42.
    发明专利
    未知

    公开(公告)号:BR9713288A

    公开(公告)日:1999-10-26

    申请号:BR9713288

    申请日:1997-11-21

    Applicant: BASF AG

    Abstract: A process is described for preparing (meth)acrylic esters by reacting (meth)acrylic acid with C4-C12-alkanols in the presence of sulfuric acid or a mono-C4-C12-alkyl sulfate as catalyst, where the catalyst is regenerated by extraction with water from the reaction mixture and the aqueous catalyst solution is recycled back to the esterification, the concentration of unreacted alkanol in the reaction mixture to be extracted being not more than 5% by weight, based on the reaction mixture to be extracted.

    43.
    发明专利
    未知

    公开(公告)号:DE59602784D1

    公开(公告)日:1999-09-23

    申请号:DE59602784

    申请日:1996-09-26

    Applicant: BASF AG

    Abstract: A process for the prodn. of (1-4C alkyl) (meth)acrylate esters (AM/AE) from esters of formula (I) and opt. esters of formula (II), in which R = H or Me; R , R = 1-4C alkyl; n = 0 or more. The process comprises reaction in the liq. phase under reduced pressure in presence of acid, with continuous removal of cleavage prods. Also claimed is a process for the prodn. of (AM/AE) by the acid-catalysed esterification of 1-4C alkanols with (meth)acrylic acid, in which by-prods. (I) and (II) are sepd. from the prod. mixt. and subjected to the above cleavage process, and the cleavage prods. are continuously removed and returned to the esterification process.

    PROCESS FOR PREPARING ESTERS OF (METH)ACRYLIC ACID

    公开(公告)号:CZ173199A3

    公开(公告)日:1999-09-15

    申请号:CZ173199

    申请日:1997-11-21

    Applicant: BASF AG

    Abstract: (Meth)acrylic esters are prepared by reacting (meth)acrylic acid with a C4-C12-alkanol in the presence of sulfuric acid or a mono-C4-C12-alkyl sulfate as catalyst, whereina) the reaction is carried out in an esterification unit which comprises a first reactor and at least one further reactor,b) a mixture of (meth)acrylic acid, C4-C12-alkanol and catalyst which contains not more than 5% by weight of water, based on the sum of the starting materials, is introduced into the first reactor,c) the esterification in the first reactor is conducted without removing ester, alkanol or water to a (meth)acrylic acid conversion of at least 40%, but only so far that the mixture remains a single phase, andd) the esterification is continued in at least one further reactor with the water formed being removed by distillation.

    Method for the production of (meth)acrylic acid esters

    公开(公告)号:AU5485298A

    公开(公告)日:1998-06-22

    申请号:AU5485298

    申请日:1997-11-21

    Applicant: BASF AG

    Abstract: A process is described for preparing (meth)acrylic esters by reacting (meth)acrylic acid with C4-C12-alkanols in the presence of sulfuric acid or a mono-C4-C12-alkyl sulfate as catalyst, where the catalyst is regenerated by extraction with water from the reaction mixture and the aqueous catalyst solution is recycled back to the esterification, the concentration of unreacted alkanol in the reaction mixture to be extracted being not more than 5% by weight, based on the reaction mixture to be extracted.

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