公开(公告)号：WO2014054945A2

公开(公告)日：2014-04-10

申请号：PCT/NL2013050698

申请日：2013-10-01

Applicant: STAMICARBON BV DBA MT INNOVATION CT ,  PELLEGRINI LAURA ANNAMARIA

Inventor： PELLEGRINI LAURA ANNAMARIA

IPC: F25J3/02 ,  C10L3/10

CPC classification number: F25J3/0266 ,  C10L3/102 ,  C10L3/103 ,  C10L3/104 ,  F25J3/0209 ,  F25J3/0233 ,  F25J2200/04 ,  F25J2200/08 ,  F25J2200/40 ,  F25J2200/74 ,  F25J2200/78 ,  F25J2210/66 ,  F25J2220/66 ,  F25J2235/60 ,  Y02C10/12

Abstract: The invention relates to a process for the removal of CO2 from acid gas by cryogenic distillation performed in two steps. The feed mixture is first distilled at high pressure (at least 45 bar) in a first distillation column. The top product or a part thereof is then, after heating, subjected to a second distillation step at a lower pressure (lower than 45 bar). The top product of the second distillation step is methane of high purity (more than 99 mol.%). The bottom product of the second distillation step is recycled back to the first distillation column. The method according to the invention allows complete separation of methane also at higher level of acidic components, is economical and does not result in solid CO2 build-up, which is a common problem in cryogenic distillation.

Abstract translation: 本发明涉及通过两步进行的低温蒸馏从酸性气体中除去CO 2的方法。 首先在第一蒸馏塔中高压（至少45巴）蒸馏进料混合物。 然后，顶部产品或其一部分在加热后进行较低压力（低于45巴）的第二蒸馏步骤。 第二蒸馏步骤的顶部产物是高纯度（大于99mol％）的甲烷。 第二蒸馏步骤的底部产物被循环回到第一蒸馏塔。 根据本发明的方法允许在较高水平的酸性组分中完全分离甲烷，是经济的并且不会导致固体CO 2堆积，这是在低温蒸馏中的常见问题。

公开(公告)号：WO2013169111A1

公开(公告)日：2013-11-14

申请号：PCT/NL2013/050351

申请日：2013-05-10

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER ,  ENEA - CASACCIA RESEARCH CENTER ,  YEDA RESEARCH AND DEVELOPMENT CO., LTD.

Inventor： IAQUANIELLO, Gaetano ,  CAPOFERRI, Daniela ,  FABRIZI, Fabrizio ,  EPSTEIN, Michael

IPC: F22B1/00 ,  F01K3/24 ,  F01K7/22 ,  F22B1/02 ,  F01K3/00

CPC classification number: F01K13/00 ,  F01K3/004 ,  F01K3/08 ,  F01K3/24 ,  F01K7/16 ,  F01K7/22 ,  F03G6/005 ,  F22B1/006 ,  F22B1/028 ,  Y02E10/46 ,  Y02E20/16

Abstract: Method for modifying a solar thermal power plant (2) operating on conventional oil based technology into a hybrid solar thermal power plant (1), wherein the method comprises: • providing an oil based solar thermal power plant (2) comprising a solar collection system with at least one radiation absorber tube containing a heat transfer oil to be heated by means of the solar collection system, • providing an molten salts solar thermal power plant, (4) wherein the molten salts solar thermal power plant comprises a solar collection system to heat a molten salts mixture • coupling of the respective plants such that the hybrid solar thermal power plant is configured to heat medium temperature steam that is generated by the oil based solar power plant by means of the molten salts mixture thereby producing high temperature steam and subsequently supplying it to a steam turbine (40) to generate electricity.

