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    PROCESS FOR THE GAS-PHASE POLYMERIZATION OF OLEFINS
    41.
    发明申请
    PROCESS FOR THE GAS-PHASE POLYMERIZATION OF OLEFINS 审中-公开
    油相的气相聚合方法

    公开(公告)号：WO2010026091A1

    公开(公告)日：2010-03-11

    申请号：PCT/EP2009/060997

    申请日：2009-08-26

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MAZZUCCO, Antonio ,  SOFFRITTI, Silvia ,  CAPUTO, Tiziana ,  COLLINA, Gianni ,  RINALDI, Riccardo ,  PICA, Roberta

    Inventor： MAZZUCCO, Antonio ,  SOFFRITTI, Silvia ,  CAPUTO, Tiziana ,  COLLINA, Gianni ,  RINALDI, Riccardo ,  PICA, Roberta

    IPC: C08F10/00 ,  C08F4/64

    CPC classification number: C08F210/16 ,  C08F110/02 ,  C08F4/6543 ,  C08F2/34 ,  C08F2/001 ,  C08F2500/24

    Abstract: A process for the polymerisation of olefins in the presence of a solid catalyst component and a catalyst activator, the process being performed in a gas-phase reactor having interconnected polymerization zones, where the growing polymer particles flow upward through a first polymerization zone (riser) under fast fluidization conditions, leave said riser and enter a second polymerization zone (downcomer) through which they flow downward under the action of gravity, leave said downcomer and are reintroduced into the riser, thus establishing a polymer circulation between said riser and said downcomer, the process being characterized in that said solid catalyst component has an average size P50 ranging from 20 μm to 65 μm and the gas flows upward in said first polymerization zone at a velocity ranging from 0.8 to 2.0 m/s.

    Abstract translation: 一种在固体催化剂组分和催化剂活化剂存在下使烯烃聚合的方法，该方法在具有互连聚合区的气相反应器中进行，其中生长的聚合物颗粒向上流过第一聚合区（提升管） 在快速流化条件下，离开所述提升管并进入第二聚合区（降液管），通过它们在重力作用下向下流动，离开所述降液管并重新引入提升管，从而在所述提升管和所述降液管之间建立聚合物循环， 该方法的特征在于所述固体催化剂组分的平均尺寸P50为20μm至65μm，气体以0.8-2.0m / s的速度在所述第一聚合区域中向上流动。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    42.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号：WO2009083522A1

    公开(公告)日：2009-07-09

    申请号：PCT/EP2008/068132

    申请日：2008-12-22

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  COLLINA, Gianni ,  FUSCO, Ofelia

    Inventor： COLLINA, Gianni ,  FUSCO, Ofelia

    IPC: C08F4/649 ,  C08F4/651 ,  C08F110/06

    CPC classification number: C08F110/06 ,  B01J27/135 ,  B01J27/138 ,  B01J31/0201 ,  B01J31/0272 ,  B01J31/143 ,  B01J31/26 ,  B01J31/38 ,  C08F4/651 ,  C08F4/6492 ,  C08F2500/12 ,  C08F2500/18

    Abstract: Prepolymerized catalyst component for the polymerization of olefins CH 2 =CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, having average particle size equal to or lower than 30 μm comprising a solid catalyst component comprising magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other one being selected from esters of aromatic mono or dicarboxylic acids, said solid catalyst component being prepolymerized with an olefin, having from 2 to 10 carbon atoms, to such an extent that the amount of the olefin prepolymer is equal to or lower than 5Og per g of solid catalyst component.

    Abstract translation: 用于烯烃CH 2 = CHR聚合的预聚合催化剂组分，其中R是氢或具有1-12个碳原子的烃基，平均粒度等于或小于30μm，包括含有卤化镁的固体催化剂组分，钛化合物 具有至少一个Ti-卤键和至少两个电子给体化合物，其中一个选自1,3-二醚，另一个选自芳族单或二羧酸的酯，所述固体催化剂组分与烯烃预聚合 具有2至10个碳原子的烯烃预聚物的量等于或低于每克固体催化剂组分的50g的程度。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    44.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号：WO2006094897A1

    公开(公告)日：2006-09-14

    申请号：PCT/EP2006/060128

    申请日：2006-02-21

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  BRITA, Diego ,  COLLINA, Gianni

    Inventor： BRITA, Diego ,  COLLINA, Gianni

    IPC: C08F4/654 ,  C08F4/651 ,  C08F10/00

    CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/651 ,  C08F2500/07 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/18

    Abstract: The present invention relates to catalysts component for the polymerization of ethylene and its mixtures with olefins CH 2 =CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising Ti, Mg, halogen, and 1,2- dimethoxyethane as internal electron donor compound. The catalyst of the invention is suitably used in (co)polymerization processes of ethylene to prepare (co)polymers having narrow Molecular Weight Distribution (MWD) and high bulk density.

