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1.发明申请
公开(公告)号：WO2012041810A1
公开(公告)日：2012-04-05
申请号：PCT/EP2011/066679
申请日：2011-09-26
Applicant: BASELL POLYOLEFINE GMBH , BAITA, Pietro , FERRARI, Paolo , MINGOZZI, Ines , PEDRIALI, Lorella , DI DIEGO, Maria , PICA, Roberta
Inventor： BAITA, Pietro , FERRARI, Paolo , MINGOZZI, Ines , PEDRIALI, Lorella , DI DIEGO, Maria , PICA, Roberta
CPC classification number: C08F4/16 , C08F10/00 , C08F10/02 , C08F210/16 , C08F2410/02 , C08F210/08 , C08F2500/08 , C08F2500/12 , C08F2500/26 , C08F4/6494 , C08F2/005 , C08F210/14
Abstract: A method for feeding an antistatic compound to a polymerization reactor, the method comprising the steps of: a) dispersing, under mixing conditions, a catalyst powder and an antistatic compound in a liquid medium, so as to form a suspension of the catalyst powder and of the antistatic compound in the liquid medium; b) transferring the obtained suspension to a polymerization reactor.
Abstract translation: 一种将抗静电化合物进料到聚合反应器中的方法，所述方法包括以下步骤：a）在液体介质中将催化剂粉末和抗静电化合物在混合条件下分散，以形成催化剂粉末和 的抗静电剂在液体介质中; b）将获得的悬浮液转移到聚合反应器中。
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公开(公告)号：WO2012041813A1
公开(公告)日：2012-04-05
申请号：PCT/EP2011/066682
申请日：2011-09-26
Applicant: BASELL POLYOLEFINE GMBH , BAITA, Pietro , BRITA, Diego , FERRARI, Paolo , MAVRIDIS, Harilaos , MEI, Gabriele , PICA, Roberta , WIESECKE, Jens
Inventor： BAITA, Pietro , BRITA, Diego , FERRARI, Paolo , MAVRIDIS, Harilaos , MEI, Gabriele , PICA, Roberta , WIESECKE, Jens
CPC classification number: C08F10/02 , C08F10/00 , C08F210/16 , C08F210/08 , C08F2500/08 , C08F2500/12 , C08F2500/26 , C08F4/6494 , C08F2/005 , C08F210/14
Abstract: Extruded articles, particularly films, comprising an ethylene polymer obtained by a polymerization process carried out in the presence the products obtained by contacting the following components: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and optionally one or more internal electron donor compounds, (b) an aluminum hydrocarbyl compound, (c) optionally an external electron donor compound, and (d) a polyalcohol partially esterified with carboxylic acids with alkyl groups having at least 10 carbon atoms.
Abstract translation: 挤出制品，特别是包含通过聚合方法获得的乙烯聚合物的薄膜，所述聚合方法在存在下通过接触下列组分获得的产物进行：（a）固体催化剂组分，其包含卤化镁，至少具有Ti- 卤素键和任选的一种或多种内部电子给体化合物，（b）铝烃基化合物，（c）任选的外部电子给体化合物，和（d）与具有至少10个碳原子的烷基的羧酸部分酯化的多元醇 。
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公开(公告)号：WO2010026091A1
公开(公告)日：2010-03-11
申请号：PCT/EP2009/060997
申请日：2009-08-26
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , MAZZUCCO, Antonio , SOFFRITTI, Silvia , CAPUTO, Tiziana , COLLINA, Gianni , RINALDI, Riccardo , PICA, Roberta
Inventor： MAZZUCCO, Antonio , SOFFRITTI, Silvia , CAPUTO, Tiziana , COLLINA, Gianni , RINALDI, Riccardo , PICA, Roberta
CPC classification number: C08F210/16 , C08F110/02 , C08F4/6543 , C08F2/34 , C08F2/001 , C08F2500/24
Abstract: A process for the polymerisation of olefins in the presence of a solid catalyst component and a catalyst activator, the process being performed in a gas-phase reactor having interconnected polymerization zones, where the growing polymer particles flow upward through a first polymerization zone (riser) under fast fluidization conditions, leave said riser and enter a second polymerization zone (downcomer) through which they flow downward under the action of gravity, leave said downcomer and are reintroduced into the riser, thus establishing a polymer circulation between said riser and said downcomer, the process being characterized in that said solid catalyst component has an average size P50 ranging from 20 μm to 65 μm and the gas flows upward in said first polymerization zone at a velocity ranging from 0.8 to 2.0 m/s.
Abstract translation: 一种在固体催化剂组分和催化剂活化剂存在下使烯烃聚合的方法，该方法在具有互连聚合区的气相反应器中进行，其中生长的聚合物颗粒向上流过第一聚合区（提升管） 在快速流化条件下，离开所述提升管并进入第二聚合区（降液管），通过它们在重力作用下向下流动，离开所述降液管并重新引入提升管，从而在所述提升管和所述降液管之间建立聚合物循环， 该方法的特征在于所述固体催化剂组分的平均尺寸P50为20μm至65μm，气体以0.8-2.0m / s的速度在所述第一聚合区域中向上流动。
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4.发明申请
公开(公告)号：WO2012041811A1
公开(公告)日：2012-04-05
申请号：PCT/EP2011/066680
申请日：2011-09-26
Applicant: BASELL POLYOLEFINE GMBH , BAITA, Pietro , FERRARI, Paolo , MINGOZZI, Ines , PEDRIALI, Lorella , DI DIEGO, Maria , PICA, Roberta
Inventor： BAITA, Pietro , FERRARI, Paolo , MINGOZZI, Ines , PEDRIALI, Lorella , DI DIEGO, Maria , PICA, Roberta
CPC classification number: C08F4/16 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2410/02 , C08F2/005 , C08F2500/07 , C08F2500/12 , C08F210/08 , C08F4/6494 , C08F4/6495
Abstract: A method for feeding an antistatic compound to a polymerization reactor comprising the steps of: a) dispersing, under mixing conditions, a catalyst powder and an antistatic compound in an oil, so as to form a suspension of catalyst powder and antistatic compound in said oil; b) successively adding, under mixing conditions, a molten thickening agent to said suspension from step a), while maintaining said suspension at a temperature such that said thickening agent solidifies on contact with said suspension; c) transferring the product obtained from b) to a polymerization reactor.
Abstract translation: 一种将抗静电化合物进料到聚合反应器中的方法，包括以下步骤：a）在混合条件下在油中分散催化剂粉末和抗静电化合物，以便在所述油中形成催化剂粉末和抗静电化合物的悬浮液 ; b）在混合条件下，将熔融增稠剂连续地加入到步骤a）的所述悬浮液中，同时将所述悬浮液保持在使所述增稠剂与所述悬浮液接触时固化的温度; c）将从b）获得的产物转移到聚合反应器中。
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