Abstract:
Provided is a sodium sulfur battery. The present invention includes a cartridge pipe that holds sodium and has a sodium discharge hole formed in a lower portion to discharge molten sodium; a solid electrolyte pipe that accommodates the cartridge pipe and allows sodium ion passage; a positive electrode container that accommodates the solid electrolyte pipe and sulfur; an insulating member that insulates a space between the solid electrolyte pipe and the positive electrode container; a negative electrode cover that is disposed to seal an upper portion of the cartridge pipe; a stopper member that is provided in an upper portion of the sodium discharge hole and blocks the sodium discharge hole; and a fixed member that is fixedly coupled with an upper portion of the stopper member and is automatically melted and cut when the sodium sulfur battery reaches a temperature that is equal to or higher than a normal operation temperature.
Abstract:
The present invention provides a sodium sulfur rechargeable battery which includes a cartridge tube which stores sodium and has a discharge hole which discharges molten sodium in a lower part in order to secure the safety of a battery by preventing an additional reaction of sulfur and sodium by blocking the supply of sodium in an emergency, a solid electrolyte tube which receives the cartridge tube and transmits sodium ions, an anode container which receives the solid electrolyte tube and sulfur, an insulating member which bonds the solid electrolyte tube to the anode container and closes a space between the solid electrolyte tube and the anode container, and a safety part which is installed inside or outside the cartridge tube and controls the amount of sodium which is supplied to a space between the solid electrolyte tube and the cartridge tube.
Abstract:
Disclosed is a jig for the thermal compression bonding of a sodium-sulfur battery. The jig comprises an inner diameter jig that has a cylindrical shape and supports a cathode-bonding material or an anode-bonding material by making the outer circumference part thereof be in contact with the inner circumference part of the cathode-bonding material or the anode-bonding material, thereby preventing the inward distortion of the cathode-bonding material or the anode-bonding material during thermal compression bonding; and an outer diameter jig that has a cylindrical shape and prevents the outward distortion of the cathode-bonding material or the anode-bonding material during the thermal compression bonding of the cathode-bonding material or the anode-bonding material by making the inner circumference part thereof be in contact with the outer circumference part of the cathode-bonding material or the anode-bonding material.
Abstract:
Provided is a sodium sulfur battery which includes a cartridge cylinder, a solid electrolyte cylinder, a positive electrode container, an insulation member, and a safe part. The cart cartridge cylinder contains sodium and includes an outlet to discharge sodium to ensure safety of a battery by blocking sodium supply in an emergent situation to prevent additional reactions of sodium and sulfur. The solid electrolyte cylinder contains the cart cartridge cylinder and passes sodium ions through. The positive electrode container contains the solid electrolyte cylinder and sulfur. The insulation member joins the solid electrolyte cylinder and the positive electrode container, and seals a space between the solid electrolyte cylinder and the positive electrode container. The safe part is arranged inside or outside the cartridge cylinder and controls the amount of sodium supplied to a space between the cartridge cylinder and the solid electrolyte cylinder.
Abstract:
안전관을 통한 안전성 확보의 한계를 극복하고, 전지의 안전성을 보다 높일 수 있으며, 전해질관 파손시 나트륨의 공급을 원천적으로 차단하여 전지의 안전성을 확보할 수 있도록, 유황이 수용되는 양극실과, 나트륨이 수용되는 음극실, 양극실과 음극실 사이에 설치되어 나트륨 이온만을 선택적으로 이동시키는 고체전해질을 포함하여 충방전이 이루어지는 전지부와; 상기 전지부 외측에 배치되며 나트륨을 수용하는 음극용기; 상기 음극용기와 상기 전지부의 음극실 사이에 연결되어 음극실로 나트륨을 유통시키기 위한 나트륨 공급부를 포함하는 나트륨 유황 전지를 제공한다.
Abstract:
본 발명은 분진 발생이 없고 연마시간을 단축시키며 산화물이 없는 코팅층을 형성하여 내식성과 내구성을 높일 수 있는 나트륨-황 이차전지 및 이의 금속용기 제조방법을 제공한다. 본 발명에 따른 나트륨-황 이차전지의 금속용기 제조방법은 오목한 내부공간이 형성된 금속용기 본체를 준비하는 단계와, 저온분사 장치를 이용하여 금속용기 본체의 내면에 코팅분말과 고압가스를 초음속으로 분사함으로써 코팅분말을 금속용기 본체에 점착시켜 코팅층을 형성하는 단계를 포함한다.
Abstract:
PURPOSE: A sodium-sulfur secondary battery and a manufacturing method of metal case thereof are provided to shorten polishing time and prevent dust generation in a coating layer formation process. CONSTITUTION: A manufacturing method of a metal case of the sodium - sulfur secondary battery comprises the following steps: preparing a metal case main body in which an concave internal space is formed; and forming a coating layer(132) by welding coating powder in the metal case main body. The coating layer formation step is formed by spraying high pressure gas and coating powder inside the metal case main body by using a low-temperature sprayer. The coating powder comprises one or more of the following: nickel -chrome alloy, chrome-iron alloy and cobalt-chrome-tungsten alloy'.
Abstract:
PURPOSE: Thermal-spray coating material and method of an annealing roll used for annealing a high-Mn cold-rolled steel sheet are provided to prevent reaction to manganese oxide and ensure heat resistance within a temperature range of 600-1100°C, using titanium compound. CONSTITUTION: Thermal-spray coating material of an annealing roll comprises titanium compound and metallic binder. The annealing roll is used for annealing the high-Mn cold-rolled steel sheet. The metallic binder comprises 45-60 weight% of Co, 8-15 weight% of Ni, 16-30 weight% of Cr, 3-10 weight% of Al and 0.3-1.5 weight% of Y. The metallic binder has 5-35vol% of the titanium compound. The titanium compound is selected from a group consisting of titanium oxide, titanium carbide, titanium nitride and titanium boride.