公开(公告)号：WO2012052389A1

公开(公告)日：2012-04-26

申请号：PCT/EP2011/068084

申请日：2011-10-17

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  PATER, Joachim T., M. ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  MORINI, Giampiero ,  VITALE, Gianni

Inventor： PATER, Joachim T., M. ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  MORINI, Giampiero ,  VITALE, Gianni

IPC: C08F10/06 ,  C08J5/18 ,  C08F4/654 ,  C08F4/651

CPC classification number: C08F10/06 ,  C08F4/651 ,  C08F4/6543

Abstract: A process for the preparation of high purity propylene polymers carried out in the presence of a catalyst comprising the product obtained by reacting:- an organo-aluminium compound, with - a solid catalyst component comprising Mg, Ti and electron donor compound selected from specific diolesters, said process being carried out employing an organo-aluminum/propylene ratio equal to or lower than 1.75 mmole/kg.

Abstract translation: 一种用于制备高纯度丙烯聚合物的方法，该催化剂在催化剂存在下进行，所述催化剂包括通过使有机铝化合物与包含Mg，Ti和选自特定二极体的电子给体化合物的固体催化剂组分反应而获得的产物 所述方法使用等于或低于1.75mmol / kg的有机铝/丙烯比进行。

公开(公告)号：WO2012052386A1

公开(公告)日：2012-04-26

申请号：PCT/EP2011/068077

申请日：2011-10-17

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  PATER, Joachim, T., M. ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  Morini, Giampiero ,  VITALE, Gianni

Inventor： PATER, Joachim, T., M. ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  Morini, Giampiero ,  VITALE, Gianni

IPC: C08F10/06 ,  C08F4/651 ,  C08F4/654

CPC classification number: C08F10/06 ,  C08F110/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2500/12 ,  C08F2/34

Abstract: A process for the (co)polymerization of propylene carried out at a temperature ranging from 77 to 95°C in the presence of a catalyst comprising the product obtained by reacting: -an organo-aluminium compound, with -a solid catalyst component comprising Mg, Ti and electron donor compound selected from specific diolesters.

Abstract translation: 在丙烯存在下，在77至95℃的温度下进行丙烯（共）聚合的方法，所述催化剂包含通过以下方法获得的产物： - 有机铝化合物与包含Mg的固体催化剂组分 ，Ti和选自特定二极体的电子给体化合物。

公开(公告)号：WO2012017038A1

公开(公告)日：2012-02-09

申请号：PCT/EP2011/063447

申请日：2011-08-04

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MIGNOGNA, Alessandro ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Jochem T. M.

Inventor： MIGNOGNA, Alessandro ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Jochem T. M.

IPC: C08F10/06 ,  C08F4/651 ,  C08F4/646

CPC classification number: C08F10/06 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6545

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of Formula (I) in which R, R 1 and R 4 groups, equal to or different from each other, are C 1 -C 15 hydrocarbon groups and the R groups can be linked to form a cycle, R 2 -R 3 groups, equal to or different from each other, are selected from hydrogen and C 1 -C 15 hydrocarbon groups, the R 1 -R 4 groups can optionally contain an heteroatom selected from halogen, P, S, N,O and Si, n is an integer from 0 to 5 and said electron donor and Ti atoms being present in an amount such that their molar ratio is equal to, or lower than, 0.65.

Abstract translation: 包含Mg，Ti和其中R，R 1和R 4基团彼此相同或不同的R，R 1和R 4基团的式（I）的电子给体的烯烃聚合用催化剂组分是C1-C15烃基，R基团可以连接 为了形成一个循环，相同或不同的R2-R3基团选自氢和C1-C15烃基，R1-R4基团可任选地含有选自卤素，P，S，N，O的杂原子 和Si，n为0至5的整数，并且所述电子给体和Ti原子的存在量使得它们的摩尔比等于或低于0.65。

公开(公告)号：WO2006117285A1

公开(公告)日：2006-11-09

申请号：PCT/EP2006/061545

申请日：2006-04-12

Applicant: BASELL POLYOLEFINE GMBH ,  RESCONI, Luigi ,  GUIDOTTI, Simona ,  SANTORIELLO, Iolanda