Abstract translation: 一种用于将以常规油基技术操作的太阳能发电厂（2）修改为混合太阳能发电厂（1）的方法，其中所述方法包括： 提供一种油基太阳能热电厂（2），其包括具有至少一个辐射吸收管的太阳能收集系统，所述辐射吸收管包含借助太阳能收集系统加热的传热油。 提供一种熔盐太阳能热电厂，（4）其中该熔盐太阳能发电厂包括一个用于加热熔融盐混合物的太阳能收集系统。 使得混合太阳能发电厂被配置为通过熔融盐混合物来加热由油基太阳能发电厂产生的介质温度的蒸汽，从而产生高温蒸汽并随后将其供应到蒸汽轮机 （40）发电。

公开(公告)号：WO2013141704A1

公开(公告)日：2013-09-26

申请号：PCT/NL2013/050203

申请日：2013-03-19

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER ,  ENEA, AGENZIA NATIONALE PER LE NUOVE TECNOLOGIE, L'ENERGIA E LO SVILUPPO ECONOMICO SOSTENIBILE

Inventor： IAQUANIELLO, Gaetano ,  CAPOFERRI, Daniela ,  BARSI, Adriano ,  FABRIZI, Fabrizio ,  GAGGIOLI, Walter ,  GIACONIA, Alberto ,  RINALDI, Luca

IPC: F01K3/24 ,  F22B1/00 ,  F22B1/02

CPC classification number: F01K3/24 ,  F01K3/20 ,  F01K3/205 ,  F01K3/22 ,  F03G6/003 ,  F03G6/005 ,  F03G6/065 ,  F03G6/067 ,  F22B1/006 ,  F22B1/028 ,  F22B35/001 ,  F22D1/003 ,  F22G5/04 ,  Y02E10/46

Abstract: A back-up boiler system for a solar thermal power plant (201) for transferring solar energy into electricity, said back-up boiler system comprising a combustion chamber (70) and a convection section (80) in fluid connection with said combustion chamber (70), wherein in the convection section (80) at least a first heat exchanger (92) is provided for heating a molten salts mixture of the solar thermal power plant and a second heat exchanger (90) for pre-heating boiler feed water of the solar thermal power plant, wherein the back-up boiler system (25) is configured to allow selection between only providing heat to the first heat exchanger (92), only providing heat to the second heat exchanger (90) and providing heat to both heat exchangers (90, 92), preferably dependent on availability of solar radiation and/or dependent on demand of power generation. The invention also relates to a solar thermal power plant (201) for transferring solar energy into electricity and a method for operating a solar thermal power plant.

Abstract translation: 一种用于太阳能发电厂（201）的备用锅炉系统，用于将太阳能转移到电中，所述备用锅炉系统包括与所述燃烧室流体连接的燃烧室（70）和对流部分（80） 70），其中在所述对流部（80）中，至少设置有第一热交换器（92），用于加热所述太阳能发电厂和第二热交换器（90）的熔融盐混合物，用于预热锅炉给水 所述太阳能热力发电设备，其中所述备用锅炉系统（25）被配置为允许仅在向所述第一热交换器（92）提供热量之间进行选择，仅向所述第二热交换器（90）提供热量并且向所述第二热交换器 热交换器（90,92），优选地取决于太阳辐射的可用性和/或取决于发电的需求。 本发明还涉及一种用于将太阳能转移到电力的太阳能发电厂（201）和用于操作太阳能发电厂的方法。

公开(公告)号：WO2013137720A1

公开(公告)日：2013-09-19

申请号：PCT/NL2013/050157

申请日：2013-03-11

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： MORICO, Barbara ,  SALLADINI, Annarita ,  IAQUANIELLO, Gaetano

IPC: C01B3/38 ,  B01J8/00 ,  B01J8/06 ,  C01B3/48

CPC classification number: C01B3/382 ,  B01J7/00 ,  B01J8/009 ,  B01J8/067 ,  B01J19/02 ,  B01J2208/00212 ,  B01J2219/0004 ,  B01J2219/0286 ,  C01B3/384 ,  C01B3/48 ,  C01B3/501 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/0833 ,  C01B2203/143 ,  C01B2203/146 ,  C01B2203/82 ,  Y02P20/134

Abstract: Disclosed is a process for the production of hydrogen in a reactor system comprising a steam reforming reaction zone comprising a reforming catalyst and a membrane separation zone comprising a hydrogen-selective membrane. The process involves a reaction system of so-called open architecture, wherein the reforming zone and the membrane separation zone operate independently of each other. The invention provides the heat for the reforming reaction through heat exchange from liquid molten salts, preferably heated by solar energy.

