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    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS AND CATALYSTS THEREFROM OBTAINED
    44.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS AND CATALYSTS THEREFROM OBTAINED 审中-公开
    用于获得烯烃和催化剂聚合的催化剂组分

    公开(公告)号：WO2008074674A1

    公开(公告)日：2008-06-26

    申请号：PCT/EP2007/063566

    申请日：2007-12-10

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MORINI, Giampiero ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  PATER, Joachim T.M. ,  VITALE, Gianni

    Inventor： MORINI, Giampiero ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  PATER, Joachim T.M. ,  VITALE, Gianni

    IPC: C08F110/02 ,  C08F4/655 ,  C08F4/654

    CPC classification number: C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F4/6555 ,  C08F4/6543 ,  C08F2500/12 ,  C08F2500/18

    Abstract: A catalyst component comprising Ti, Mg, Cl, and optionally OR 1 groups in which R 1 is a C1- C20 hydrocarbon group up to an amount such as to give a molar ORI/Ti ratio lower than 0.5, characterized by the following properties: surface area, determined by BET method, of lower than 80 m 2 /g, - a total porosity (P T ), measured by the mercury method, in the range of 0.60-1.50 cm 3 /g - - a difference (P T -P F ) of higher than 0.1 in which P T is the total porosity and P F is the porosity due to pore with radius equal to or less than 1 μm; - an amount of Ti in the catalyst component of less that 10 %wt based on the total weight of catalyst component. The said catalyst components show high morphological stability under the low molecular weight ethylene polymerization conditions while at the same time maintaining characteristics of high activity.

    Abstract translation: 包含Ti，Mg，Cl和任选OR 1的基团的催化剂组分，其中R 1是C 1 -C 20烃基，直到一定量，以产生摩尔 ORI / Ti比小于0.5，其特征在于以下性能：通过BET法测定的表面积低于80m 2 / g， - 总孔隙率（P < SUB>）通过汞法测量的范围为0.60-1.50cm 3 / g-的差异（P SUB>）高于0.1，其中P T是总孔隙率，P> F是由于半径等于或小于1μm的孔的孔隙率; - 催化剂组分中的Ti的量相对于催化剂组分的总重量小于10重量％。 所述催化剂组分在低分子量乙烯聚合条件下显示出高的形态稳定性，同时保持高活性的特性。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF BUTENE-1
    50.
    发明公开
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF BUTENE-1 有权
    KATALYSATONOMPONENTEN ZUR POLYMERISATION VON BUTEN-1

    公开(公告)号：EP2859026A1

    公开(公告)日：2015-04-15

    申请号：EP13725706.9

    申请日：2013-05-30

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： MIGNOGNA, Alessandro ,  ESPOSITO, Simona ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim T. M. ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni

    IPC: C08F110/08 ,  C08F4/651

    CPC classification number: C08F4/52 ,  C08F4/10 ,  C08F4/16 ,  C08F110/08 ,  C08F4/651 ,  C08F2500/15 ,  C08F2500/17 ,  C08F110/06 ,  C08F2500/12

    Abstract: Process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I), In which the R groups equal to or different from each other, are C
    1 -C
    15 hydrocarbon groups, the R
    1 -R
    2 groups, equal to or different from each other, are hydrogen, halogen or C
    1 -C
    15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0; (b) An aluminium alkyl cocatalyst and (c) an external electron donor

    Abstract translation: 在催化剂存在下进行的丁烯-1的聚合方法，包括（a）包含Mg，Ti的固体催化剂组分和下式（I）的电子给体化合物：其中R基团等于或不同于 彼此是C 1 -C 15烃基，R 1 -R 2基彼此相同或不同，是氢，卤素或C 1 -C 15烃基，任选地含有选自卤素，P ，S，N和Si，n和m是0至3的整数，条件是它们中的至少一个不同于0; （b）烷基铝助催化剂和（c）外电子给体

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