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公开(公告)号：KR100428496B1
公开(公告)日：2004-04-28
申请号：KR1020010042398
申请日：2001-07-13
Applicant: 한국에너지기술연구원
IPC: C01G23/00
CPC classification number: Y02P20/544
Abstract: PURPOSE: A preparation method of barium titanate powder by hydrothermal synthesis is provided, which prevents corrosion of powder preparation equipment and lowers production cost by using Ba and Ti hydroxides as raw materials instead of conventional raw materials containing chlorides. CONSTITUTION: The continuous preparation method of fine and homogeneous BaTiO3 powder through hydrothermal process comprises the steps of: (i) mixing barium hydroxide, Ba(OH)2-8H2O, with titanium hydroxide, TiO(OH)2 in a concentration ratio of 0.5-2 : 1 under pressure of 10-40MPa, which is expressed by the formula TiO(OH)2 + Ba(OH)2-8H2O -->BaTiO3 +10H2O; (ii) supplying hot water to the mixture for 100-400deg.C of mixture; (iii) reacting 3-10sec. to form critical nuclei; (iv) supplying hot water to the intermediates forming critical nuclei, and dehydrating under subcritical and supercritical state to get BaTiO3; (v) separating synthesized materials and recycling.
Abstract translation: 目的：提供一种通过水热合成制备钛酸钡粉末的方法，该方法可以防止粉末制备设备的腐蚀，并且通过使用Ba和Ti氢氧化物作为原料代替传统的含氯化物原料来降低生产成本。 一种通过水热法连续制备细小均匀的BaTiO 3粉末的方法，包括以下步骤：（i）将氢氧化钡，Ba（OH）2·8H 2 O与浓度比为0.5的氢氧化钛，TiO（OH）2 （OH）2 + Ba（OH）2·8H 2 O→BaTiO 3 + 10H 2 O表示的10〜40MPa的压力下， （ii）向混合物提供热水100-400℃的混合物; （iii）反应3-10秒。 形成临界核; （iv）向形成临界核的中间体供应热水，并在亚临界和超临界状态下脱水得到BaTiO 3; （v）分离合成材料并回收。
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公开(公告)号：KR1020020053896A
公开(公告)日：2002-07-06
申请号：KR1020000081696
申请日：2000-12-26
Applicant: 한국에너지기술연구원
IPC: C08B16/00
CPC classification number: Y02P20/544
Abstract: PURPOSE: Provided are a method and a device which substantially increase a reaction rate of hydrolysis using a supercritical water and improve the yield of hydrolysis. CONSTITUTION: The method comprises the steps of (i) heating and pressurizing a raw water containing a small amount of sulfuric acid or sulfate in a heating part(4), (ii) providing the raw water to reactor(8) together with cellulose slurry provided by the slurry pump(10) to effect a hydrolysis, (ii) terminating a reaction by firstly cooling the reactants discharged from the reactor(8) with cooling water provided from cooling water tank(12), (iii) completely terminating a reaction by secondarily cooling the reactants by heat exchanger(13), (iv) passing the reaction product to filter unit(14) to filter an unreacted cellulose, while the filtrate being obtained from a product collecting tank.
Abstract translation: 目的：提供一种使用超临界水显着增加水解反应速率并提高水解产率的方法和装置。 方案：该方法包括以下步骤：（i）在加热部分（4）中加热和加压含有少量硫酸或硫酸盐的原水，（ii）将原水与纤维素浆料一起提供给反应器 由浆料泵（10）提供以进行水解，（ii）通过首先用从冷却水箱（12）提供的冷却水冷却从反应器（8）排出的反应物来终止反应，（iii）完全终止反应 通过热交换器（13）二次冷却反应物，（iv）将过滤器从产品收集罐获得，将反应产物通过过滤器单元（14）以过滤未反应的纤维素。
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公开(公告)号：KR1020130091828A
公开(公告)日：2013-08-20
申请号：KR1020120013070
申请日：2012-02-09
Applicant: 한국에너지기술연구원
CPC classification number: B01D53/62 , B01D53/025 , B01D2252/2041 , B01D2252/20442 , B01D2252/20447 , B01D2252/20484 , B01D2253/108 , B01D2253/20 , B01D2253/306 , B01D2253/308 , B01D2253/311 , B01D2257/504 , B01J20/186 , B01J20/3204 , B01J20/3248 , B01J20/3251 , B01J20/3255 , Y02A50/2342 , Y02C10/04 , Y02C10/08
Abstract: PURPOSE: A zeolite sorption agent wherein solid amine is impregnated is disclosed, along with a manufacturing method thereof, to be excellent in a sorption capacity, an ability to remove carbon dioxide, event at 50°C, a temperature combustible waste gas is ejected to the atmosphere. CONSTITUTION: A zeolite sorption agent wherein solid amine is impregnated comprises the steps of: preparing a solid amine solution, adding molded zeolite in the solid amine solution, impregnating the zeolite added solution at 30-90°C, for 2-8 hours, in a vacuum, and drying the solution in a vacuum oven at 90-110°C, for 10-30 hours.