Abstract translation: 公开了一种在反应器系统中生产氢气的方法，其包括包含重整催化剂和包含氢选择性膜的膜分离区的蒸汽重整反应区。 该方法涉及所谓的开放结构的反应体系，其中重整区和膜分离区彼此独立地操作。 本发明通过液体熔融盐的热交换提供热重整反应，优选由太阳能加热。

公开(公告)号：WO2013062415A1

公开(公告)日：2013-05-02

申请号：PCT/NL2012/050748

申请日：2012-10-26

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： IAQUANIELLO, Gaetano ,  ANTONETTI, Elena ,  CONTALDO, Palma

IPC: C01B3/38 ,  C01B3/48 ,  C07C29/151

CPC classification number: C01B3/26 ,  C01B3/30 ,  C01B3/38 ,  C01B3/386 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0475 ,  C01B2203/061 ,  C01B2203/1235 ,  C01B2203/141 ,  C01B2203/142 ,  C07C29/00 ,  C07C29/1518

Abstract: Method for producing synthesis gas for methanol production The present invention relates to a method for producing synthesis gas from a hydrocarbon containing feed, which synthesis gas is particularly suitable for subsequent use in methanol production. In this method, a feed (100) is divided into two streams, wherein one stream is subjected to catalytic partial oxidation (CPO) (2) and the other stream is subjected to steam reforming (5) followed by a water gas shift reaction (51). The two streams are then recombined and can be used further in methanol synthesis (6). The recombined stream preferably has an R ratio, being a molar ratio (H 2 -C0 2 )/(CO+C0 2 ), in the range of 1.9 - 2.2 and preferably about 2. The invention further relates to a method for producing methanol from a hydrocarbon containing feed, wherein first synthesis gas is obtained according to the method of the invention, which synthesis gas is further used to produce methanol. Also, the invention relates to a method of adapting an existing methanol plant to the methanol production process of the invention.

Abstract translation: 用于生产甲醇生产合成气的方法本发明涉及一种由含烃进料生产合成气的方法，该合成气特别适用于随后用于甲醇生产。 在该方法中，将进料（100）分成两股料流，其中一条料流进行催化部分氧化（CPO）（2），另一条料流进行蒸汽重整（5），随后进行水煤气变换反应 51）。 然后将两种物流重组，并可以进一步用于甲醇合成（6）。 重组流优选具有在1.9-2.2的范围内的摩尔比（H 2 -CO 2）/（CO + CO 2）的R比。优选地，本发明还涉及一种从烃生产甲醇的方法 其中根据本发明的方法获得第一合成气，该合成气被进一步用于生产甲醇。 本发明还涉及使现有的甲醇装置适应本发明的甲醇生产方法。

公开(公告)号：WO2013062413A1

公开(公告)日：2013-05-02

申请号：PCT/NL2012/050744

申请日：2012-10-25

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： IAQUANIELLO, Gaetano ,  CUCCHIELLA, Barbara ,  ANTONETTI, Elena

IPC: C01B3/38 ,  C01B3/48 ,  C07C29/151

CPC classification number: C07C29/48 ,  C01B3/323 ,  C01B3/386 ,  C01B3/48 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0475 ,  C01B2203/061 ,  C01B2203/1235 ,  C01B2203/1258 ,  C01B2203/142 ,  C07C29/1518 ,  C07C31/04

Abstract: Method for producing synthesis gas for methanol production The present invention relates to a method for producing synthesis gas from a hydrocarbon containing feed, which synthesis gas is particularly suitable for subsequent use in methanol production. In this method, a hydrocarbon containing feed, particularly natural gas (100), is subjected to catalytic partial oxidation (CPO) (2), followed by the water gas shift (WGS) (4) reaction of a part of the reformed feed. At least part of the shifted feed is then subjected to hydrogen purification, preferably by pressure swing adsorption (PSA) (5) to obtain pure hydrogen (108), which hydrogen is subsequently combined with the remaining parts of the feeds to yield synthesis gas particularly suitable for methanol synthesis. The recombined stream preferably has an R ratio, being the molar ratio (H 2 -C0 2 )/(CO+C0 2 ), in the range 1.9-2.2 and preferably about 2. The invention further relates to a method for producing methanol from a hydrocarbon containing feed, wherein first synthesis gas is obtained according to the method of the invention, which synthesis gas is further used to produce methanol.

