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公开(公告)号:DE59205457D1
公开(公告)日:1996-04-04
申请号:DE59205457
申请日:1992-08-29
Applicant: BASF AG
Inventor: KERSTING MEINOLF , HUNGENBERG KLAUS-DIETER , KOELLE PETER
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公开(公告)号:ZA9206923B
公开(公告)日:1994-03-11
申请号:ZA9206923
申请日:1992-09-11
Applicant: BASF AG
Inventor: KERSTING MEINOLF , KERTH JUERGEN , HUNGERBERG KLAUS-DIETER , KOELLE PETER
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公开(公告)号:BR9005591A
公开(公告)日:1991-09-17
申请号:BR9005591
申请日:1990-11-05
Applicant: BASF AG
Inventor: SCHWAGER HARALD , KOELLE PETER , KERTH JUERGEN , ZOLK RALF
Abstract: Catalyst systems of the Ziegler-Natta catalyst type, containing, as active constituents, a) a titanium-containing solid component which contains titanium, magnesium, halogen and a carboxylic acid ester, and, as cocatalyst, b) an aluminium compound and c) optionally further electron-donor compounds, characterised in that they contain in the solid component, as the carboxylic acid ester, a diester of a carboxylic acid of the formula Ia or Ib in which R , R , R and R are identical or different and are hydrogen, C1-C15-alkyl, C7-C15-alkylaryl or 5- to 7-membered cycloalkyl, which may itself carry C1- to C10-alkyl groups. These catalyst systems are particularly suitable for the preparation of polypropylene and copolymers of propylene with minor amounts of other alpha , beta -unsaturated olefinic compounds having 2 to 12 carbon atoms.
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