Abstract translation: 目的：公开了其中固体胺被浸渍的沸石吸附剂及其制备方法，其具有优异的吸附能力，除去二氧化碳的能力，在50℃的情况下，将可燃性废气喷射到 气氛。 构成：其中固体胺被浸渍的沸石吸附剂包括以下步骤：制备固体胺溶液，在固体胺溶液中加入模塑沸石，在30-90℃下将沸石添加溶液浸渍2-8小时， 真空，并将该溶液在90-110℃的真空烘箱中干燥10-30小时。
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公开(公告)号：KR1020130026639A
公开(公告)日：2013-03-14
申请号：KR1020110089922
申请日：2011-09-06
Applicant: 한국에너지기술연구원
CPC classification number: B01D71/024 , C01B13/0255
Abstract: PURPOSE: A perovskite type ion conductivity tube shape oxygen separating film and a manufacturing method are provided to use serviceably to oxygen separation from the air with carbon dioxide as the oxygen permeation degree and the thermal stability are improved a lot in high pressure and temperature compare to the separation film which is not coated. CONSTITUTION: A perovskite type ion conductivity tube shape oxygen separating film has the composition of the Ba1-xSrxCo1-yFeyO3- and is coated with the La1-xSrxTi1-yFeyO3-. In a chemical formula, it is 0
Abstract translation: 目的：提供钙钛矿型离子传导性管状氧分离膜和制造方法，可有效地利用二氧化碳作为氧气渗透度从空气中分离氧气，并且在高压和高温下热稳定性提高很多 未涂布的分离膜。 构成：钙钛矿型离子传导性管状氧分离膜具有Ba1-xSrxCo1-yFeyO3的组成，并且涂覆有La1-xSrxTi1-yFeyO3-。 在化学式中，它是0 <= x <= 1，0 <= y <= 1。 钙钛矿型离子导电管形氧分离膜的制造方法包括以下步骤： 以BSCF粉末的相应8-11与粘合剂1的比例混合干燥步骤; 以8〜11倍的蒸馏水稀释聚乙二醇后，以液态混合2-3份稀释物质与1种增塑剂的重量比的步骤; 通过压缩成型混合物产生管形分离膜的步骤; 通过干燥和塑化所生产的管形分离膜产生精细分离膜的步骤; 在具有20-40％的LSTF粉末的胶体悬浮液中浸泡并涂覆管状分离膜的步骤; 以及通过干燥和塑化涂覆的管状分离膜来产生LSTF涂布的BSCF精细分离膜的步骤。
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公开(公告)号：KR101178457B1
公开(公告)日：2012-09-06
申请号：KR1020100045262
申请日：2010-05-14
Applicant: 한국에너지기술연구원
Abstract: 본 발명은 페롭스카이트형 혼합전도성 산소분리막 및 그 제조방법에 관한 것으로, 더욱 상세하게는 종래의 BSCF 조성의 분리막에 LSTF 조성의 분리막을 코팅함으로써 산소 투과 특성 및 이산화탄소에 대한 내성이 향상된 LSTF-6437이 코팅된 BSCF-5582 산소분리막 및 그 제조방법에 관한 것이다.
