Azo dyes - using 2,6-diaminopyridine deriv coupling component

    公开(公告)号:DE2259684A1

    公开(公告)日:1974-06-12

    申请号:DE2259684

    申请日:1972-12-06

    Applicant: BASF AG

    Abstract: Title dyes are of formula (I) where D = residue of diazo component, R = opt. substd. alkyl or opt. substd. phenyl. X = H, CN or opt. subst. carbamoyl grp., R' = (CH2)mCH(CH3)C6H5, (CH2)mCH(CH3)C6H4CH3, CH(CH3)(CH2)3-C(CH3)2-OH, (CH2)3-O-C6H11, (CH2)3-O-CH2-C6H10-CH2OH, (CH2)3(OCH-CH)p(H)(CH3)(O-R8), (CH-CH)(H)(OC6H5)(CH3), (CH-CH)(H)(OC6H4CH3)(CH3), an OH-contg. gp. (CH2)3(OCH-CH)(H)(CH3)(O-R8, (CH2)3(CH2)2OH, (CH2)3(OC2H4)qOR8, (CH2)3OR9, C2H4OC65 or C2H4OC6H4CH3, R2 = H or an opt. substd. (cyclo)aliphatic araliphatic or aryl grp., R3 = 1 - 3C alkyl or hydroxyalkyl grp., R4 = H, 1 - 3C alkyl or hydroxyalkyl, R5 = H, 1 - 4C alkyl or (m)ethoxy grp. or Cl, R7 = ethyl, propyl, butyl, cyclohexyl, benzyl, phenylethyl or methylphenyl grp., R8 = H, 1 - 4C alkyl, cyclohexyl, phenyl methylphenyl, benzyl or phenylethyl grp., R9 = cyclohexyl, phenyl, methylphenyl, benzyl or phenylethyl grp., m = 1 or 2, n = 0, 1 or 2, p = 1, 2, 3 or 4 and q = 2, 3 or 4. The dyes have yellow to blue tints and are useful for dyeing textiles e.g. of polyester, polyamide, polyacrylonitrile etc.

    Azo dyes - prepd by coupling diazotised amines with benzothiazolyl derivs

    公开(公告)号:DE2232449A1

    公开(公告)日:1974-01-10

    申请号:DE2232449

    申请日:1972-07-01

    Applicant: BASF AG

    Abstract: Yellow to organe azo dyes for natural and synthetic polyamides, e.g. wool, silk, leather, nylon 6 or 6,6; cellulose esters, e.g. -2 1/2 and triacetate and synthetic linear polyesters, have the formula: (where D is a diazo component gp.; X is 2-9 C opt. substd. carbamoyl or carboxylate; M is H, Na, K or opt. substd. NH4 and n is 0 to 3). They are prepd diazotising amines DNH2 and coupling with cpds. (where p is 0 or 1) or by sulphonating cpds. of formula: D-NH-=CX- , esp. with oleum.

    Azo dyes - using 2,6-diaminopyridine deriv coupling component

    公开(公告)号:DE2226933A1

    公开(公告)日:1973-12-13

    申请号:DE2226933

    申请日:1972-06-02

    Applicant: BASF AG

    Abstract: Title dyes are of formula (I) where D = residue of diazo component, R = opt. substd. alkyl or opt. substd. phenyl. X = H, CN or opt. subst. carbamoyl grp., R' = (CH2)mCH(CH3)C6H5, (CH2)mCH(CH3)C6H4CH3, CH(CH3)(CH2)3-C(CH3)2-OH, (CH2)3-O-C6H11, (CH2)3-O-CH2-C6H10-CH2OH, (CH2)3(OCH-CH)p(H)(CH3)(O-R8), (CH-CH)(H)(OC6H5)(CH3), (CH-CH)(H)(OC6H4CH3)(CH3), an OH-contg. gp. (CH2)3(OCH-CH)(H)(CH3)(O-R8, (CH2)3(CH2)2OH, (CH2)3(OC2H4)qOR8, (CH2)3OR9, C2H4OC65 or C2H4OC6H4CH3, R2 = H or an opt. substd. (cyclo)aliphatic araliphatic or aryl grp., R3 = 1 - 3C alkyl or hydroxyalkyl grp., R4 = H, 1 - 3C alkyl or hydroxyalkyl, R5 = H, 1 - 4C alkyl or (m)ethoxy grp. or Cl, R7 = ethyl, propyl, butyl, cyclohexyl, benzyl, phenylethyl or methylphenyl grp., R8 = H, 1 - 4C alkyl, cyclohexyl, phenyl methylphenyl, benzyl or phenylethyl grp., R9 = cyclohexyl, phenyl, methylphenyl, benzyl or phenylethyl grp., m = 1 or 2, n = 0, 1 or 2, p = 1, 2, 3 or 4 and q = 2, 3 or 4. The dyes have yellow to blue tints and are useful for dyeing textiles e.g. of polyester, polyamide, polyacrylonitrile etc.