Inventor： RESCONI, Luigi ,  GUIDOTTI, Simona ,  SANTORIELLO, Iolanda

IPC: C08F10/00 ,  C08F4/6592 ,  C07F17/00 ,  C07F7/08

CPC classification number: C07F7/0818 ,  C07F17/00 ,  C08F4/65912 ,  C08F10/00 ,  C08F10/08 ,  C08F110/06 ,  C08F110/08 ,  C08F210/08 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2/02 ,  C08F2500/17 ,  C08F210/16

Abstract: A process for preparing 1-butene polymers, comprising polymerizing 1-butene or copolymerizing 1-butene with ethylene, propylene or an alpha-olefin of formula CHT 2 =CHT wherein T is a C 3 -C 10 alkyl group, in the presence of a catalyst system obtainable by contacting: A) a metallocene compound belonging to formula (I): wherein M is zirconium titanium or hafnium; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a a hydrocarbon radical, optionally containing heteroatoms; R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 are hydrogen atoms, or C 1 -C 4O hydrocarbon radicals optionally containing heteroatoms; R 1 , R 2 and R 3 , are linear or branched, C 1 -C 2o -alkyl radicals, optionally containing heteroatoms; B) a Jumoxane or a compound capable of forming an alkyl metallocene cation; and optionally C) organo aluminum compound.

Abstract translation: 一种制备1-丁烯聚合物的方法，包括将1-丁烯或1-丁烯与乙烯，丙烯或式CHT 2 CH = CHT的α-烯烃聚合，其中T是C 3 在可以通过下述方法获得的催化剂体系存在下进行：A）属于式（I）的茂金属化合物：其中M是锆钛或铪; X，彼此相同或不同，是氢原子，卤素原子，烃基，任选地含有杂原子; R 4，R 5，R 6，R 7，R 8， R 9，R 10，R 11，R 12和R 13是 氢原子或任选含有杂原子的C 1 -C 40烃基; R 1，R 2和R 3是直链或支链的C 1 -C 2 O 任选地含有杂原子的烷基; B）可以形成烷基茂金属阳离子的Jumoxane或化合物; 和任选的C）有机铝化合物。

公开(公告)号：WO2005105865A1

公开(公告)日：2005-11-10

申请号：PCT/EP2005/004506

申请日：2005-04-25

Applicant: BASELL POLYOLEFINE GMBH ,  RESCONI, Luigi ,  GUIDOTTI, Simona

Inventor： RESCONI, Luigi ,  GUIDOTTI, Simona

IPC: C08F10/08

CPC classification number: C08F10/08 ,  C08F4/65912 ,  C08F110/08 ,  C08F210/02 ,  C08F210/08 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/15 ,  C08F210/06 ,  C08F210/16

Abstract: A process for obtaining atactic 1-butene polymer optionally containing at least one comonomer selected from ethylene, propylene or an alpha-olefin of formula CH2=CHR, wherein R is a linear or branched C3-C 20 alkyl group, comprising the step of polymerizing 1-butene and optionally ethylene, propylene or said alpha-olefin, in the presence of a catalyst system obtainable by contacting: a) at least one metallocene compound of formula (I) in its meso or meso-like form wherein M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group; L is a divalent C 1 -C 40 hydrocarbon radical optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; R' and R 2 , are C 1 -C 40 hydrocarbon radicals; T, equal to or different from each other, is a moiety of formula (IIa) or (Ilb) wherein R 3 is a C I -C 40 hydrocarbon radical; R 4 and R 6 , are hydrogen atoms or C 1 -C 40 hydrocarbon radicals; R 5 is a C I -C 40 hydrocarbon radical; R 7 and R 8 , equal to or different from each other, are hydrogen atoms or C 1 -C 40 hydrocarbon radicals; and b) an alumoxane or a compound capable of forming an alkyl metallocene cation.