본 발명에 따른 LSTF-6437이 코팅된 BSCF-5582 산소분리막은 BSCF-5582 분리막의 표면을 LSTF-6437 코팅액으로 코팅함으로써 산소투과 시 이산화탄소(CO
2 )에 의한 불순물 생성 반응을 억제하여 산소 투과량의 저하를 방지할 수 있으며 코팅 표면의 비표면적 증가에 따라 산소투과량을 증가시킬 수 있는 장점이 있다.-
Patent Agency Ranking46.发明授权
公开(公告)号：KR101157141B1
公开(公告)日：2012-06-22
申请号：KR1020090131571
申请日：2009-12-28
Applicant: 한국에너지기술연구원
CPC classification number: B01D53/1475 , B01D53/1493 , B01D53/62 , B01D2251/306 , B01D2251/606 , B01D2252/2041 , B01D2252/20426 , B01D2252/20447 , B01D2252/504 , B01D2257/504 , Y02A50/2342 , Y02C10/04 , Y02C10/06
Abstract: 본 발명은 이산화탄소 흡수제에 관한 것으로, 더욱 상세하게는 알칼리 탄산염 물질에 입체장애(hindered) 시클릭 아민을 첨가함으로써 이산화탄소 흡수속도가 향상되고 재생에너지가 절감되며 염 생성 및 상분리가 발생되지 않도록 하는 입체장애 시클릭 아민이 첨가된 알칼리탄산염계 이산화탄소 흡수제 및 이를 이용한 이산화탄소 제거방법에 관한 것이다.
본 발명에 따른 알칼리염계 이산화탄소 흡수제에 의하면 낮은 재생에너지와 높은 이산화탄소 흡수속도로 인해 이산화탄소 포집비용을 절감할 수 있으며 염 생성 및 층 분리 현상이 발생하지 않아 흡수제를 보충할 필요가 없어서 공정효율을 정상상태로 유지할 수 있다는 장점이 있다.
이산화탄소 흡수제, 입체장애아민, 알칼리탄산염, 입체장애 시클릭 아민-
公开(公告)号：KR101149079B1
公开(公告)日：2012-05-24
申请号：KR1020100004464
申请日：2010-01-18
Applicant: 한국에너지기술연구원
CPC classification number: B01D53/228 , B01D61/38 , B01D69/141
Abstract: The present invention relates to an ionic liquid-polymer gel membrane with improved gas permeability, and a preparation method thereof, and more specifically, to a membrane prepared to allow an ionic liquid to be dispersed in a polymer gel, thereby improving gas permeability. Particularly, the present invention relates to an ionic liquid-polymer gel membrane wherein membrane selectivity and permeability exceed an upper bound by increasing the amount of dispersed ionic liquid, and a preparation method thereof. The preparation method of the membrane for separating a specific gas from a mixture gas according to the present invention comprises the following steps of: mixing a polymer, an ionic liquid and PC as a solvent to prepare a mixture solution; and drying the mixture solution to remove the solvent from the mixture solution. In addition, the polymer is polyvinylidene fluoride-hexafluoropropyl copolymer (PVdF-HFP), and the ionic liquid is 1-ethyl-3-methylimidazolium tetrafluoroborate ([emim][BF4]).
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公开(公告)号：KR1020120004580A
公开(公告)日：2012-01-13
申请号：KR1020100065141
申请日：2010-07-07
Applicant: 한국에너지기술연구원
CPC classification number: Y02A50/2342 , Y02C10/04 , B01J20/262 , B01D53/02 , B01D2253/202 , B01D2253/25 , B01D2257/504 , B01J20/18
Abstract: PURPOSE: A carbon dioxide absorber using meso-porous materials and a carbon dioxide eliminating method using the same are provided to increase an area, to which carbon dioxide is absorbed, based on branches of polyethyleneimine. CONSTITUTION: A carbon dioxide absorber includes meso-porous materials and polyethyleneimine. The average molecular weight of the polyethyleneimine is between 450 and 650. The polyethyleneimine is immersed in the meso-porous materials. The meso-porous materials are MCM-41 or MCM-48. The absorber absorbs carbon dioxide at a temperature between 40 and 80 degrees Celsius. The immersing rate of the polyethyleneimine is M2/(M1+M2)x100 and is in a range between 25 and 35 wt%, between 45 and 55 wt%, or between 65 and 75 wt%. The M1 is the content of the meso-porous materials. The M2 is the content of polyethyleneimine.