Abstract translation: 用于生产甲醇生产合成气的方法本发明涉及一种由含烃进料生产合成气的方法，该合成气特别适用于随后用于甲醇生产。 在该方法中，将含烃进料，特别是天然气（100）进行催化部分氧化（CPO）（2），然后进行部分重整进料的水煤气变换（WGS）（4）反应。 然后至少部分转移的进料进行氢气净化，优选通过变压吸附（PSA）（5）进行氢气净化，以获得纯氢气（108），该氢气随后与进料的剩余部分组合以产生合成气，特别是 适合甲醇合成。 重组流优选具有在1.9-2.2范围内且优选约2的摩尔比（H 2 -CO 2）/（CO + CO 2）的R比。本发明还涉及一种由含有 进料，其中根据本发明的方法获得第一种合成气，该合成气被进一步用于生产甲醇。

公开(公告)号：WO2013025108A1

公开(公告)日：2013-02-21

申请号：PCT/NL2012/050576

申请日：2012-08-17

Applicant: STAMICARBON B.V. ,  TROLLUX, Jacques Francois Andre

Inventor： TROLLUX, Jacques Francois Andre

IPC: F17C13/08 ,  F17C5/06 ,  F17C7/02 ,  F17C7/00

CPC classification number: B63B25/14 ,  B63B27/24 ,  F17C1/002 ,  F17C5/06 ,  F17C7/00 ,  F17C7/02 ,  F17C13/082 ,  F17C2221/013 ,  F17C2221/033 ,  F17C2223/0115 ,  F17C2223/0123 ,  F17C2223/0153 ,  F17C2223/033 ,  F17C2223/035 ,  F17C2260/02 ,  F17C2260/04 ,  F17C2265/06 ,  F17C2270/0105 ,  F17C2270/0155

Abstract: Disclosed is a method of transporting C0 2 by ship for the purpose of storage in the ocean. The C0 2 is transported at a temperature between -25°C and +25°C, and under a pressure that is sufficiently high for the C0 2 to be in a liquid or supercritical state. The choice of temperature/pressure conditions for the C0 2 enables the transport of C0 2 one way to be effectively combined with transport of compressed natural gas (CNG) the other way. Ships can be used that have relatively cheap tubular containment equipment similar to the type normally used for CNG but with lower pressure and not subject to cyclic thermal and mechanical effects of pressurizing and depressurizing.

Abstract translation: 公开了为了在海洋中储存的目的，用船运送CO 2的方法。 CO 2在-25℃和+ 25℃之间的温度下运输，并且在足够高的压力下使CO 2处于液体或超临界状态。 CO 2的温度/压力条件的选择使得CO 2的输送能够有效地与压缩天然气（CNG）的运输有效结合。 可以使用具有类似于通常用于CNG的类型的相对便宜的管状容纳设备的船舶，但是具有较低的压力并且不受加压和减压的循环热和机械效应的影响。

公开(公告)号：WO2012177137A1

公开(公告)日：2012-12-27

申请号：PCT/NL2012/050444

申请日：2012-06-25

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER ,  IAQUANIELLO, Gaetano ,  CUCCHIELLA, Barbara ,  ANTONETTI, Elena

Inventor： IAQUANIELLO, Gaetano ,  CUCCHIELLA, Barbara ,  ANTONETTI, Elena

IPC: C01B3/02 ,  C01B3/38 ,  C01B3/48 ,  C07C273/04

CPC classification number: C01C1/04 ,  C01B3/025 ,  C01B3/386 ,  C01B3/48 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0288 ,  C01B2203/043 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/068 ,  C01B2203/1241 ,  C01B2203/127 ,  C01B2203/148 ,  C07C273/04

Abstract: Disclosed is a process for the production of ammonia comprising a step wherein synthesis gas is formed by catalytic partial oxidation. Also disclosed is a process of producing urea, wherein ammonia is formed in a process involving a step of catalytic partial oxidation, and carbon dioxide formed in the same process is reacted with said ammonia so as to form urea.