Abstract translation: 获得任选含有选自乙烯，丙烯或式CH 2 = CHR的α-烯烃的至少一种共聚单体的无规性1-丁烯聚合物的方法，其中R是直链或支链C 3 -C 20烷基，其包括聚合1 丁烯和任选的乙烯，丙烯或所述α-烯烃在催化剂体系的存在下，可通过以下步骤获得： - ）至少一种其中间或内消旋形式的式（I）金属茂化合物，其中M是 过渡金属; p是0至3的整数; X相同或不同，是氢原子，卤素原子或烃基; L是任选含有属于元素周期表第13-17族的杂原子的二价C 1 -C 40烃基; R'和R 2是C1-C40烃基; T为相同或不同的式（IIa）或（IIb）的部分，其中R 3为C 1 -C 40烃基; R 4和R 6是氢原子或C 1 -C 40烃基; R 5是C 1 -C 40烃基; R 7和R 8彼此相同或不同，是氢原子或C 1 -C 40烃基; 和b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

公开(公告)号：WO2004005360A3

公开(公告)日：2005-11-10

申请号：PCT/EP0307485

申请日：2003-07-09

Applicant: BASELL POLYOLEFINE GMBH ,  RESCONI LUIGI ,  FOCANTE FRANCESCA ,  CAMURATI ISABELLA ,  GUIDOTTI SIMONA

Inventor： RESCONI LUIGI ,  FOCANTE FRANCESCA ,  CAMURATI ISABELLA ,  GUIDOTTI SIMONA

IPC: C07F5/02 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/02 ,  C08F4/645

CPC classification number: C07F5/027 ,  C08F4/65912 ,  C08F4/65925 ,  C08F10/00 ,  C08F110/02 ,  C08F4/65908

Abstract: An organometallic compound obtainable by contacting: a compound having the following formula (I), wherein: R is a hydrocarbon radical; R , R and R , are hydrogen atoms, halogen atoms, or hydrocarbon radicals; with a Lewis acid of formula (II) MtR 3 (II) wherein Mt is a metal belonging to Group 13 of the Periodic Table of the Elements; R are selected from the group consisting of halogen atoms, halogenated C6-C20 aryl and halogenated C7-C20 alkylaryl groups.

Abstract translation: 通过使具有下式（I）的化合物接触而获得的有机金属化合物，其中：R a是烃基; R b，R o和R d分别是氢原子，卤素原子或烃基; 与式（II）的路易斯酸MtR 1（II）其中Mt是属于元素周期表第13族的金属; R 1选自卤素原子，卤代C 6 -C 20芳基和卤代C 7 -C 20烷基芳基。

公开(公告)号：WO2012175425A1

公开(公告)日：2012-12-27

申请号：PCT/EP2012/061466

申请日：2012-06-15

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MIGNOGNA, Alessandro ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim, T. M.

Inventor： MIGNOGNA, Alessandro ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim, T. M.

IPC: C08F10/00 ,  C08F4/651

CPC classification number: C08F4/50 ,  C08F4/16 ,  C08F10/00 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/12 ,  C08F4/6541

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R 1 to R 4 groups, equal to or different from each other, are hydrogen, C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and S i ,, R 6 group is selected from C 1 -C 15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si, and R 5 is selected from phenyl groups mono or poly substituted with halogens, said groups R 1 -R 4 being also optionally linked to form a saturated or unsaturated mono or poly cycle.

Abstract translation: 包含Mg，Ti和下式（I）的电子给体化合物的烯烃聚合的催化剂组分，其中相同或不同的R 1至R 4基团为氢，任选地含有 选自卤素，P，S，N和Si，R 6基团的杂原子选自任选含有选自卤素，P，S，N和Si的杂原子的C 1 -C 15烃基，R 5选自苯基单或多 被卤素取代，所述基团R 1 -R 4也任选地连接形成饱和或不饱和的单或多环。

公开(公告)号：WO2012130614A1

公开(公告)日：2012-10-04

申请号：PCT/EP2012/054447

申请日：2012-03-14

Applicant: Basell Poliolefine Italia S.r.l. ,  LIGUORI, Dario ,  VITALE, Gianni ,  PATER, Joachim T. M. ,  MORINI, Giampiero ,  GUIDOTTI, Simona ,  DALL'OCCO, Tiziano

