公开(公告)号：ES2174542T3

公开(公告)日：2002-11-01

申请号：ES98965863

申请日：1998-12-21

Applicant: BASF AG

Inventor： HEINEKE DANIEL ,  MEISSNER RUPRECHT ,  HESSE MICHAEL ,  GEHRKEN HENNING-PETER

IPC: B01J23/72 ,  B01J31/06 ,  B01J37/02 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  C07B35/04 ,  C07B61/00 ,  C07C45/00 ,  C07C45/29 ,  C07C49/403

Abstract: The disclosure is directed to a process for preparing an oxidic catalyst comprising copper in an oxidation state >0, which comprises treating a solid oxidic support material with an aqueous solution comprising at least one copper salt and at least one organic water soluble polymer which binds copper ions coordinatively in a concentration of from 0.1 to 100 g/l and then calcining, to the catalyst obtainable by this process and also to a process for dehydrogenating secondary alcohols to ketones using the catalysts, especially for dehydrogenating cyclohexanol.

公开(公告)号：PL341439A1

公开(公告)日：2001-04-09

申请号：PL34143998

申请日：1998-12-21

Applicant: BASF AG

Inventor： HEINEKE DANIEL ,  MEISSNER RUPRECHT ,  HESSE MICHAEL ,  GEHRKEN HENNING-PETER

IPC: B01J23/72 ,  B01J31/06 ,  B01J37/02 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  C07B35/04 ,  C07B61/00 ,  C07C45/00 ,  C07C45/29 ,  C07C49/403

Abstract: The disclosure is directed to a process for preparing an oxidic catalyst comprising copper in an oxidation state >0, which comprises treating a solid oxidic support material with an aqueous solution comprising at least one copper salt and at least one organic water soluble polymer which binds copper ions coordinatively in a concentration of from 0.1 to 100 g/l and then calcining, to the catalyst obtainable by this process and also to a process for dehydrogenating secondary alcohols to ketones using the catalysts, especially for dehydrogenating cyclohexanol.

公开(公告)号：CZ9804254A3

公开(公告)日：1999-11-17

申请号：CZ425498

申请日：1997-06-17

Applicant: BASF AG

Inventor： HEINEKE DANIEL ,  MEISSNER RUPRECHT ,  HESSE MICHAEL ,  MARKL ROBERT

IPC: B01J21/04 ,  B01J23/72 ,  B01J23/89 ,  B01J32/00 ,  B01J35/10 ,  B01J37/04 ,  C07C45/00

CPC classification number: B01J23/8926 ,  B01J23/72 ,  C07C45/002 ,  C07C49/403

公开(公告)号：BR9710017A

公开(公告)日：1999-08-10

申请号：BR9710017

申请日：1997-06-17

Applicant: BASF AG

Inventor： HEINEKE DANIEL ,  MEISSNER RUPRECHT ,  HESSE MICHAEL ,  MARKL ROBERT

IPC: B01J21/04 ,  B01J23/72 ,  B01J23/89 ,  B01J32/00 ,  B01J35/10 ,  B01J37/04 ,  C07C45/00

Abstract: The invention relates to a catalyst comprising alpha -aluminium oxide as the support material and copper as the active constituent, the BET surface (as defined in DIN 66131) of the aluminium oxide being not lower than 30 m /g. It also relates to a process for preparing said catalyst according to the invention, and the use thereof in dehydrogenation of cyclohexanol to form cyclohexanone, and also to the use of alpha -aluminium oxide, the BET surface (as defined in DIN 66131) of said aluminium oxide being not lower than 30 m /g, to prepare a catalyst.

公开(公告)号：NO986155A

公开(公告)日：1998-12-28

申请号：NO986155

申请日：1998-12-28

Applicant: BASF AG

Inventor： HEINEKE DANIEL ,  MEISSNER RUPRECHT ,  HESSE MICHAEL ,  MORKL ROBERT

IPC: B01J21/04 ,  B01J23/72 ,  B01J23/89 ,  B01J32/00 ,  B01J35/10 ,  B01J37/04 ,  C07C45/00

CPC classification number: B01J23/8926 ,  B01J23/72 ,  C07C45/002 ,  C07C49/403

公开(公告)号：ZA844793B

公开(公告)日：1985-02-27

申请号：ZA844793

申请日：1984-06-25

Applicant: BASF AG

Inventor： MEISSNER RUPRECHT ,  NETH NORBERT

IPC: B01J23/22 ,  B01J27/055 ,  C01B17/79 ,  B01J ,  C01B

Abstract: Catalysts for the oxidation of sulfur dioxide to sulfur trioxide, consisting of a silica-based carrier and, applied on this, an active substance containing vanadium and alkali metal compounds, are prepared by dissolving vanadium pentoxide in an alkali solution, acidifying the solution with sulfuric acid, mixing the acidified solution with the carrier, molding the mixture and drying and calcining the molding. To obtain mechanically stable catalysts, a dissolved alkali metal silicate and/or silica sol are added to the alkaline solution before acidification, the latter process is carried out at below 35 DEG C. and the solution is then immediately incorporated into the carrier. The resulting moist crumbly material contains from 2 to 6% by weight of V2O5, from 35 to 45% by weight of H2O and from 15 to 50% by weight of SiO2. From 5 to 25% by weight of the total silica content originates from the dissolved alkali metal silicate and/or silica sol.

公开(公告)号：ZA8404793B

公开(公告)日：1985-02-27

申请号：ZA8404793

申请日：1984-06-25

Applicant: BASF AG

Inventor： MEISSNER RUPRECHT ,  NETH NORBERT

IPC: B01J23/22 ,  B01J27/055 ,  C01B17/79 ,  B01J ,  C01B

CPC classification number: C01B17/79 ,  B01J23/22

公开(公告)号：DK306084D0

公开(公告)日：1984-06-22

申请号：DK306084

申请日：1984-06-22

Applicant: BASF AG

Inventor： MEISSNER RUPRECHT ,  NETH NORBERT

IPC: B01J23/22 ,  B01J27/055 ,  C01B17/79 ,  B01J ,  C01B

Abstract: Catalysts for the oxidation of sulfur dioxide to sulfur trioxide, consisting of a silica-based carrier and, applied on this, an active substance containing vanadium and alkali metal compounds, are prepared by dissolving vanadium pentoxide in an alkali solution, acidifying the solution with sulfuric acid, mixing the acidified solution with the carrier, molding the mixture and drying and calcining the molding. To obtain mechanically stable catalysts, a dissolved alkali metal silicate and/or silica sol are added to the alkaline solution before acidification, the latter process is carried out at below 35 DEG C. and the solution is then immediately incorporated into the carrier. The resulting moist crumbly material contains from 2 to 6% by weight of V2O5, from 35 to 45% by weight of H2O and from 15 to 50% by weight of SiO2. From 5 to 25% by weight of the total silica content originates from the dissolved alkali metal silicate and/or silica sol.