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公开(公告)号：KR1020000027446A
公开(公告)日：2000-05-15
申请号：KR1019980045378
申请日：1998-10-28
Applicant: 한국과학기술연구원
CPC classification number: B01D67/0011 , B01D67/0016 , B01D69/10 , B01D71/64 , B01D71/68 , B01D2325/022 , B01D2325/026 , Y10T428/24998
Abstract: PURPOSE: A method is provided to easily control the size of a pore and to reduce the distribution of the pore size as well as to improve the permeability and the mechanical intensity by fixing the structure of a high molecular solution with the physical gelation of the high molecular solution. CONSTITUTION: An asymmetric support membrane is produced by the steps of: preparing a high molecular solution by dissolving 15-35wt% of a high molecule on the basis of total weight of a high molecular solution in a single main solvent for changing a high molecular solution into physical gel or in a mixed solvent adding a co-solvent to the main solvent; and producing an asymmetric support membrane by inducing phases to be separated through the deposition of the prepared high molecular solution in water after physically gelating the solution by forming the solution in the final membrane. The high molecule is selected from a group consisting of poly vinyl chloride, polyether sulfone, polyether imide and polyamic(methylester).
Abstract translation: 目的：提供一种方法来容易地控制孔的尺寸并减小孔径的分布，以及通过将高分子溶液的结构固定在高的物理凝胶上来提高渗透性和机械强度 分子溶液。 构成：通过以下步骤制备不对称支撑膜：通过在单一主要溶剂中基于高分子溶液的总重量将15-35wt％的高分子溶解以改变高分子溶液来制备高分子溶液 进入物理凝胶或在向主溶剂中加入共溶剂的混合溶剂中; 以及通过在通过在最终膜中形成溶液物理凝胶化溶液之后，通过将所制备的高分子溶液沉积在水中来诱导待分离的相，产生不对称支撑膜。 高分子选自聚氯乙烯，聚醚砜，聚醚酰亚胺和聚酰胺（甲酯）。
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42.发明授权2,2'-비스(트리플루오로메틸) 비페닐 단위를 함유한 폴리아미드 고분자로부터 제조된 분리막 및 이를 이용한 기체 혼합물의 분리 방법 失效由具有2，2'-双（三氟甲基）联苯单体的聚酰胺聚合物制备的分离膜和使用它们分离气相混合物的方法
公开(公告)号：KR100184379B1
公开(公告)日：1999-04-15
申请号：KR1019960052937
申请日：1996-11-08
Applicant: 한국과학기술연구원
IPC: B01D71/40
CPC classification number: C08G69/26 , B01D53/228 , B01D71/56
Abstract: 하기 화학식 1로 표시되는 반복 단위를 갖는 폴리아미드 고분자로부터 제조된, 폴리아미드 분리막 및 이를 이용한 기체 혼합물의 분리 방법이 기술되어 있다.
본 발명에 따른 폴리아미드 분리막은 자유 부피가 크고 분자 운동이 제한되어 있어 투과도 및 선택 투과도 등의 유체 투과 특성이 우수하다.
[화학식 1]
상기 식중, R은 디카르복실산 또는 디카르복실산 할라이드로부터 도입된 지방족 또는 방향족 유기기이다.-
公开(公告)号：KR100540157B1
公开(公告)日：2006-01-10
申请号：KR1020030068269
申请日：2003-10-01
Applicant: 한국과학기술연구원
IPC: H01L31/04
CPC classification number: H01G9/2009 , H01G9/2022 , H01G9/2031 , H01G9/2059 , Y02E10/542
Abstract: Disclosed is a solid state dye-sensitized solar cell employing a composite polymer electrolyte, which includes a photoelectrode, a counter electrode, and an electrolyte interposed between the photoelectrode and counter electrode. The electrolyte includes at least one of a middle molecular substance, a polymer mixture, and inorganic nanoparticles, and a redox derivative. The dye-sensitized solar cell reduces crystallinity of the polymer electrolyte to significantly increase ionic conductivity, and enables the polymer electrolyte to smoothly permeate into a titanium oxide layer to improve mechanical properties, thereby significantly increasing energy conversion efficiency. Accordingly, the dye-sensitized solar cell assures high energy conversion efficiency without an electrolyte leak, and thus, it can be stably and practically used for a long time.
