2-AMINOCINNAMIC ACID ESTERS
    2.
    发明申请
    2-AMINOCINNAMIC ACID ESTERS 审中-公开
    2-氨基辛酸酯

    公开(公告)号:WO9209575A2

    公开(公告)日:1992-06-11

    申请号:PCT/EP9102166

    申请日:1991-11-16

    Applicant: BASF AG

    CPC classification number: C07D209/48

    Abstract: The invention concerns the preparation of 3-(3,4,5,6-tetrahydrophthalimido)cinnamic acid esters of formula (I) (R1 = H, halogen; R2, R3 = halogen; R4 = C-organic rest; R5 = H, CH¿3?) by the reduction of 3-nitrocinnamic acid esters of formula (II) with hydrogen in the presence of a catalyst and the condensation of the 3-aminocinnamic acid esters obtained of formula (III) with a 3,4,5,6-tetrahydrophthalic acid anhydride of formula (IV). 3-(3,4,5,6-tetrahydrophthalimido)cinnamic acid esters of formula (I) are useful active agents in the plant-protection field.

    3.
    发明专利
    未知

    公开(公告)号:DE59109206D1

    公开(公告)日:2001-03-01

    申请号:DE59109206

    申请日:1991-11-16

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP91/02166 Sec. 371 Date Apr. 29, 1993 Sec. 102(e) Date Apr. 29, 1993 PCT Filed Nov. 16, 1991 PCT Pub. No. WO92/09575 PCT Pub. Date Jun. 11, 1992.3-(3,4,5,6-tetrahydrophthalimido)cinnamic esters I I (R1=H, halogen; R2, R3=halogen; R4=C-organic radical, R5=H, CH3) are prepared by reducing 3-nitrocinnamic esters II and condensing the resulting 3-aminocinnamic esters III III with a 3,4,5,6-tetrahydrophthalic anhydride IV IV and are valuable active ingredients in crop protection.

    4.
    发明专利
    未知

    公开(公告)号:AT198882T

    公开(公告)日:2001-02-15

    申请号:AT91920302

    申请日:1991-11-16

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP91/02166 Sec. 371 Date Apr. 29, 1993 Sec. 102(e) Date Apr. 29, 1993 PCT Filed Nov. 16, 1991 PCT Pub. No. WO92/09575 PCT Pub. Date Jun. 11, 1992.3-(3,4,5,6-tetrahydrophthalimido)cinnamic esters I I (R1=H, halogen; R2, R3=halogen; R4=C-organic radical, R5=H, CH3) are prepared by reducing 3-nitrocinnamic esters II and condensing the resulting 3-aminocinnamic esters III III with a 3,4,5,6-tetrahydrophthalic anhydride IV IV and are valuable active ingredients in crop protection.

    6.
    发明专利
    未知

    公开(公告)号:ES2091007T3

    公开(公告)日:1996-10-16

    申请号:ES93912713

    申请日:1993-05-18

    Applicant: BASF AG

    Abstract: The manufacture of 5-dichloroacetyl-3,3,6-trimethyl-9-oxo-1,5-diazabicyclo[4.3.0]-nonane I by the reaction of 3,3,6-trimethyl-9-oxo-1,5-diaza-bicyclo[4.3.0]nonane II with dichloroacetyl chloride in the presence of a solvent and a base, wherein a) this reaction is carried out in a two-phase system comprising a virtually water-insoluble organic solvent and water, and sodium or potassium hydroxide acting as the base is metered in at a rate corresponding to the rate of consumption of the dichloroacetyl chloride such that the aqueous phase exhibits a pH of from 7 to 9, and b) the resulting product is separated.

    PREPARATION OF 3-FORMYLTETRAHYDROTHIOPYRANS

    公开(公告)号:CA1230125A

    公开(公告)日:1987-12-08

    申请号:CA463007

    申请日:1984-09-12

    Applicant: BASF AG

    Abstract: 3-Formyltetrahydrothiopyrans are prepared by hydroyenating a 3-formyl-5,6-dihydro-2H-thiopyran in the presence of a catalyst containing nickel, cooalt, platinum, copper and/or silver; if necessary, the 3-formyl-5,6-dihydro-2H-thiopyrans are prepared by converting bis-(.beta.-formylethyl) sulfides and/or 3-formyl-4-hydroxy-tetrahydrothiopyrans in the presence of an acidic catalyst, and, if required, these bis-(.beta.-formylethyl) sulfides and/ or 3-formyl-4-hydroxytetrahydrothiopyrans are prepared by reacting an acrolein with hydrogen sulfide a) in the presence of a basic catalyst and of methylene chloride, aromatic hydrocarbons and/or 1,1,2-trichloroethane as solvents, and/or b) in the presence of a carboxamide. The compounds obtainable by the process according to the invention are useful starting materials for the preparation of dyes, drugs and pesticides.

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