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公开(公告)号:FR1279609A
公开(公告)日:1961-12-22
申请号:FR847704
申请日:1960-12-22
Applicant: BASF AG
Inventor: KESSLER HANSJUERGEN , PENNING ERNST , WILHELM HANS , REINHARD HANS
IPC: C08F220/28 , C08F222/18 , D06M15/263
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公开(公告)号:CA821587A
公开(公告)日:1969-08-26
申请号:CA821587D
Applicant: BASF AG
Inventor: WELZEL GERHARD , REINHARD HANS , MUELLER ALFRED
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公开(公告)号:GB1125718A
公开(公告)日:1968-08-28
申请号:GB280866
申请日:1966-01-21
Applicant: BASF AG
Inventor: REINHARD HANS , HOELSCHER FRIEDRICH , DOTZAUER BERNHARD
IPC: C09D127/08 , D21H19/20 , D21H19/82
Abstract: 1,125,718. Coated sheet material. BADISCHE ANILIN-& SODA FABRIK, A.G. 21 Jan., 1966 [22 Jan., 1965], No. 2808/66. Heading B2E. [Also in Division C3] Sheet materials containing cellulose are coated with a sub-coat by applying aqueous dispersions of mixtures of (1) copolymers A of 80-98% by weight of vinylidene chloride and 2-20% by weight of copolymerisable monoethylenically unsaturated compounds and (2) polymers B of ethylenically unsaturated compounds having a glass transition temperature of +10 to -55C, the amount of polymers B being 10-65% of the weight of the sum of the polymers A and B in the mixture, drying the sub-coat and thereafter applying as top-coat aqueous dispersions of a copolymer of 80-98% by weight of vinylidene chloride and 2-20% by weight of a copolymerisable monoethylenically unsaturated compound and drying the top-coat. Compounds copolymerisable with the vinylidene chloride in copolymers A may be esters of acrylic and/or methacrylic acid and monohydric aliphatic alcohols containing 1-8 carbon atoms in the alcohol radical, and vinyl chloride, acrylonitrile, methacrylonitrile, styrene, vinyl esters of aliphatic monocarboxylic acids having 2-12 carbon atoms, such as vinyl acetate and propionate, acrylamide, methacrylamide, acrylic acid, methacrylic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid, the monoamides and N-substituted monoamides of said acids, esters and monoesters of these acids, and aliphatic monohydric and aliphatic monohydric alcohols containing 1-8 carbon atoms, maleic anhydride and itaconic anhydride. Polymers B may be copolymers containing 40-90% by weight of esters of acrylic acid and/or methacrylic acid with monohydric alcohols containing 2-8 carbon atoms and 10-60% of other conventional monoethylenically unsaturated compounds polymerisable by free radical mechanisms, such as methyl methacrylate, methyl acrylate, styrene, acrylonitrile, vinyl chloride or vinylidene chloride Copolymers of n-butyl acrylate and of butadiene with styrene, acrylonitrile or esters of ethylenically unsaturated carboxylic acids may be used. The proportions of monomers must be such as to provide the specified glass transition temperature. Various suitable copolymers are identified in the Examples. Emulsifiers may be added to the dispersions such as surface active salts of sulphonated ethenoxylated alkylphenols or fatty alcohols. Heat and light stabilizers, anti-foams,. thickeners and plasticizers may be added. Coating may be by means of doctor knives, rollers or shreading means, flooding means, houring or dipping. Drying may be with infrared rays or preheated air. The substrate may be paper or laminates of paper with metal foils such as aluminium foils.
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公开(公告)号:GB1119787A
公开(公告)日:1968-07-10
申请号:GB4876565
申请日:1965-11-17
Applicant: BASF AG
Inventor: REINHARD HANS , HERRLE KARL , BLUM DIETER WOLFGANG , LOECHNER ARNOLD
Abstract: Packaging material is prepared by coating flat substrates with aqueous dispersions of polymers of vinylidene chloride wherein the aqueous polymer dispersions are mixtures of an aqueous dispersion of 50 to 75 parts by weight of a copolymer A of 85 to 92% by weight of vinylidene chloride and 15 to 8% by weight of an ester of an ethylenically unsaturated carboxylic acid having 3 to 5 carbon atoms with an alcohol containing 1 to 8 carbon atoms and an aqueous dispersion of 25 to 50 parts by weight of a copolymer B of 55 to 67% by weight of butadiene and 33 to 45% by weight of acrylonitrile and/or methacrylonitrile. From 10 to 50% by weight of the ester units of copolymer A may be replaced by units of acrylonitrile, methacrylonitrile and/or vinyl chloride. Up to 20% by weight of the units of butadiene in copolymer B may be replaced by units of one or more esters of ethylenically unsaturated carboxylic acids having 3 to 5 carbon atoms with alcohols containing 1 to 8 carbon atoms. Examples of copolymers are given. The substrate may be fibrous e.g. paper, or films or sheeting of plastics e.g. polyethylene, polypropylene, polystyrene, polyethylene terephthalate, polyvinyl chloride, and metal foils e.g. aluminium foil. The coating may be applied by means of doctor knives, air brushes or rollers, spray, flooding, pouring a dipping means. A further coating containing a copolymer of vinylidene chloride and methyl acrylate may be applied.
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公开(公告)号:CA756051A
公开(公告)日:1967-04-04
申请号:CA756051D
Applicant: BASF AG
Inventor: REINHARD HANS , HOELSCHER FRIEDRICH , DOTZAUER BERNHARD
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公开(公告)号:FR1414154A
公开(公告)日:1965-10-15
申请号:FR991609
申请日:1964-10-15
Applicant: BASF AG
Inventor: MUELLER HERBERT , SEIBT HUBERTUS , REINHARD HANS , PETRI ROLF
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47.
公开(公告)号:GB951015A
公开(公告)日:1964-03-04
申请号:GB2185262
申请日:1962-06-06
Applicant: BASF AG
Inventor: REINHARD HANS , SLIWKA WOLFGANG , PETRI ROLF
Abstract: Concretes are prepared by adding to the conventional mix, 0.5 to 50% by weight, based on the weight of cement, of a copolymer of 20-80% vinyl chloride and 80-20% of vinyl proprionate in the form of an aqueous dispersion or a redispersible powder 0.5-60% by weight, based on the copolymer, of hydrocarbons may also be added e.g. benzene, toluene, xylene, the higher boiling aliphatics and the terpenes. The dispersing agent may be polyvinyl alcohol.
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公开(公告)号:FR1289737A
公开(公告)日:1962-04-06
申请号:FR860065
申请日:1961-04-27
Applicant: BASF AG
Inventor: PENNING ERNST , REINHARD HANS , DISTLER HARRY
IPC: C08F2/22 , C08F20/62 , C08F28/00 , C08F220/06
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公开(公告)号:BE603084A
公开(公告)日:1961-10-26
申请号:BE603084
申请日:1961-04-26
Applicant: BASF AG
Inventor: PENNING ERNST , REINHARD HANS , DISTLER HARRY
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公开(公告)号:FR1269384A
公开(公告)日:1961-08-11
申请号:FR833199
申请日:1960-07-18
Applicant: BASF AG
Inventor: REINHARD HANS , PETRI ROLF , HOELSCHER FRIEDRICH
IPC: C04B24/26
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