公开(公告)号：DE3887647D1

公开(公告)日：1994-03-17

申请号：DE3887647

申请日：1988-11-18

Applicant: BASF AG

Inventor： BAUS ULF DR ,  REUTHER WOLFGANG DR

IPC: C07D231/12 ,  C07D231/16 ,  C07D277/32 ,  C07D277/68 ,  C07D277/74

公开(公告)号：DE58905664D1

公开(公告)日：1993-10-28

申请号：DE58905664

申请日：1989-06-10

Applicant: BASF AG

Inventor： BAUS ULF DR ,  REUTHER WOLFGANG DR ,  HAHN ERWIN DR

IPC: C07D231/12 ,  C07D231/16 ,  C07D521/00

Abstract: Process for the preparation of N-hydroxypyrazoles of the general formula I in which R , R and R can be identical or different and can denote hydrogen or halogen, which is characterised in that pyrazoles of the general formula II in which the radicals R , R and R have the meaning given in formula I, are reacted with an aliphatic or aromatic peroxocarboxylic acid, preferably in the presence of 0 to 15 mol of an alkali metal or alkaline earth metal hydroxide or carbonate, such that the reaction temperature is between -5 DEG C and 60 DEG C. The reaction can be carried out in water as the solvent or in a 2-phase system composed of water and an only poorly water-miscible inert organic solvent, optionally in the presence of a suitable phase transfer catalyst. The peroxocarboxylic acid can be prepared before the reaction in a reaction mixture of H2O2, carboxylic acid halide or a carboxylic acid anhydride or employed in the form of an alkali metal or alkaline earth metal salt.

公开(公告)号：CS9000881A3

公开(公告)日：1992-02-19

申请号：CS88190

申请日：1990-02-23

Applicant: BASF AG

Inventor： SCHUETZ FRANZ DR ,  SAUTER HUBERT DR ,  BRAND SIEGBERT DR ,  WENDEROTH BERND DR ,  BAUS ULF DR ,  REUTHER WOLFGANG DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR

IPC: A01N43/56 ,  A01N43/58 ,  C07D231/12 ,  C07D231/14 ,  C07D231/16 ,  C07D231/56 ,  C07D521/00

Abstract: Substituted N-hydroxypyrazoles of the general formula I where R1, R2 and R3 are identical or different and are hydrogen, alkyl, haloalkyl, cycloalkyl, alkoxycarbonyl, halogen, aryl or arylalkyl, the aromatic ring being unsubstituted or substituted, or R2 and R3 form, with the pyrazole ring, a substituted or unsubstituted aromatic or aliphatic ring, X is CH or N, and their plant-tolerated acid addition salts and metal complexes, and fungicides containing these compounds.

公开(公告)号：DE3914632A1

公开(公告)日：1990-11-08

申请号：DE3914632

申请日：1989-05-03

Applicant: BASF AG

Inventor： BAUS ULF DR ,  REUTHER WOLFGANG DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR

IPC: C07D405/12 ,  A01N43/56 ,  A01N43/653 ,  C07D249/08 ,  C07D521/00

Abstract: Compounds of the general formula I (I) where X is alkyl, aryl, aryloxy or alkoxy, Y is hydrogen, alkyl, alkoxy, halogen, aryl or aryloxy, n is 0 to 5, and Z is CH or N, and fungicides containing these compounds.

公开(公告)号：DE3906771A1

公开(公告)日：1990-09-06

申请号：DE3906771

申请日：1989-03-03

Applicant: BASF AG

Inventor： BAUS ULF DR ,  REUTHER WOLFGANG DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR

IPC: A01N43/653 ,  C07D249/08 ,  C07D521/00

公开(公告)号：DE3905948A1

公开(公告)日：1990-08-30

申请号：DE3905948

申请日：1989-02-25

Applicant: BASF AG

Inventor： SCHUETZ FRANZ DR ,  SAUTER HUBERT DR ,  BRAND SIEGBERT DR ,  WENDEROTH BERND DR ,  BAUS ULF DR ,  REUTHER WOLFGANG DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR

IPC: A01N43/56 ,  A01N43/58 ,  C07D231/12 ,  C07D231/14 ,  C07D231/16 ,  C07D231/56 ,  C07D521/00

Abstract: Substituted N-hydroxypyrazoles of the general formula I where R1, R2 and R3 are identical or different and are hydrogen, alkyl, haloalkyl, cycloalkyl, alkoxycarbonyl, halogen, aryl or arylalkyl, the aromatic ring being unsubstituted or substituted, or R2 and R3 form, with the pyrazole ring, a substituted or unsubstituted aromatic or aliphatic ring, X is CH or N, and their plant-tolerated acid addition salts and metal complexes, and fungicides containing these compounds.

公开(公告)号：DE3905766A1

公开(公告)日：1990-08-30

申请号：DE3905766

申请日：1989-02-24

Applicant: BASF AG

Inventor： BAUS ULF DR ,  REUTHER WOLFGANG DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR

IPC: A01N43/653 ,  C07D249/08 ,  C07D521/00

Abstract: Compounds of the general formula I where 5 R is alkyl or substituted or unsubstituted aryl, X is C=O or CHOH and derivatives thereof, Y is hydrogen, alkyl, alkoxy, halogen, aryl or aryloxy, and n is 1 to 5, and fungicides containing these compounds.

公开(公告)号：DE3840342A1

公开(公告)日：1990-05-31

申请号：DE3840342

申请日：1988-11-30

Applicant: BASF AG

Inventor： BAUS ULF DR ,  REUTHER WOLFGANG DR

IPC: A61K31/00 ,  C07D231/00 ,  C07D231/16

Abstract: Process for the preparation of 4-chloropyrazoles of the general formula I in which R to R , independently of one another, denote hydrogen or a radical which is inert under the reaction conditions, by reacting pyrazoles of the general formula II in which R to R have the abovementioned meanings, with 0.95 to 10 equivalents of hypochlorous acid or its salts, essentially in the absence of a carboxylic acid.

公开(公告)号：DE3820739A1

公开(公告)日：1989-12-21

申请号：DE3820739

申请日：1988-06-18

Applicant: BASF AG

Inventor： BAUS ULF DR ,  REUTHER WOLFGANG DR ,  HAHN ERWIN DR

IPC: C07D231/12 ,  C07D231/16 ,  C07D521/00

Abstract: Process for the preparation of N-hydroxypyrazoles of the general formula I in which R , R and R can be identical or different and can denote hydrogen or halogen, which is characterised in that pyrazoles of the general formula II in which the radicals R , R and R have the meaning given in formula I, are reacted with an aliphatic or aromatic peroxocarboxylic acid, preferably in the presence of 0 to 15 mol of an alkali metal or alkaline earth metal hydroxide or carbonate, such that the reaction temperature is between -5 DEG C and 60 DEG C. The reaction can be carried out in water as the solvent or in a 2-phase system composed of water and an only poorly water-miscible inert organic solvent, optionally in the presence of a suitable phase transfer catalyst. The peroxocarboxylic acid can be prepared before the reaction in a reaction mixture of H2O2, carboxylic acid halide or a carboxylic acid anhydride or employed in the form of an alkali metal or alkaline earth metal salt.

公开(公告)号：DE59303720D1

公开(公告)日：1996-10-17

申请号：DE59303720

申请日：1993-06-01

Applicant: BASF AG

Inventor： DYLLICK-BRENZINGER RAINER DR ,  BAUS ULF DR

IPC: C07C41/16 ,  C07C43/20