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公开(公告)号：KR100538544B1
公开(公告)日：2005-12-23
申请号：KR1020030082721
申请日：2003-11-20
Applicant: 한국과학기술연구원
IPC: B01D71/02
Abstract: 본 발명은 즈비터 이온성 은 화합물을 주성분으로 한 올레핀/파라핀 분리용 촉진수송 분리막에 관한 것이다. 올레핀 또는 디엔계 탄화수소를 파라핀계 탄화수소와 분리하기 위한 본 발명의 촉진수송 분리막은, 올레핀이나 디엔과 가역적으로 착체 (complex)를 형성할 수 있는 즈비터 이온성 은 화합물이 단독 또는 고분자와 혼합된 용액을 다공성 지지체 위에 코팅시켜 제조한다. 이렇게 제조된 촉진 수송 분리막내에 존재하는 은 이온은 설포네이트 (SO
3 ) 기에 강하게 결합되어 있어 불순물이나 빛에 의해 거의 환원되지 않기 때문에 분리막의 안정성이 크게 향상될 수 있어 올레핀이나 디엔계 탄화수소에 대한 투과성과 선택성이 높고 장시간의 운전상황에서도 초기의 활성을 오랫동안 지속하는 특성을 나타낸다.-
公开(公告)号：KR100453680B1
公开(公告)日：2004-10-20
申请号：KR1020010069933
申请日：2001-11-10
Applicant: 한국과학기술연구원
IPC: C08J5/22
Abstract: PURPOSE: A crosslinked irreversible chemical gel film-type ion exchange membrane, its preparation method and a fuel cell containing the ion exchange membrane are provided, to reduce the effect of moisture and methanol on the hydrogen ion conductivity, to reduce the thickness and to improve the ion conductivity. CONSTITUTION: The ion exchange membrane is such that its crosslinking point is formed by the crosslinking reaction of a structural unit A selected from the groups represented by the formulas 1 and 2, and it comprises a structural unit B selected from the groups represented by the formula 3 or ArR7, wherein R1 to R5 are independent each another and are H, a phenyl group, an alkyl group of C1-C4, an alkylene group of C1-C4, an alkynyl group of C1-C4, a nitrile group or a functional group capable of inducing the condensation independently(i.e. epoxy, cyanate, ester and halogen); R6 is H or an alkyl group of C1-C4; Ar is a substituted or unsubstituted phenyl group(wherein the substituent is a phenyl group, an alkyl group of C1-C4, an alkylene group of C1-C4, or an alkynyl group of C1-C4); and R7 is -SO3H, -COOH or -P(O)(OR8)OH(wherein R8 is H or an alkyl group of C1-C4).