    Abstract translation: 本发明涉及用于聚合乙烯及其与烯烃CH 2 = CHR的混合物的催化剂组分，其中R是具有1-12个碳原子的烷基，环烷基或芳基，包括Ti，Mg ，卤素和1,2-二甲氧基乙烷作为内电子给体化合物。 本发明的催化剂适用于乙烯的（共）聚合方法，以制备具有窄分子量分布（MWD）和高堆积密度的（共）聚合物。

    PROCESS FOR THE PREPARATION OF A SPHERICAL SUPPORT COMPRISING MgC12 AND ALCOHOL
    45.
    发明申请
    PROCESS FOR THE PREPARATION OF A SPHERICAL SUPPORT COMPRISING MgC12 AND ALCOHOL 审中-公开
    制备包含MgC12和醇的球形支持的方法

    公开(公告)号：WO2006063973A1

    公开(公告)日：2006-06-22

    申请号：PCT/EP2005/056664

    申请日：2005-12-12

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  ALDROVANDI, Enrico ,  EVANGELISTI, Daniele ,  ALESSANDRINI, Gino ,  COLLINA, Gianni

    Inventor： ALDROVANDI, Enrico ,  EVANGELISTI, Daniele ,  ALESSANDRINI, Gino ,  COLLINA, Gianni

    IPC: C08F10/00 ,  C08F4/64

    CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F4/022 ,  C08F4/6543 ,  C08F2500/15

    Abstract: The present invention relates to a process for preparing spherical support particles used in the preparation of catalytic components for the polymerization of olefins. The process comprises, (a) forming a mixture of an MgCl2-alcohol adduct in molten form and a liquid which is immiscible with the said adduct in a ratio such that the molten adduct forms the disperse phase, (b) suitably treating the mixture in order to obtain an emulsion, and (c) rapidly cooling the emulsion to solidify the disperse phase and collecting the solid adduct particles, said process being characterized by the fact that at least one of the steps (a) to (c) is carried out in the presence of an applied magnetic or electromagnetic field.

    Abstract translation: 本发明涉及用于制备用于烯烃聚合的催化组分的球形载体颗粒的方法。 该方法包括（a）形成熔融形式的MgCl 2 - 醇加合物和与所述加合物不混溶的液体的混合物，使得熔融加合物形成分散相，（b）适当地处理混合物中的混合物 为了获得乳液，和（c）快速冷却乳液以固化分散相并收集固体加合物颗粒，所述方法的特征在于进行至少一个步骤（a）至（c） 在存在施加的磁场或电磁场的情况下。

    ELASTOMERIC POLYOLEFIN COMPOSITIONS
    46.
    发明申请
    ELASTOMERIC POLYOLEFIN COMPOSITIONS 审中-公开
    弹性聚烯烃组合物

    公开(公告)号：WO2006037705A1

    公开(公告)日：2006-04-13

    申请号：PCT/EP2005/054370

    申请日：2005-09-05

    Applicant: Basell Poliolefine Italia s.r.l. ,  MASSARI, Paola ,  NEUMANN, Andreas ,  COLLINA, Gianni ,  FUSCO, Ofelia

    Inventor： MASSARI, Paola ,  NEUMANN, Andreas ,  COLLINA, Gianni ,  FUSCO, Ofelia

    IPC: C08L23/10

    CPC classification number: C08F210/06 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/16 ,  C08F4/651 ,  C08F2/001 ,  C08L2666/06 ,  C08F2500/15 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/04 ,  C08F210/08 ,  C08F2500/21 ,  C08F210/14

    Abstract: An olefin polymer composition comprising (by weight, unless otherwise specified): A) 60-85% of a crystalline propylene homopolymer or a crystalline copolymer of propylene containing 3% or less of ethylene or C 4 -C 10 α-olefin(s) or of combinations thereof, said homopolymer or copolymer having a Polydispersity Index (P.I.) value of from 4.5-6 and a content of isotactic pentads (mmmm), measured by 13 C NMR on the fraction insoluble in xylene at 25 °C, higher than 96%; B) 15-40% of a partially amorphous copolymer of ethylene containing from 35% to 70% of propylene or C 4 -C 10 α-olefin(s) or of combinations thereof, and optionally minor proportions of a diene. The said olefin polymer composition exhibits a value of elongation at break ranging from 150 to 600% according to ISO method 527.

    Abstract translation: 包含（按重量计，除非另有说明）的烯烃聚合物组合物：A）60-85％的结晶丙烯均聚物或含有3％或更少乙烯或C 4 -C 3的丙烯的结晶共聚物 所述均聚物或共聚物的多分散指数（PI）值为4.5-6，全同立构五单元组（mmmm）的含量由 25℃，高于96％的不溶于二甲苯的级分的13 C NMR; B）15-40％的含有35％至70％丙烯或C 4 -C 10α-烯烃的部分无定形乙烯共聚物或 它们的组合，和任选的少量二烯。 所述烯烃聚合物组合物根据ISO方法527显示出150至600％的断裂伸长率值。

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