    Azo dyes - from 2,6-diaminopyridine derivatives

    公开(公告)号:DE2062717A1

    公开(公告)日:1972-06-29

    申请号:DE2062717

    申请日:1970-12-19

    Applicant: BASF AG

    Abstract: New dyes have the formula (I): where D is the residue of a diazo component of the benzene, naphthalene, diphenyl, azobenzene, thiophene, benz(iso)thiazole, thiazole, (benz)triazole, indazole, pyrazole or anthraquinone series, X is CN or CONH2, R is H, 1-8C alkyl, alkyl substd. by OH, 1-8C alkoxy, COOH, 2-6C carbalkoxy, 1-10C acyloxy or is not >8C alkylamino or interrupted by O, phenyl (opt. substd. by Cl, CH3, C2H5, OHCH2CH2, CH3O or C2H5O), cyclohexyl, benzyl, phenylethyl or omega-N-pyrrolidonyl-alkyl with 2-3C in the alkyl gp., R1 is H, 1-8C alkyl, alkyl substd. by OH, 1-8C alkoxy, or is not 8C alkylamino, R and R1 together with the N atom represent the residue of pyrrolidine, piperidine, morpholine or (N-methyl)-piperazine, R2 is as in R, R3 is as in R1, and R2 + R3 are as in R + R1. The dyes are yellow to greenish-blue, and are suitable for dyeing or printing polyacrylonitrile, polyamides, cellulose esters and polyesters. Strong dyeings with good resistance, esp. to thermo-fixing and light are obtd.

    48.
    发明专利
    未知

    公开(公告)号:DE1770960A1

    公开(公告)日:1972-01-13

    申请号:DE1770960

    申请日:1968-07-24

    Applicant: BASF AG

    Abstract: 1,225,336. Quinophthalone dyes. BADISCHE ANILIN- & SODA FABRIK A.G. 23 July, 1969 [24 July, 1968], No. 37037/69. Heading CAP. Quinophthalone dyes of formula (in which X and Y are each Cl or Br), are prepared by heating 8-aminoquinaldine with tetrachloro- and/or tetrabromo-phthalic anhydride, preferably in an inert solvent in the presence of ZnCl 2 .

    49.
    发明专利
    未知

    公开(公告)号:DE1770959A1

    公开(公告)日:1971-06-03

    申请号:DE1770959

    申请日:1968-07-24

    Applicant: BASF AG

    Abstract: 1,269,389. Azo and azomethine dyes. BADISCHE ANILIN- & SODA-FABRIK A.G. 23 July, 1969 [24 July, 1968], No. 37036/69. Heading C4P. Metal-containing azomethine and azo dyes are of formula (in which A completes an optionally substituted benzene or naphthalene ring free from SO 3 H groups; M is a metal of atomic no. 23-92). Preferably A completes a naphthalene or benzene ring optionally substituted by NO 2 , Cl, CH 3 , N(CH 3 ) 2 , SO 2 N(CH 3 ) 2 , CO 2 H or CONHC 6 H 5 , pnitrophenylazo or (p-phenylazo)phenylazo, and Me is Cu or Ni. The dyes may be prepared by condensing ortho- OHO-A-OH with 2-(8- aminoquinolyl-(2))-indandione-(1,3) to form an azomethine dye of formula and simultaneously or subsequently treating with a metallizing agent.

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