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    PRODUCTION OF CATECHOL MONOETHER OR CATECHOL
    2.
    发明专利
    PRODUCTION OF CATECHOL MONOETHER OR CATECHOL 失效

    公开(公告)号：JPH1180059A

    公开(公告)日：1999-03-23

    申请号：JP20058098

    申请日：1998-07-15

    Applicant: BASF AG

    Inventor： HEINEKE DANIEL ,  DINGERDISSEN UWE ,  WULFF-DOERING JOACHIM ,  HESSE MICHAEL

    IPC: B01J23/44 ,  C07B61/00 ,  C07C33/26 ,  C07C37/00 ,  C07C37/055 ,  C07C37/06 ,  C07C37/07 ,  C07C37/50 ,  C07C39/08 ,  C07C41/18 ,  C07C41/28 ,  C07C43/205 ,  C07C43/23

    Abstract: PROBLEM TO BE SOLVED: To obtain a catechol monoether or catechol, both of which are useful as intermediates for synthesizing medicines, flavors, and seasonings, simply and economically, by reacting a specific oxygen-containing cyclohexane compound in the presence of a specific catalyst. SOLUTION: A catechol monoether shown by formula III is obtained by the reaction of (A) a compound shown by formula I (R is a 1-8C hydrocarbon group; R and R are each H or R ) or a compound shown by formula II in the presence of (B) a catalyst in which palladium (B2 ) is supported on vanadium oxide carrier (B1 ) (e.g. a catalyst which contains B2 at 0.2-5 wt.% per sum of B1 and B2 calculated as metal, whose BET surface area is 10-300 m /g, which has an average pore size of 2-100 nm and a pore volume of 0.1-1 ml/g, and which crystal transformation of B1 is monoclinic system at 60-100%) in gas phase. The catechol shown by formula IV is obtained also by the reaction in water.

    SPINEL MONOLIGHT CATALYST AND METHOD OF MANUFACTURING THE SAME
    3.
    发明专利
    SPINEL MONOLIGHT CATALYST AND METHOD OF MANUFACTURING THE SAME 失效

    公开(公告)号：JP2001149782A

    公开(公告)日：2001-06-05

    申请号：JP2000317318

    申请日：2000-10-18

    Applicant: BASF AG

    Inventor： BENDER MICHAEL ,  KUMBERGER OTTO ,  HESSE MICHAEL

    IPC: B01D53/94 ,  B01J23/00 ,  B01J23/72 ,  B01J23/76 ,  B01J23/84 ,  B01J23/847 ,  B01J35/04 ,  B01J37/02

    Abstract: PROBLEM TO BE SOLVED: To provide a spinel monolithic catalyst, manufacturing method therefor and a method of using it for reducing NOx in a waste combustion gas. SOLUTION: This spinel monolighic catalyst contains the spinel shown by general formula I: AxB(1-x)E2O4 (wherein all of A are Cu or half of A or less may be substituted with Co, Fe, Mn or Cr; B is at least one element selected from the group consisting of Zn, Mg, Ca, Zr, Ce, Sn, Ti, V, Mo and W; all of E are Al or half of E or less may be substituted with Fe2O3, Cr2O3, Ga2O3, La2O3 or a mixture of them; and (x) is 0-1, preferably 0-0.9). The spinel monolighic catalyst is obtained by manufacturing a particularly monolithic sintered compact by using the spinel or subsequently covering at least the surface of the sintered compact with an active composition, impregnating the obtained sintered compact with the solution containing transition elements of group V of the periodic table or adding the oxides or salts of these elements to the obtained sintered compact, drying and sintering it.

    TWO-STAGE METHOD FOR PRODUCING BUTANDIOL IN TWO REACTORS
    9.
    发明申请
    TWO-STAGE METHOD FOR PRODUCING BUTANDIOL IN TWO REACTORS 审中-公开
    两步反应器制备丁醇的两步法

    公开(公告)号：WO03104214A8

    公开(公告)日：2004-05-13

    申请号：PCT/EP0306060

    申请日：2003-06-10

    Applicant: BASF AG ,  HESSE MICHAEL ,  SCHLITTER STEPHAN ,  BORCHERT HOLGER ,  SCHUBERT MARKUS ,  ROESCH MARKUS ,  BOTTKE NILS ,  FISCHER ROLF-HARTMUTH ,  WECK ALEXANDER ,  WINDECKER GUNTHER ,  HEYDRICH GUNNAR

    Inventor： HESSE MICHAEL ,  SCHLITTER STEPHAN ,  BORCHERT HOLGER ,  SCHUBERT MARKUS ,  ROESCH MARKUS ,  BOTTKE NILS ,  FISCHER ROLF-HARTMUTH ,  WECK ALEXANDER ,  WINDECKER GUNTHER ,  HEYDRICH GUNNAR

    IPC: C07C29/149 ,  C07D315/00 ,  C07C31/20 ,  C07D307/20

    CPC classification number: C07D315/00 ,  C07C29/149 ,  C07C31/207

    Abstract: The invention relates to a method for producing optionally akyl-substituted 1,4-butandiol by two-stage catalytic hydration in the gaseous phase of C4 dicarboxylic acids and/or the derivatives thereof with the steps of: a) introducing a gaseous flow of a C4 dicarboxylic acid or a derivative thereof at 200 to 300 °C and 2 to 60 bar in a first reactor and catalytic gas phase hydration to a mainly optionally alkyl-substituted gamma-butyrolactone containing product; b) introducing the product flow so obtained into a second reactor at a temperature of from 150 °C to 240 °C and a pressure of from 15 to 100 bar and catalytic gas phase hydration to optionally alkyl-substituted 1,4-butandiol; c) removing the desired product from the intermediates, byproducts and possibly not reacted educt; d) optionally returning non-reacted intermediates to one or both hydration stages, whereby in both hydration stages one catalyst each is used which comprises = 5 % by weight, preferably 5 to 95 % by weight, especially 20 to 90 % by weight of an oxidic carrier, the pressure prevailing in the second reactor is higher than in the first reactor, and the product mixture removed from the first reactor is introduced into the second reactor without further purifying it.

    Abstract translation: 本发明涉及一种用于在C4二羧酸和/或其衍生物，包括以下步骤的气相制备任选被烷基取代的1,4-丁二醇，通过两阶段催化氢化：a）将C4二羧酸的气体流或它们的衍生物 在200〜300℃和2至在第一反应器和催化气相加氢在含有产物主要为任选被烷基取代的γ-丁内酯60巴; b）将由此获得进入第二反应器在150℃的温度至240℃的产品流和15至100巴和催化气相任选烷基取代的1,4-丁二醇的压力; c）从中间体，副产物和任选未反应的离析物中分离所需产物; d）任选地回收未转化的中间体在一个或两个氢化阶段，其中，在每种情况下，催化剂在两个氢化中使用的<= 95重量％，优选为5〜95重量％，特别是10至80重量％的CuO 和> = 5具有重量％，优选为5〜95重量％，特别是20至90重量的氧化载体的％，在第二反应器更高的压力占优势比在第一反应器和与第一反应器的产物混合物将取出的 不经进一步纯化而引入第二反应器中。

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