Abstract translation: 公开了一种生产氨的方法，包括通过催化部分氧化形成合成气的步骤。 还公开了生产尿素的方法，其中在涉及催化部分氧化步骤的方法中形成氨，并且将在相同方法中形成的二氧化碳与所述氨反应以形成尿素。

公开(公告)号：WO2012112038A1

公开(公告)日：2012-08-23

申请号：PCT/NL2012/050080

申请日：2012-02-14

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER ,  TROLLUX, Jacques Francois Andre

Inventor： TROLLUX, Jacques Francois Andre

IPC: F17C3/02

CPC classification number: F17C3/022 ,  F17C2201/0109 ,  F17C2201/0128 ,  F17C2201/0157 ,  F17C2201/0166 ,  F17C2201/032 ,  F17C2201/052 ,  F17C2203/0333 ,  F17C2203/0354 ,  F17C2203/0358 ,  F17C2203/0631 ,  F17C2203/0651 ,  F17C2203/0678 ,  F17C2221/033 ,  F17C2223/0161 ,  F17C2223/033 ,  F17C2223/047 ,  F17C2227/0135 ,  F17C2227/0178 ,  F17C2270/0136

Abstract: Disclosed is a concrete tank for very large LNG tanks. The invention utilizes membrane technology in concrete structures that deviate from the standard cylindrical constructions. Typical concrete housings of the invention are a parallelepipedic structure, or an annular structure comprising two concentric walls. Both structures can be covered by a gabled or an arched roof, and avoid the size limitations imposed on cylindrical structures as a result of the size limitations inherent to concrete domes. The invention proposes also several ways to improve the available working height of LNG within such concrete structures of a given height.

Abstract translation: 公开了一种用于非常大型LNG罐的混凝土罐。 本发明利用膜技术在混凝土结构中偏离标准圆柱结构。 本发明的典型的混凝土外壳是平行六面体结构或包括两个同心壁的环形结构。 这两种结构都可以被山墙或拱形屋顶覆盖，并且由于混凝土圆顶固有的尺寸限制，避免了对圆柱形结构施加的尺寸限制。 本发明还提出了在给定高度的这种混凝土结构内改善LNG的可用工作高度的若干方式。

公开(公告)号：WO2011099844A8

公开(公告)日：2012-08-16

申请号：PCT/NL2010050069

申请日：2010-02-12

Applicant: STAMICARBON ,  ELIASSON JOHANNA ,  ERIKSSON YLVA ,  HOLMSTROM DAVID ,  HULTEBERG P CHRISTIAN ,  KARLSSON HANS T ,  NILSSON FILIP ,  OJALA FRIDA ,  VAN DEN TILLAART JOHAN ALBERT ARNO

Inventor： ELIASSON JOHANNA ,  ERIKSSON YLVA ,  HOLMSTROM DAVID ,  HULTEBERG P CHRISTIAN ,  KARLSSON HANS T ,  NILSSON FILIP ,  OJALA FRIDA ,  VAN DEN TILLAART JOHAN ALBERT ARNO

IPC: C07C273/04

CPC classification number: C07C273/04 ,  B01D53/58 ,  B01D2253/102 ,  B01D2253/108 ,  Y02A50/2346 ,  Y02P20/142 ,  Y02P20/582

Abstract: Disclosed is a method for the removal of ammonia from the off-gas of a finishing section of a urea production plant. The method comprises contacting the off-gas with a solid adsorbent capable of physically adsorbing ammonia, particularly activated carbon or zeolite. Thereupon the solid adsorbent having ammonia adsorbed thereon is separated from the gas and regenerated by dissolving ammonia in an extraction liquid, preferably water. After separating the water from the solid adsorbent, the latter is re-used in the process.

Abstract translation: 公开了一种从尿素生产设备的精加工部分的废气中除去氨的方法。 该方法包括使废气与能够物理吸附氨，特别是活性炭或沸石的固体吸附剂接触。 因此，将吸附有氨的固体吸附剂与气体分离，并通过将氨溶解在萃取液中，优选水中再生。 在从固体吸附剂中分离水后，后者在该过程中被重新使用。