Abstract translation: 目的：提供一种交联的不可逆化学凝胶膜型离子交换膜及其制备方法和包含该离子交换膜的燃料电池，以降低水分和甲醇对氢离子传导性的影响，减少厚度并改善 离子电导率。 组成：离子交换膜是这样的，即其交联点通过选自式1和2所示的基团的结构单元A的交联反应形成，并且它包含选自式 3或ArR7，其中R1至R5彼此独立且为H，苯基，C1-C4的烷基，C1-C4的亚烷基，C1-C4的炔基，腈基或官能团 能够独立诱导缩合的基团（即环氧，氰酸酯，酯和卤素）; R6是H或C1-C4的烷基; Ar是取代或未取代的苯基（其中取代基是苯基，C1-C4的烷基，C1-C4的亚烷基或C1-C4的炔基）。 和R7是-SO3H，-COOH或-P（O）（OR8）OH（其中R8是H或C1-C4的烷基）。
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Patent Agency Ranking
公开(公告)号：KR100407793B1
公开(公告)日：2003-12-01
申请号：KR1020010054158
申请日：2001-09-04
Applicant: 한국과학기술연구원
IPC: H01M8/02
CPC classification number: H01M8/1051 , B01D69/141 , B01J47/12 , C08J5/2275 , C08J2323/06 , C08J2325/06 , H01M8/04197 , H01M8/1004 , H01M8/1011 , H01M8/1023 , H01M8/1039 , H01M8/1086 , Y02E60/523 , Y02P70/56
Abstract: 본 발명은 분리능이 있는 수소 이온 교환 복합막, 복합 용액, 그 제조방법 및 이를 포함하는 연료전지에 관한 것으로서, 본 발명에 따른 이온 교환 복합막은 배리어 물질인 클레이 또는 유기화된 유기 클레이가 이온 전도성 고분자 필름에 분산되어 있는 구조를 갖고 있다. 이러한 이온 교환 복합막은 메탄올을 선택적으로 차단하면서도 수소 이온의 확산에 큰 저하가 없으며, 또한 비용면에서도 유리한 장점을 가지고 있다. 따라서, 본 발명의 이온 교환 복합막은 메탄올을 연료로 하는 직접 메탄올 연료전지에 유용하게 사용될 수 있다.
Abstract translation: 离子交换组合物膜由离子导电聚合物膜中分散的天然粘土和/或有机粘土构成，作为甲醇阻挡材料。 该膜表现出低甲醇交叉，高质子传导性，因此适合用于具有低成本优势的直接甲醇燃料电池。 ＆lt;图像＆GT;
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公开(公告)号：KR1020030006786A
公开(公告)日：2003-01-23
申请号：KR1020010042699
申请日：2001-07-16
Applicant: 한국과학기술연구원
IPC: B01D71/28
CPC classification number: C10G31/11 , B01D53/228 , B01D69/142 , C07C7/144 , C07C11/02
Abstract: PURPOSE: A polymer separation membrane containing silver salt is provided to promote transfer of olefin in order to keep a performance of the membrane and increase stability thereof even though the membrane is used for a long time. CONSTITUTION: The separation membrane comprises polymer, silver salt and a phthalate compound having a chemical formula (wherein R is alkyl or phenyl group having C2-C8) to separate olefin/paraffine and promote transfer thereof. The polymer may have hetero type atoms containing pairs of non-covalent electrons in main chains. The silver salt is contained in an amount equal to 0.5-3 times of numbers of moles of monomers to form the polymer. The silver salt is selected from a group consisting of AgBF4, AgPF6, AgSO3CF3, AgClO4 and AgSbF6. The phthalate compounds are able to be included in the membrane in an amount of 0.05-10wt.% based on total weight of the polymer.
Abstract translation: 目的：提供含有银盐的聚合物分离膜以促进烯烃的转移，以便保持膜的性能并提高其稳定性，即使膜长时间使用。 构成：分离膜包含具有化学式的聚合物，银盐和邻苯二甲酸酯化合物（其中R是具有C 2 -C 8的烷基或苯基）以分离烯烃/石蜡并促进其转移。 聚合物可以具有在主链中含有非共价电子对的杂原子。 银盐的含量等于单体摩尔数的0.5-3倍，形成聚合物。 银盐选自AgBF4，AgPF6，AgSO3CF3，AgClO4和AgSbF6。 相对于聚合物的总重量，邻苯二甲酸酯化合物能够以0.05-10重量％的量包含在膜中。
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公开(公告)号：KR100359333B1
公开(公告)日：2002-10-31
申请号：KR1020000001935
申请日：2000-01-17
Applicant: 한국과학기술연구원
IPC: B01D71/64
Abstract: 본 발명은 폴리아믹산 용액을 비용매에 침지시켜 상분리법으로 분리막을 제조한 다음 이를 고온에서 이미드화 하여 폴리이미드 분리막을 제조함에 있어서, 상기 폴리아믹산 용액을 비용매에 침지 시키기 전에 가열처리하여 부분적으로 이미드화 시킴을 특징으로하는 비대칭형 폴리이미드 분리막의 제조방법에 관한 것이다.
