公开(公告)号：DE3346935A1

公开(公告)日：1985-07-04

申请号：DE3346935

申请日：1983-12-24

Applicant: BASF AG

Inventor： MUENSTEDT HELMUT DR ,  NAARMANN HERBERT DR

IPC: C08G61/00 ,  C08F8/00 ,  C08G61/10 ,  C08G61/12 ,  C08L79/04 ,  H01B1/12 ,  C08F34/00 ,  C08F8/34 ,  C08F8/42

Abstract: The long-term stability of the electrical conductivity of pyrrole polymers is improved by a process in which the polymers are treated with an aqueous acid. Pyrrole polymers treated in this manner are used as conductor elements in the electrical industry.

公开(公告)号：DE3346934A1

公开(公告)日：1985-07-04

申请号：DE3346934

申请日：1983-12-24

Applicant: BASF AG

Inventor： MUENSTEDT HELMUT DR ,  NAARMANN HERBERT DR

IPC: C08G61/00 ,  C08F8/00 ,  C08G61/10 ,  C08G61/12 ,  C08L79/04 ,  H01B1/12 ,  C08F34/00 ,  C08F8/34 ,  C08F8/42

Abstract: The long-term stability of the electrical conductivity of pyrrole polymers is improved by a process in which the polymers are treated with an aqueous alkali metal hydroxide solution. Pyrrole polymers treated in this manner are used as electrical conductor elements or resistive films.

公开(公告)号：DE3340679A1

公开(公告)日：1985-05-23

申请号：DE3340679

申请日：1983-11-10

Applicant: BASF AG

Inventor： NAARMANN HERBERT DR ,  KOESSLER LUDWIG

IPC: C08G61/12 ,  C08G73/06 ,  C08J5/18 ,  C25B3/00 ,  H01B1/12 ,  B01J21/02 ,  B01J23/16 ,  B01J27/08 ,  C08F34/00 ,  C08G73/02 ,  C08L45/00 ,  C25D13/08 ,  C25D13/18 ,  C30B29/58

公开(公告)号：DE3169694D1

公开(公告)日：1985-05-09

申请号：DE3169694

申请日：1981-09-09

Applicant: BASF AG

Inventor： BRANDSTETTER FRANZ DR ,  HAMBRECHT JUERGEN DR ,  NAARMANN HERBERT DR ,  SCHUSTER HANS DR

IPC: C08G81/00 ,  C08G65/48 ,  C08G81/02 ,  C08L25/04 ,  C08L51/00 ,  C08L71/04

Abstract: Thermosplastic molding materials which contain styrene polymers and polyphenylene ethers whose phenolic hydroxyl groups have been reacted with reactive copolymers.

公开(公告)号：DE3168797D1

公开(公告)日：1985-03-21

申请号：DE3168797

申请日：1981-09-09

Applicant: BASF AG

Inventor： BRANDSTETTER FRANZ DR ,  ECHTE ADOLF DR ,  MITTNACHT HANS DR ,  NAARMANN HERBERT DR

IPC: C08L25/00 ,  C08L51/04 ,  C08L71/12 ,  C08L71/04

公开(公告)号：DE3315854A1

公开(公告)日：1984-10-31

申请号：DE3315854

申请日：1983-04-30

Applicant: BASF AG

Inventor： NAARMANN HERBERT DR ,  KOEHLER GERNOT DR

IPC: C08F38/02

Abstract: A process for the preparation of polyacetylenes in which acetylene or a mixture of acetylene with other alkynes is polymerised in a liquid reaction medium by means of catalysts based on salts of nickel or cobalt and alkaline metal borohydrides or alkaline metal aluminium hydrides, where, before the polymerisation, the liquid reaction medium containing the catalysts and acetylene or the acetylene-containing mixture is kept at temperatures of from -100 to -40 DEG C for some time and then heated to temperatures above -40 DEG C and polymerised.

公开(公告)号：DE3164459D1

公开(公告)日：1984-08-02

申请号：DE3164459

申请日：1981-10-24

Applicant: BASF AG

Inventor： NAARMANN HERBERT DR ,  NAEGELE DIETER DR ,  PENZIEN KLAUS DR ,  SCHLAG JOHANNES DR ,  KIENER VOLKER DR ,  BOEHN HUGO

IPC: C08G73/00 ,  C08G61/12 ,  C08G73/06 ,  C08J5/18 ,  H01B1/12 ,  H01L51/30 ,  H01M4/60

Abstract: Electrically conductive complexes of polypyrroles with nitroaromatic anions are prepared by polymerizing pyrrole, an N-alkylpyrrole and/or an N-arylpyrrole by anodic oxidation in a polar solvent, in the presence of a salt of an acidic nitroaromatic compound.

公开(公告)号：DE3244899A1

公开(公告)日：1984-06-07

申请号：DE3244899

申请日：1982-12-04

Applicant: BASF AG

Inventor： NAARMANN HERBERT DR ,  MUENCH VOLKER DR ,  PENZIEN KLAUS DR

IPC: C08F8/28 ,  H01B1/12 ,  H01L31/0224 ,  H01L51/30 ,  C08F8/00 ,  C08F8/40 ,  C08F38/00 ,  C08L43/02 ,  C08L49/00 ,  H01L31/04

Abstract: A process for the preparation of electroconductive conjugated polymers having electrical conductivities of greater than 6 . 10 S/cm, in which phosphonium ylides of polyenes are reacted with aldehydes or ketones which contain a conjugated pi -electron system in the molecule, and the resultant polymer is subsequently treated with conventional complexing agents.

公开(公告)号：DE3238930A1

公开(公告)日：1984-04-26

申请号：DE3238930

申请日：1982-10-21

Applicant: BASF AG

Inventor： HAMBRECHT JUERGEN DR ,  NAARMANN HERBERT DR ,  ECHTE ADOLF DR ,  SIMAK PETR DR ,  SWOBODA JOHANN DR

IPC: C08G63/664 ,  C08G65/48 ,  C08G65/44

Abstract: The invention relates to a process for the preparation of high-molecular-weight polyphenylene ethers from monohydric phenols by conventional polycondensation in which the polymers obtained are reacted with ss-lactones of the formula (I) in which R , R , R and R may be identical or different and are hydrogen atoms or alkyl, cycloalkyl, aryl, carboxyl, carboxyalkyl, nitrile or substituted alkyl groups, and/or are reacted with polymeric propiolactones. Particularly suitable lactones are propiolactone, ss,ss-dimethylpropiolactone, alpha , alpha -diphenylpropiolactone or polymeric propiolactone.

公开(公告)号：DE3237735A1

公开(公告)日：1984-04-12

申请号：DE3237735

申请日：1982-10-12

Applicant: BASF AG

Inventor： NAARMANN HERBERT DR ,  MUENCH VOLKER DR ,  PENZIEN KLAUS DR

IPC: C08F38/02

Abstract: Process for the preparation of polyacetylenes by homopolymerisation or copolymerisation of acetylene and/or acetylene compounds in the presence of certain metal catalysts and white phosphorus or phosphorus compounds containing a P-P bond.