Inventor： LIGUORI, Dario ,  VITALE, Gianni ,  PATER, Joachim T. M. ,  MORINI, Giampiero ,  GUIDOTTI, Simona ,  DALL'OCCO, Tiziano

IPC: B01J31/02 ,  C08F4/00

CPC classification number: C08F4/76 ,  B01J31/0202 ,  B01J2531/22 ,  B01J2531/46 ,  C08F4/10 ,  C08F4/52 ,  C08F110/02 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/651 ,  C08F4/6555

Abstract: Catalyst components for the polymerization of olefins CH 2 =CHR wherein R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms, comprising Mg, Ti, CI and a diol or a derivative thereof.

Abstract translation: 用于烯烃CH 2 = CHR的聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包含Mg，Ti，Cl和二元醇或其衍生物。

公开(公告)号：WO2012052387A1

公开(公告)日：2012-04-26

申请号：PCT/EP2011/068080

申请日：2011-10-17

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MORINI, Giampiero ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  PATER, Joachim T. M.

Inventor： MORINI, Giampiero ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  PATER, Joachim T. M.

IPC: C08F10/06 ,  C08F4/651 ,  C08F4/654 ,  C08F4/649

CPC classification number: C08F4/16 ,  C08F10/06 ,  C08F110/06 ,  C08F4/6543 ,  C08F4/6494 ,  C08F4/651 ,  C08F2/14 ,  C08F2500/03 ,  C08F2500/12

Abstract: A catalyst system comprising the product obtained by contacting (a) a solid catalyst component containing Mg, Ti, halogen and at least an electron donor compound selected from diolesters of a specific formula (b) an alkylaluminum cocatalyst and (c) an ester of formula R'OOC-(CR" 2 ) m -COOR' in which m is an integer from 2 to 8, the R' groups, equal to or different from each other, are C1-C10 alkyl groups and the R" groups, independently, are hydrogen or C1 -C15 hydrocarbon groups.

Abstract translation: 一种催化剂体系，其包括通过使（a）含有Mg，Ti，卤素和至少一种选自特定式（b）的二极体的电子给体化合物的（a）固体催化剂组分与烷基铝助催化剂和（c）式 R'OOC-（CR“2）m-COOR'，其中m为2至8的整数，R'基彼此相同或不同，为C1-C10烷基，R”基团独立地为 是氢或C 1 -C 15烃基。

公开(公告)号：WO2012017040A1

公开(公告)日：2012-02-09

申请号：PCT/EP2011/063450

申请日：2011-08-04

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MORINI, Giampiero ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  Pater, Jochem, T., M.

Inventor： MORINI, Giampiero ,  BALBONI, Davide ,  CRISTOFORI, Antonio ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  Pater, Jochem, T., M.

IPC: C08F10/06 ,  C08F4/651 ,  C08F4/646 ,  C08F4/654

CPC classification number: C08F4/6494 ,  C08F10/06 ,  C08F4/6465 ,  C08F4/651 ,  C08F4/6543

Abstract: A catalyst component for the polymerization of olefins comprising Mg, Ti and at least two electron donor compounds, one of which (A) belonging to specific diolesters and the other electron donor compound (B) being selected from aromatic monoesters of the following formula (B) in which R groups equal to or different from each other, are selected from C 1 -C 15 hydrocarbon groups which can be also linked to form one or more cycles, m is an integer from 1 to 5 and R 5 is a C 1 -C 15 alkyl group, said electron donors A and B being in amounts such that the A/B molar ratio is lower than 20.

Abstract translation: 一种用于烯烃聚合的催化剂组分，包括Mg，Ti和至少两种电子给体化合物，其中一种（A）属于特定二极体，另一种电子给体化合物（B）选自下式的芳族单酯（B ）其中R基彼此相同或不同，选自可以连接形成一个或多个周期的C 1 -C 15烃基，m是1至5的整数，R 5是C 1 -C 15烷基 所述电子给体A和B的量使得A / B摩尔比低于20。