。 另外，提供连续的水热反应器系统，其可以用于例如制备含氧化锆的纳米颗粒。