METHOD OF MAKING THE AROMATIC AZOMETHINS THE AROMATIC AZOMETHINS

    公开(公告)号:CS216532B2

    公开(公告)日:1982-11-26

    申请号:CS435280

    申请日:1980-06-19

    Applicant: BASF AG

    Abstract: Aromatic azomethines are prepared by reacting anilines with formaldehyde and then removing the greater part of the water by distillation, low-boiling alcohols, in certain amounts, being present during the distillation and, if desired, during the reaction or during a part thereof. The aromatic azomethines obtainable by the novel process are valuable starting materials for the preparation of herbicides, especially pre-emergence herbicides and post-emergence herbicides, fungicides, insecticides, bacteriostatic agents, fungistatic agents and vulcanization accelerators.

    45.
    发明专利
    未知

    公开(公告)号:ES2091007T3

    公开(公告)日:1996-10-16

    申请号:ES93912713

    申请日:1993-05-18

    Applicant: BASF AG

    Abstract: The manufacture of 5-dichloroacetyl-3,3,6-trimethyl-9-oxo-1,5-diazabicyclo[4.3.0]-nonane I by the reaction of 3,3,6-trimethyl-9-oxo-1,5-diaza-bicyclo[4.3.0]nonane II with dichloroacetyl chloride in the presence of a solvent and a base, wherein a) this reaction is carried out in a two-phase system comprising a virtually water-insoluble organic solvent and water, and sodium or potassium hydroxide acting as the base is metered in at a rate corresponding to the rate of consumption of the dichloroacetyl chloride such that the aqueous phase exhibits a pH of from 7 to 9, and b) the resulting product is separated.

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