Abstract translation: 目的：提供使用中孔多孔材料的二氧化碳吸收器和使用其的二氧化碳消除方法，以增加基于聚乙烯亚胺的分支吸收二氧化碳的面积。 构成：二氧化碳吸收剂包括中孔多孔材料和聚乙烯亚胺。 聚乙烯亚胺的平均分子量在450和650之间。将聚乙烯亚胺浸入中孔多孔材料中。 中孔多孔材料是MCM-41或MCM-48。 吸收剂在40摄氏度和80摄氏度之间的温度下吸收二氧化碳。 聚乙烯亚胺的浸渍速率为M2 /（M1 + M2）×100，为25〜35重量％，45〜55重量％，65〜75重量％。 M1是介孔材料的含量。 M2是聚乙烯亚胺的含量。
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49.发明公开알카리염이 포함된 이미다졸륨계 이온성액체의 이산화탄소 흡수제 및 그 제조방법과 그것을 이용한 이산화탄소 흡수방법 无效包含碱性盐的咪唑鎓离子液体的二氧化碳吸收及其生产方法和使用二氧化碳的二氧化碳吸收方法
公开(公告)号：KR1020110084717A
公开(公告)日：2011-07-26
申请号：KR1020100004420
申请日：2010-01-18
Applicant: 한국에너지기술연구원
CPC classification number: Y02A50/2342 , Y02C10/04 , Y02C10/06 , B01D53/1493 , B01D53/1475 , B01D2252/20473 , B01D2252/30 , B01D2252/60
Abstract: PURPOSE: The carbon dioxide absorbing agent of imidasolium-based ionic liquid, a method for fabricating the same, and a method for absorbing carbon dioxide using the same are provided to reduce energy required for regenerating the absorbing agent by substituting imidazolium-based ionic liquid absorbing agent with alkaline salt to obtain the carbon dioxide absorbing agent. CONSTITUTION: Alkaline salt is added in ionic liquid. The ionic liquid is 1-butyl-3-methylimidazolium iodide using imidazolium as cation. The alkaline salt is selected from KHCO_3 or KOH. The alkaline salt added ionic liquid is stirred to obtain a carbon dioxide absorbing agent. A carbon dioxide absorbing process is implemented in a carbon dioxide absorbing performance measuring unit(10) at temperature between 35 and 45 degrees Celsius and the pressure more than or equal to 10bar.
Abstract translation: 目的：提供了基于亚胺体系的离子液体的二氧化碳吸收剂，其制造方法和使用其的二氧化碳吸收方法，以通过用咪唑鎓离子液体吸收代替来吸收吸收剂再生所需的能量 用碱性盐代替二氧化碳吸收剂。 构成：在离子液体中加入碱性盐。 离子液体是使用咪唑鎓作为阳离子的1-丁基-3-甲基咪唑鎓碘化物。 碱性盐选自KHCO_3或KOH。 搅拌碱加盐的离子液体，得到二氧化碳吸收剂。 二氧化碳吸收过程在二氧化碳吸收性能测量单元（10）中在35至45摄氏度的温度和大于或等于10bar的压力下实施。
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公开(公告)号：KR1020090062832A
公开(公告)日：2009-06-17
申请号：KR1020070130276
申请日：2007-12-13
Applicant: 한국에너지기술연구원
Abstract: Provided are a method of manufacturing a Perovskite-type ion conductive oxygen membrane having a hexahedral structure or rhombohedral structure instead of a simple cubic structure to obtain a high oxygen permeability, and a process of separating oxygen using the oxygen membrane. A method of manufacturing a Perovskite-type ion conductive oxygen membrane comprises: a first step of adding citric acid into a metal nitrate solution and dissolving distilled water into the metal nitrate solution to prepare a mixed solution; a second step of evaporating water of the mixed solution to dry the mixed solution; a third step of milling and calcining the dried mixture to prepare a synthesized powder; and a fourth step of compression molding the synthesized powder to manufacture a membrane. The membrane has a hexahedral structure or rhombohedral structure.
Abstract translation: 提供一种制造具有六面体结构或菱面体结构的钙钛矿型离子导电氧膜的方法，而不是简单的立方结构以获得高氧渗透性，以及使用氧膜分离氧的方法。 一种钙钛矿型离子导电氧膜的制造方法，其特征在于，在金属硝酸盐溶液中添加柠檬酸，将蒸馏水溶解在硝酸金属溶液中，制备混合溶液的第一工序; 蒸发混合溶液的水以干燥混合溶液的第二步骤; 研磨和煅烧干燥混合物以制备合成粉末的第三步骤; 以及压缩成型合成粉末以制造膜的第四步骤。 膜具有六面体结构或菱面体结构。
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