본 발명은 상분리법으로 분리막을 제조하는 시간을 단축할 수 있어 생산성이 향상된다. 아울러 본 발명은 이미드화율 조절로 막의 구조를 비대칭구조 등으로 형성할 수 있고, 분리막의 내용매성도 향상 시킬 수 있다.-
公开(公告)号：KR1020020068648A
公开(公告)日：2002-08-28
申请号：KR1020010008793
申请日：2001-02-21
Applicant: 한국과학기술연구원
CPC classification number: B01D69/142 , B01D53/228 , B01D2257/7022
Abstract: PURPOSE: A solid polymer electrolyte facilitated transport membrane for use in the separation of alkene hydrocarbons from thermal-cracking products of naphthalene is provided, which is characterized in that non-volatile surfactants are added in solid polymer electrolyte facilitated transport membrane to improve long term operation stability. CONSTITUTION: The solid polymer electrolyte facilitated transport membrane is prepared by coating a solid polymer electrolyte layer comprising (i) transition metal salts selectively and reversibly reactable with alkenes; (ii) non-volatile polymer; and (iii) surfactants on the surface of a porous support. Transition metal ions react with non-volatile polymer ligand to form complex, and double bond of alkenes selectively and reversibly react with transition metal ions of the complex so that it is possible to separate only alkene hydrocarbons from alkene/alkane hydrocarbons.
Abstract translation: 目的：提供固体聚合物电解质，促进用于从萘的热裂解产物中分离烯烃的输送膜，其特征在于将非挥发性表面活性剂加入固体聚合物电解质促进输送膜中以改善长期操作 稳定性。 构成：通过涂覆固体聚合物电解质层制备固体聚合物电解质促进输送膜，该固体聚合物电解质层包含（i）过渡金属盐与烯烃选择性且可逆反应; （ii）不挥发性聚合物; 和（iii）多孔载体表面上的表面活性剂。 过渡金属离子与非挥发性聚合物配体反应形成复合物，烯烃的双键选择性地和可逆地与络合物的过渡金属离子反应，使得可以仅从烯烃/烷烃分离出烯烃。
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公开(公告)号：KR1020020043829A
公开(公告)日：2002-06-12
申请号：KR1020000072959
申请日：2000-12-04
Applicant: 한국과학기술연구원
IPC: C08K3/00
CPC classification number: C08G83/003 , C08F8/42 , C08G83/001 , Y10S977/773 , Y10S977/788
Abstract: PURPOSE: Provided are an inorganic-polymer composite material attached with nano particles on its surface by using dendrimer, in which inorganic nano particles are well dispersed on surface of polymer material without permanent cohesion, and a method for producing the same. CONSTITUTION: The method comprises the steps of (i) forming an anhydride reactor on a matrix of polymer material; (ii) selectively adding either of metal or inorganic salt to dendrimer, to form either of dendrimer-metal precursor solution or dendrimer-inorganic particles solution; (iii) reacting the matrix with the either solution to chemically combine with each other; and (iv) irradiating the combined product to reduce metal or inorganic particle ion. The matrix is a polymer film having anhydride functionality attached by plasma treating the polymer film in the presence of maleic anhydride.
Abstract translation: 目的：提供一种通过使用树枝状大分子在其表面上附着有纳米颗粒的无机 - 聚合物复合材料及其制备方法，其中无机纳米颗粒良好地分散在聚合物材料表面上而不具有永久内聚力。 构成：该方法包括以下步骤：（i）在聚合物材料的基体上形成酸酐反应器; （ii）选择性地向树枝状聚合物中加入金属或无机盐，以形成树枝状大分子金属前体溶液或树枝状大分子 - 无机颗粒溶液; （iii）使所述基质与所述任一溶液反应以彼此化学结合; 和（iv）照射组合产品以还原金属或无机颗粒离子。 基质是通过在马来酸酐存在下等离子体处理聚合物膜而具有酸酐官能度的聚合物膜。
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